Li0.5Bi0.5MoO4对Li2Zn2(MoO4)3陶瓷的微波介电性能影响

摘要/Abstract

摘要： 采用传统固相反应法制备了xLi_0.5Bi_0.5MoO₄-(1-x)Li₂Zn₂(MoO₄)₃ [xLBM-(1-x)LZM]复合陶瓷,研究添加不同质量分数(x=25%,30%,35%,40%和45%)的LBM对LZM陶瓷的烧结特性、物相组成、微观结构以及微波介电性能的影响。结果表明:添加一定量的LBM不仅能将LZM的谐振频率温度系数(τ_f)调节近零,还能降低LZM的烧结致密化温度;LBM可与LZM共存,且不发生化学反应生成其他新相。随着LBM添加量增加,复合陶瓷的烧结致密化温度逐渐降低、体积密度先增大后减小、介电常数(ε_r)与τ_f逐渐增大而品质因数(Q×f)逐渐减小。当LBM添加量为40%时,LZM-LBM复合陶瓷在600 ℃烧结2 h获得最大体积密度为4.41 g/cm³,以及优异的微波介电性能:ε_r为13.8,Q×f为28 581 GHz,τ_f为-4×10^-6/℃。

关键词: Li_0.5Bi_0.5MoO₄陶瓷, Li₂Zn₂(MoO₄)₃陶瓷, 低温烧结, 微波介电性能

Abstract: The xLi_0.5Bi_0.5MoO₄-(1-x)Li₂Zn₂(MoO₄)₃ [xLBM-(1-x)LZM] composite ceramics were prepared by traditional solid-state reaction method. The sintering characteristics, phase composition, microstructures and microwave dielectric properties of LZM ceramics with different mass fraction (x=25%, 30%, 35%, 40% and 45%) of LBM were investigated. The results show that, LBM effectively adjust the resonant frequency temperature coefficient (τ_f) of LZM ceramics to near zero and also decreases the sintering temperature; LBM can coexist with LZM, and no new phases are detected in addition to the LZMT and LBM phase. With the increase of LBM ceramics, the sintering densification temperature decreases gradually, the bulk density of composite ceramics initially increases and then decreases, the permittivity (ε_r) and τ_f increases, the quality factor (Q×f) decreases gradually. When 40%LBM ceramics is added, LZM-LBM composite ceramics sintered at 600 ℃ for 2 h obtained maximun bulk density of 4.41 g/cm³,and excellent microwave dielectric properties of the ε_r is 13.8, the Q×f is 28 581 GHz and τ_f is -5×10^-6/℃.

Key words: Li_0.5Bi_0.5MoO₄ ceramics, Li₂Zn₂(MoO₄)₃ ceramics, low temperature sintering, microwave dielectric property

中图分类号:

TQ174

舒国劲, 窦占明, 杨俊, 庞锦标, 袁世逢, 刘凯, 申懿婷. Li_0.5Bi_0.5MoO₄对Li₂Zn₂(MoO₄)₃陶瓷的微波介电性能影响[J]. 人工晶体学报, 2022, 51(12): 2118-2124.

SHU Guojin, DOU Zhanming, YANG Jun, PANG Jinbiao, YUAN Shifeng, LIU Kai, SHEN Yiting. Effect of Li_0.5Bi_0.5MoO₄ on Microwave Dielectric Properties of Li₂Zn₂(MoO₄)₃ Ceramics[J]. JOURNAL OF SYNTHETIC CRYSTALS, 2022, 51(12): 2118-2124.

参考文献

[1] OHSATO H. Research and development of microwave dielectric ceramics for wireless communications[J]. Journal of the Ceramic Society of Japan, 2005, 113(1323): 703-711.
[2] SEBASTIAN M T. Acknowledgment[M]//Dielectric Materials for Wireless Communication. Amsterdam: Elsevier, 2008: xiii.
[3] SEBASTIAN M T, WANG H, JANTUNEN H. Low temperature co-fired ceramics with ultra-low sintering temperature: a review[J]. Current Opinion in Solid State and Materials Science, 2016, 20(3): 151-170.
[4] LUO X F, REN L C, XIA Y S, et al. Microstructure, sinterability and properties of CaO-B₂O₃-SiO₂ glass/Al₂O₃ composites for LTCC application[J]. Ceramics International, 2017, 43(9): 6791-6795.
[5] 张高群,汪宏.超低温烧结微波介质陶瓷研究进展[J].硅酸盐学报,2017,45(9):1256-1264.
ZHANG G Q, WANG H. Research progress of ultra-low temperature cofired ceramics for microwave applications[J]. Journal of the Chinese Ceramic Society, 2017, 45(9): 1256-1264(in Chinese).
[6] WENG Z Z, GUAN R G, XIONG Z X. Effects of the ZBS addition on the sintering behavior and microwave dielectric properties of 0.95Zn₂SiO₄-0.05CaTiO₃ ceramics[J]. Journal of Alloys and Compounds, 2017, 695: 3517-3521.
[7] WENG Z Z, WU C, XIONG Z X, et al. Low temperature sintering and microwave dielectric properties of TiO₂ ceramics[J]. Journal of the European Ceramic Society, 2017, 37(15): 4667-4672.
[8] ZHANG G Q, GUO J, HE L, et al. Preparation and microwave dielectric properties of ultra-low temperature sintering ceramics in K₂O-MoO₃ binary system[J]. Journal of the American Ceramic Society, 2014, 97(1): 241-245.
[9] ZHANG G Q, WANG H, GUO J, et al. Ultra-low sintering temperature microwave dielectric ceramics based on Na₂O-MoO₃ binary system[J]. Journal of the American Ceramic Society, 2015, 98(2): 528-533.
[10] ZHOU D, PANG L X, QI Z M, et al. Novel ultra-low temperature co-fired microwave dielectric ceramic at 400 degrees and its chemical compatibility with base metal[J]. Scientific Reports, 2014, 4: 5980.
[11] ZHOU D, WANG H, PANG L X. Bi₂O₃-MoO₃ binary system: an alternative ultralow sintering temperature microwave dielectric[J]. Journal of the American Ceramic Society, 2009, 92(10): 2242-2246.
[12] ZHOU D, RANDALL C A, PANG L X, et al. Microwave dielectric properties of Li₂(M²⁺)₂Mo₃O₁₂ and Li₃(M³⁺)Mo₃O₁₂ (M=Zn, Ca, Al, and In) lyonsite-related-type ceramics with ultra-low sintering temperatures[J]. Journal of the American Ceramic Society, 2011, 94(3): 802-805.
[13] LIU X B, ZHOU H F, CHEN X L, et al. Phase structure and microwave dielectric properties of (1-x)Li₂Zn₃Ti₄O₁₂-xTiO₂ ceramics[J]. Journal of Alloys and Compounds, 2012, 515: 22-25.
[14] QUAN T T, SHU G J, HAO L, et al. Phase compositions, microstructures, and microwave dielectric properties of Li₂Zn₃Ti₄O₁₂-based temperature stable materials modified by CaTiO₃ additions[J]. Journal of Materials Science: Materials in Electronics, 2019, 30(22): 20160-20165.
[15] 杨晓丽.Li₂Zn₂Mo₃O₁₂基微波介质陶瓷的制备及其介电性能研究[D].南京:南京航空航天大学,2017.
YANG X L. Study on the preparation and dielectric properties of Li₂Zn₂Mo₃O₁₂-based microwave dielectric ceramics[D]. Nanjing: Nanjing University of Aeronautics and Astronautics, 2017(in Chinese).
[16] 徐静,杨晓丽,郑勇,等.温度稳定型Li₂(Zn_1-xCo_x)₂Mo₃O₁₂陶瓷的微波介电性能研究[J].电子元件与材料,2017,36(11):16-21+37.
XU J, YANG X L, ZHENG Y, et al. Microwave dielectric properties of temperature stable Li₂(Zn_1-xCo_x)₂Mo₃O₁₂ ceramics[J]. Electronic Components and Materials, 2017, 36(11): 16-21+37(in Chinese).
[17] ZHOU D, RANDALL C A, PANG L X, et al. Microwave dielectric properties of (ABi)_1/2MoO₄ (A=Li, Na, K, Rb, Ag) type ceramics with ultra-low firing temperatures[J]. Materials Chemistry and Physics, 2011, 129(3): 688-692.
[18] ZHANG Y H, SUN J J, DAI N, et al. Crystal structure, infrared spectra and microwave dielectric properties of novel extra low-temperature fired Eu₂Zr₃(MoO₄)₉ ceramics[J]. Journal of the European Ceramic Society, 2019, 39(4): 1127-1131.
[19] GUO J, ZHOU D, WANG H, et al. Microwave and infrared dielectric response of temperature stable (1-x)BaMoO₄-xTiO₂ composite ceramics[J]. Journal of the American Ceramic Society, 2012, 95(1): 232-237.

Li_0.5Bi_0.5MoO₄对Li₂Zn₂(MoO₄)₃陶瓷的微波介电性能影响

Effect of Li_0.5Bi_0.5MoO₄ on Microwave Dielectric Properties of Li₂Zn₂(MoO₄)₃ Ceramics

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	李旺;杜江萍;唐鹿. V5+掺杂CaCu3 Ti4 O12陶瓷的低温合成及烧结性能[J]. 人工晶体学报, 2019, 48(3): 499-504.
[2]	李欢;薛屺;牟军;?屏?谢准. 低温烧结3Y-TZP陶瓷的研究[J]. 人工晶体学报, 2018, 47(6): 1204-1209.
[3]	屈婧婧;魏星;马莉;刘飞;袁昌来;李维. Mg3(Si1-xCex)2O7系复合陶瓷微波介电性能研究[J]. 人工晶体学报, 2018, 47(5): 1018-1023.
[4]	廖燕君;蒙柳方;刘秋颖;王子兴;袁昌来. SrTiO3/Mg6Ti5O16复合陶瓷的微波介电性能研究[J]. 人工晶体学报, 2018, 47(4): 734-738.
[5]	郭腾;郭雨;丁志杰;惠贞贞;叶祥桔;陈君华;顾燕. 具有尖晶石结构的LiFeTiO4材料的烧结与微波介电性能的研究[J]. 人工晶体学报, 2017, 46(6): 1015-1020.
[6]	孙文飞;刘卫;黎阳. 磷酸盐低温烧结高强度SiC泡沫陶瓷及性能研究[J]. 人工晶体学报, 2017, 46(6): 1038-1042.
[7]	张文杰;王晓川;雷文;汪小红;吕文中. ZnO-B2O3玻璃对0.95(Mg0.9Zn0.1)TiO3-0.05CaTiO3陶瓷烧结特性和微波介电性能的影响[J]. 人工晶体学报, 2015, 44(8): 2106-2111.
[8]	宋福生;李月明;沈宗洋;谢志翔;王竹梅;廖润华. Zn1-xMgxZrNb2O8微波介质陶瓷的结构与性能研究[J]. 人工晶体学报, 2015, 44(8): 2225-2230.
[9]	李月明;洪文海;谢志翔;王竹梅;沈宗洋;廖润华. Zn0.99Cu0.01Al2O4-TiO2基微波介质陶瓷的研究[J]. 人工晶体学报, 2015, 44(5): 1171-1175.
[10]	谢志翔;洪文海;李月明;王竹梅;沈宗洋;廖润华. Zn0.99Cu0.01Al2O4-SrTiO3微波陶瓷介电性能的研究[J]. 人工晶体学报, 2015, 44(3): 681-685.
[11]	齐建全;贾宏耀;骆佳丽;谢威;钟瑞霞;韩秀梅;马振伟;董晓瑜;吴音. 锆钛酸钡陶瓷的超低温烧结及其介电特性[J]. 人工晶体学报, 2015, 44(11): 3284-3287.
[12]	金彪;汪潇;杨留栓. 掺杂和包覆H3BO3对BZN陶瓷烧结和介电性能的影响[J]. 人工晶体学报, 2014, 43(5): 1243-1246.
[13]	李月明;汪启轩;王竹梅;沈宗洋;洪燕;谭芳. 粉体粒径对CSLST微波介质陶瓷烧结温度的影响[J]. 人工晶体学报, 2014, 43(2): 333-338.
[14]	冯志;徐光亮;余洪滔;王霖;程艳奎. Cu2+掺杂对M型钡铁氧体烧结行为和磁性能的影响[J]. 人工晶体学报, 2014, 43(1): 168-172.
[15]	谭菊. 溶胶-凝胶法制备不同锌硅比硅酸锌陶瓷[J]. 人工晶体学报, 2013, 42(2): 360-364.