Dy3+掺杂Gd2MgTiO6白色荧光粉的制备及发光性能研究

摘要/Abstract

摘要： 采用溶胶-凝胶法制备出掺杂不同Dy³⁺浓度的系列Gd₂MgTiO₆(GMT)白色荧光粉。通过X射线衍射仪(XRD)、扫描电子显微镜(SEM)、荧光光谱仪对GMT:xDy³⁺(x=0.01、0.03、0.05、0.07、0.09、0.11)样品进行表征。研究结果表明:所制备的系列荧光粉的结构均为单斜晶系,Dy³⁺成功掺入GMT基质的同时不影响原晶体结构;样品晶粒尺寸在微米量级。在351 nm的近紫外光激发下,样品在483和578 nm处分别显示了极强的蓝光和黄光,其中蓝光归因于Dy³⁺的⁴F_9/2→⁶H_15/2的能级跃迁,黄光归因于Dy³⁺的⁴F_9/2→⁶H_13/2能级跃迁;随着Dy³⁺浓度的不断增加,出现明显的浓度猝灭现象,其机理归因于电偶极子-电偶极子相互作用。当x=0.05时,此时CIE坐标为(0.324 71, 0.359 74),与标准白光的CIE坐标(0.33,0.33)较为接近,表明GMT:Dy³⁺是一种具有潜在应用价值的单一基质白色荧光粉。

关键词: GMT基质, 溶胶-凝胶法, Dy³⁺单掺, w-LED

Abstract: A series of Gd₂MgTiO₆ (GMT) white phosphors doped with different Dy³⁺ concentrations were prepared by the sol-gel method.The GMT:xDy³⁺(x=0.01, 0.03, 0.05, 0.07, 0.09, 0.11) samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and fluorescence spectroscopy. The research results show that the structure of the prepared series of fluorescent powders is monoclinic, and Dy³⁺ was successfully doped into GMT matrix without affecting the original crystal structure. The grain size of the sample is in the micrometer scale. Under near-ultraviolet excitation at 351 nm, the sample exhibits extremely strong blue and yellow light at 483 and 578 nm, respectively. The blue light is attributed to the ⁴F_9/2→⁶H_15/2 energy level transition of Dy³⁺, while the yellow light belongs to the ⁴F_9/2→⁶H_13/2 energy level transition of Dy the continuous increase of Dy³⁺ concentration, there is a significant concentration quenching phenomenon, which is attributed to the interaction between electric dipoles. When x=0.05, the CIE coordinates (0.324 71, 0.359 74) are relatively close to the CIE coordinates of standard white light (0.33, 0.33), indicating that GMT:Dy³⁺ is a single matrix white phosphor with potential application value.

Key words: GMT matrix, sol-gel method, Dy³⁺ monodoping, w-LED

中图分类号:

TQ152
TM53

赵炎, 蒋小康, 高峰, 尹红梅, 周恒为. Dy³⁺掺杂Gd₂MgTiO₆白色荧光粉的制备及发光性能研究[J]. 人工晶体学报, 2023, 52(11): 2050-2056.

ZHAO Yan, JIANG Xiaokang, GAO Feng, YIN Hongmei, ZHOU Hengwei. Preparation and Luminescence Properties of Dy³⁺ Doped Gd₂MgTiO₆ White Phosphor[J]. Journal of Synthetic Crystals, 2023, 52(11): 2050-2056.

参考文献

[1] XIONG H R, GAO X, YUAN F, et al. Photoluminescence enhancement of orange-emitting Ca₅(PO₄)₂SiO₄:Sm³⁺ phosphor through charge compensation of A⁺ (Li⁺, Na⁺ and K⁺) ions for white light-emitting diodes[J]. Dalton Transactions, 2022, 51(22): 8874-8884.
[2] CHENG J, BIAN X T, ZHAI Z Y, et al. A single-phase full-color phosphor Sr₂Ca₂La(PO₄)₃O:Eu²⁺, Tb³⁺, Mn²⁺: photoluminescence and energy transfer[J]. Journal of Rare Earths, 2022. 40(4): 541-550.
[3] SHI L, HAN Y J, JI Z X, et al. Highly efficient and thermally stable CaYMgSbO₆:Mn⁴⁺ double perovskite red phosphor for indoor plant growth[J]. Journal of Materials Science: Materials in Electronics, 2019, 30(3): 3107-3113.
[4] MURALIMANOHAR P, SRILATHA G, SATHYAMOORTHY K, et al. Preparation and luminescence properties of Dy³⁺ doped BaAlBO₃F₂ glass ceramic phosphor for solid state white LEDs[J]. Optik, 2021, 225: 165807.
[5] LI Z J, LIU B, ZHANG Y Y, et al. Cyan, deep red and white light emission generated by SrLaGa₃O₇:Bi³⁺, SrLaGa₃O₇:Mn⁴⁺ and SrLaGa₃O₇:Bi³⁺/Mn⁴⁺ phosphors[J]. Journal of Alloys and Compounds, 2022, 894: 162455.
[6] 陆逸, 许英朝, 孟宪国, 等. 高热稳定性CaSrNb₂O₇:Sm³⁺橙红色荧光粉的合成及发光性能[J/OL]. 中国稀土学报: 1-11. http://kns.cnki.net/kcms/detail/11.2365.TG.20221129.1616.006.html.
LU Y, XU Y L, MENG X G, et al. Synthesis and luminescence performance of high thermal stability CaSrNb₂O₇:Sm³⁺ orange red fluorescent powder[J/OL]. Journal of Rare Earth Research in China: 1-11. http://kns.cnki.net/kcms/detail/11.2365.TG.20221129.1616.006.html (in Chinese).
[7] 曹铷. 过渡金属离子Mn⁴⁺与稀土离子Tb³⁺在BaZn_1.06Al_9.94O₁₇基质中的发光性质研究[D]. 延吉: 延边大学, 2019.
CAO R. Luminescence properties of transition metal ion Mn⁴⁺ and rare earth Tb³⁺ in BaZn_1.06Al_9.94O₁₇ matrix[D].Yanji: Yanbian University, 2019 (in Chinese).
[8] SHARMA S, BRAHME N, BISEN D P, et al. Generation of cold white light by using energy transfer process in single phase Ce³⁺/Tb³⁺ co-doped CaSrAl₂SiO₇ phosphor[J]. Optics & Laser Technology, 2021, 135: 106682.
[9] 武丽娜. 稀土离子掺杂双钙钛矿A_ⅰA_ⅱMgB_ⅱO₆:RE³⁺(A_i= Li⁺, Na⁺;A_ⅱ= Y³⁺, Eu³⁺; B_ⅱ= W⁶⁺, Mo⁶⁺)荧光粉的研究[D]. 西安:西北大学, 2022.
WU L N. Research on rare earth ions doped double perovskite A_iA_iiMgB_iiO₆:RE³⁺(A_i=Li⁺, Na⁺; A_ii=Y³⁺, Eu³⁺; B_ii=W⁶⁺, Mo⁶⁺) Fluorescent powder [D].Xi An: Northwestern University, 2022 (in Chinese).
[10] TANG W J, GUO Q F, SU K, et al. Structure and photoluminescence properties of Dy³⁺ doped phosphor with whitlockite structure[J]. Materials, 2022, 15(6): 2177.
[11] HU T, XIA L, LIU W, et al. Dy³⁺-doped LaInO₃: a host-sensitized white luminescence phosphor with exciton-mediated energy transfer[J]. Journal of Materials Chemistry C, 2021, 9(38): 13410-13419.
[12] LIAN Y S, WANG Y, LI J F, et al. Structural and optical properties of Dy³⁺:YAlO₃ phosphors for yellow light-emitting diode applications[J]. Journal of Rare Earths, 2021, 39(8): 889-896.
[13] 刘家明. CaTiO₃: Dy³⁺白色荧光粉的合成与性能研究[D]. 成都: 成都理工大学, 2019.
LIU J M. Synthesis and properties of CaTiO₃: Dy³⁺ white phosphor[D].Chengdu: Chengdu University of Technology, 2019 (in Chinese).
[14] YU X F, WANG Z Y, WANG Q R, et al. Warm white emission of Ca₂P₂O₇:Dy³⁺, Eu³⁺ phosphor via hydrothermal method[J]. Journal of Alloys and Compounds, 2022, 897: 162745.
[15] 蒋小康, 周琦, 张王曦月, 等. Gd₂ZnTiO₆:Dy³⁺白光荧光粉的制备及荧光性质的研究[J]. 化工新型材料, 2022, 50(6): 281-285.
JIANG X K, ZHOU Q, ZHANG W X Y, et al. Synthesis and property of Gd₂ZnTiO₆:Dy³⁺ white phosphor[J]. New Chemical Materials, 2022, 50(6): 281-285 (in Chinese).
[16] LU C H, KUO P H, SOM S. Efficient white light emission from a single silicate host with promising color quality for white light emitting diodes[J]. Optik, 2022, 251: 168244.
[17] MUSHTAQUE S G M, PAWADE V B, DHOBLE S J. Energy transfer process in a rare earth (Ce³⁺, Dy³⁺, Sm³⁺)-doped nanocrystalline phosphate phosphor[J]. Luminescence, 2022, 37(6): 1009-1017.
[18] SONG F M. Synthesis and photoluminescence of new Eu³⁺ activated Cs₂Ba(MoO₄)₂ red-emitting phosphors with high color purity for white LEDs[J]. Journal of Luminescence, 2021, 239: 118324.
[19] 鞠小霞, 王海波, 向枫, 等. 钼酸盐荧光粉的研究进展[J]. 稀土, 2019, 40(6): 105-116.
JU X X, WANG H B, XIANG F, et al. Recent advances of molybdate phosphors[J]. Chinese Rare Earths, 2019, 40(6): 105-116 (in Chinese).
[20] UPADHYAY K, THOMAS S, TAMRAKAR R K, et al. Comparative study of structural and optical behavior of Er³⁺ doped Y₂SiO₅ phosphor prepared by different methods[J]. Materials Science and Engineering: B, 2022, 275: 115511.
[21] 蒋小康, 周琦, 周恒为. Gd₂ZnTiO₆:Dy³⁺, Eu³⁺单基质白光荧光粉的制备与发光性能[J]. 高等学校化学学报, 2022, 43(6): 77-83.
JIANG X K, ZHOU Q, ZHOU H W. Synthesis and luminescence properties of Gd₂ZnTiO₆:Dy³⁺, Eu³⁺ single phase white light-emitting phosphors[J]. Chemical Journal of Chinese Universities, 2022, 43(6): 77-83 (in Chinese).
[22] LIU Y Y, GAO J, SHI W, et al. Deep-red-emitting Mg₂InSbO₆:Mn⁴⁺ phosphors with a double-perovskite structure for plant-cultivation LEDs: synthesis and photoluminescence properties[J]. Ceramics International, 2021, 47(13): 18814-18823.
[23] ZHANG Z J, LI W, MA N, et al. High-brightness red-emitting double-perovskite phosphor Sr₂LaTaO₆:Eu³⁺ with high color purity and thermal stability[J]. Chinese Optics Letters, 2021, 19(3): 030003.
[24] ZENG H T, ZHOU T L, WANG L, et al. Two-site occupation for exploring ultra-broadband near-infrared phosphor—double-perovskite La₂MgZrO₆:Cr³⁺[J]. Chemistry of Materials, 2019, 31(14): 5245-5253.
[25] VEENA V P, SHILPA C K, JASIRA S V, et al. Modern era of double perovskite nano-phosphors: La₂MgTiO₆, Gd₂MgTiO₆ and Y₂MgTiO₆-a brief review[J]. Zeitschrift Für Naturforschung A, 2022, 77(10): 1003-1013.
[26] BLASSE G. Energy transfer in oxidic phosphors[J]. Physics Letters A, 1968, 28(6): 444-445.
[27] VAN UITERT L G. Characterization of energy transfer interactions between rare earth ions[J]. Journal of the Electrochemical Society, 1967, 114(10): 1048.

Dy³⁺掺杂Gd₂MgTiO₆白色荧光粉的制备及发光性能研究

Preparation and Luminescence Properties of Dy³⁺ Doped Gd₂MgTiO₆ White Phosphor

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