超低膨胀微晶玻璃发展现状及应用

摘要/Abstract

摘要： 超低膨胀微晶玻璃是在Li₂O-Al₂O₃-SiO₂系玻璃的基础上经过严格的受控晶化,在母体玻璃中析出以β-石英固溶体为主晶相的微晶玻璃材料。由于具有极低的热膨胀系数,以及优异的热稳定性、化学稳定性和力学性能,超低膨胀微晶玻璃在诸多领域得到了广泛应用。本文综述了超低膨胀微晶玻璃的组成、制备方法、国内外研究历程及发展现状、应用,指出了目前生产超低膨胀微晶玻璃存在的问题和国产超低膨胀微晶玻璃与国际顶尖产品存在的差距,以及国产超低膨胀微晶玻璃今后的发展方向。

关键词: Li₂O-Al₂O₃-SiO₂系玻璃, 超低膨胀, β-石英固溶体, 微晶玻璃, 受控晶化

Abstract: Ultra-low expansion glass-ceramics is a kind of glass-ceramics with β-quartz solid solution as main crystal phase precipitated in parent glass after strictly controlled crystallization on the basis of Li₂O-Al₂O₃-SiO₂ system glass. Because of its low coefficient of thermal expansion, excellent thermal stability, chemical stability and mechanical properties, ultra-low expansion glass-ceramics have been widely used in many fields. In this paper, the composition, preparation method, domestic and international research process and development status, application of ultra-low expansion glass-ceramics are reviewed, and the existing problems in the production of ultra-low expansion glass-ceramics and the gap between the domestic ultra-low expansion glass-ceramics and the top international products, and the development direction of domestic ultra-low expansion glass-ceramics in the future are pointed out.

Key words: Li₂O-Al₂O₃-SiO₂ system glass, ultra-low expansion, β-quartz solid solution, glass-ceramics, controlled crystallization

中图分类号:

TQ171

赵春霞, 蒋新朝, 张微, 刘杰, 范仕刚, 何粲. 超低膨胀微晶玻璃发展现状及应用[J]. 人工晶体学报, 2023, 52(12): 2135-2145.

ZHAO Chunxia, JIANG Xinzhao, ZHANG Wei, LIU Jie, FAN Shigang, HE Can. Development Status and Application of Ultra-Low Expansion Glass-Ceramics[J]. JOURNAL OF SYNTHETIC CRYSTALS, 2023, 52(12): 2135-2145.

参考文献

[1] 周卫卫, 陈宝, 郝振邦, 等. Li₂O-Al₂O₃-SiO₂高强度半透光微晶玻璃晶化及机械性能研究[J]. 硅酸盐通报, 2022, 41(11): 3813-3818.
ZHOU W W, CHEN B, HAO Z B, et al. Study on crystallization and mechanical properties of Li₂O-Al₂ O₃-SiO₂ high strength semi-transparent glass-ceramics[J]. Bulletin of the Chinese Ceramic Society, 2022, 41(11): 3813-3818 (in Chinese).
[2] 黄伟胜. 超低膨胀锂铝硅透明微晶玻璃的研究与应用现状[J]. 中国陶瓷工业, 2011, 18(5): 20-23.
HUANG W S. Research and application of lithium aluminosilicate transparent glass-ceramic with zero thermal expansion[J]. China Ceramic Industry, 2011, 18(5): 20-23 (in Chinese).
[3] 殷海荣, 吕承珍, 李阳, 等. 零膨胀锂铝硅透明微晶玻璃的研究与应用现状[J]. 硅酸盐通报, 2008, 27(3): 537-541.
YIN H R, LV C Z, LI Y, et al. Research and application of lithium aluminosilicate transparent glass-ceramic with zero thermal expansion[J]. Bulletin of the Chinese Ceramic Society, 2008, 27(3): 537-541 (in Chinese).
[4] 张巍. 锂霞石应用研究综述[J]. 矿物学报, 2016, 36(1): 80-90.
ZHANG W. A review on research on applications of eucryptite[J]. Acta Mineralogica Sinica, 2016, 36(1): 80-90 (in Chinese).
[5] LUTPI H A, MOHAMAD H, ABDULLAH T K, et al. Effect of isothermal treatment on the structural, microstructure, and physio-mechanical properties of Li₂O-Al₂O₃-SiO₂ glass-ceramic[J]. Journal of the Australian Ceramic Society, 2022, 58(1): 9-20.
[6] GUO X Z, CAI X B, SONG J, et al. Crystallization and microstructure of Li₂O-Al₂O₃-SiO₂ glass-ceramics produced with environmentally acceptable fining agents[J].Journal of the Chinese Ceramic Society(Eng), 2015, 2(2): 91-97.
[7] 沃尔夫拉姆·霍兰,乔治·H.比尔. 微晶玻璃技术[M]. 第2版. 北京: 化学工业出版社, 2019: 71.
WOLFRAM H,GEORGE H B.Glass-ceramic technology[M]. 2nd ed. Beijing:Chemical Industry Press, 2019: 71(in Chinese).
[8] 刘红刚, 平文亮, 李升, 等. 碱金属和碱土金属铝硅酸盐微晶盖板玻璃的研究现状和发展趋势[J]. 硅酸盐通报, 2022, 41(11): 3925-3936.
LIU H G, PING W L, LI S, et al. Research status and development trend of alkali metal and alkaline earth metal aluminosilicate microcrystalline cover glass[J]. Bulletin of the Chinese Ceramic Society, 2022, 41(11): 3925-3936 (in Chinese).
[9] 李溦长, 王欣, 胡丽丽, 等. 高强度Li₂O-Al₂O₃-SiO₂体系微晶玻璃研究进展[J]. 硅酸盐通报, 2022, 41(11): 3795-3805+3825.
LI W C, WANG X, HU L L, et al. Research progress on high-strength Li₂O-Al₂O₃-SiO₂ system glass-ceramics[J]. Bulletin of the Chinese Ceramic Society, 2022, 41(11): 3795-3805+3825 (in Chinese).
[10] DRESSLER M, RÜDINGER B, DEUBENER J. Crystallization kinetics in a lithium alumosilicate glass using SnO₂ and ZrO₂ additives[J]. Journal of Non-Crystalline Solids, 2014, 389: 60-65.
[11] SHAKERI M S. Fabrication, microstructure, and optical properties of nanocrystalline transparent LAST glass ceramics containing CeO₂[J]. International Journal of Minerals, Metallurgy, and Materials, 2014, 21(4): 401-407.
[12] KLEEBUSCH E, PATZIG C, KRAUSE M, et al. The titanium coordination state and its temporal evolution in Li₂O-Al₂O₃-SiO₂ (LAS) glasses with ZrO₂ and TiO₂ as nucleation agents-a XANES investigation[J]. Ceramics International, 2020, 46(3): 3498-3501.
[13] 许小军, 宁青菊, 李艳杰. 晶核剂对LAS微晶玻璃晶化行为的影响[J]. 陶瓷, 2013(3): 9-13.
XU X J, NING Q J, LI Y J. The effect of nucleating agents on crystallization behavior of LAS transparent glass-ceramics[J]. Ceramics, 2013(3): 9-13 (in Chinese).
[14] 殷海荣, 吕承珍, 汪涛, 等. 热处理温度对LAS透明微晶玻璃微观结构的影响[J]. 陕西科技大学学报(自然科学版), 2010, 28(6): 19-22+30.
YIN H R, LV C Z, WANG T, et al. Effect of heat-treatment temperature on the microstructure and properties of Las transparent glass-ceramics[J]. Journal of Shaanxi University of Science & Technology (Natural Science Edition), 2010, 28(6): 19-22+30 (in Chinese).
[15] 王世超,许平西,钟波.锂铝硅微晶玻璃不混溶及其析晶探讨[J].建材发展导向.2021(11):62-63.
WANG S C, XU P X, ZHONG B.Discussion on immiscibility and crystallization of lithium aluminum silicate glass-ceramics[J].Development Guide to Building Materials.2021(11):62-63.
[16] KLEEBUSCH E, PATZIG C, KRAUSE M, et al. The effect of TiO₂ on nucleation and crystallization of a Li₂O-Al₂O₃-SiO₂ glass investigated by XANES and STEM[J]. Scientific Reports, 2018, 8: 2929.
[17] ARVIND A, SARKAR A, SHRIKHANDE V K, et al. The effect of TiO₂ addition on the crystallization and phase formation in lithium aluminum silicate (LAS) glasses nucleated by P₂O₅[J]. Journal of Physics and Chemistry of Solids, 2008, 69(11): 2622-2627.
[18] WU J P, RAWLINGS R D, BOCCACCINI A R, et al. A glass-ceramic derived from high TiO₂-containing slag: microstructural development and mechanical behavior[J]. Journal of the American Ceramic Society, 2006, 89(8): 2426-2433.
[19] 刘丰华, 张海青, 李志祥, 等. 微晶玻璃粉前体、微晶玻璃粉、其制备方法及应用: CN104071985A[P]. 2014-10-01.
LIU F H, ZHANG H Q, LI Z X, et al. Precursor of glass-ceramics powder,glass-ceramics powder,preparation method and application thereof: CN201410332382.8[P]. 2014-10-01.
[20] PASK J A, TOMSIA A P. Formation of mullite from sol-gel mixtures and kaolinite[J]. Journal of the American Ceramic Society, 1991, 74(10): 2367-2373.
[21] BRINKER C J, SCHERER G W, ROTH E P. Sol→gel→glass: ii. Physical and structural evolution during constant heating rate experiments[J]. Journal of Non-Crystalline Solids, 1985, 72(2/3): 345-368.
[22] LEE G S, MESSING G L, DELAAT F G A. Crystallization of sol-gel-derived lithium aluminosilicate (LAS) glass ceramic powders[J]. Journal of Non-Crystalline Solids, 1990, 116(2/3): 125-132.
[23] LIU Z E, SUN Y H, DU X J, et al. Preparation and crystallization of ultrafine Li₂O-Al₂O₃-SiO₂ powders[J]. Journal of Materials Science, 1995, 30(2): 390-394.
[24] 吴松全, 王福平, 何利娜, 等. 聚丙烯酰胺凝胶法制备Li₂O-Al₂O₃-SiO₂微晶玻璃超微粉[J]. 硅酸盐学报, 2004, 32(2): 200-204.
WU S Q, WANG F P, HE L N, et al. Preparation of ultrafine Li₂O-Al₂O₃-SiO₂ glass-ceramic powders by polyacrylamide gel method[J]. Journal of the Chinese Ceramic Society, 2004, 32(2): 200-204 (in Chinese).
[25] 张常建, 肖卓豪, 卢安贤. 透明微晶玻璃的研究现状与展望[J]. 材料导报, 2009, 23(13): 38-43+53.
ZHANG C J, XIAO Z H, LU A X. Investigation progress and application of transparent glass-ceramics[J]. Materials Review, 2009, 23(13): 38-43+53 (in Chinese).
[26] RIELLO P, CANTON P, COMELATO N, et al. Nucleation and crystallization behavior of glass-ceramic materials in the Li₂O-Al₂O₃-SiO₂ system of interest for their transparency properties[J]. Journal of Non-Crystalline Solids, 2001, 288(1/2/3): 127-139.
[27] 范仕刚, 余明清, 赵春霞, 等. 超低膨胀微晶玻璃产业现状及发展趋势[J]. 新材料产业, 2007(7): 57-60.
FAN S G, YU M Q, ZHAO C X, et al. Present situation and development trend of ultra-low expansion glass-ceramics industry[J]. Advanced Materials Industry, 2007(7): 57-60 (in Chinese).
[28] BEALL G H, PINCKNEY L R. Nanophase glass-ceramics[J]. Journal of the American Ceramic Society, 2004, 82(1): 5-16.
[29] ZAWRAH M F, HAMZAWY E M A. Effect of cristobalite formation on sinterability, microstructure and properties of glass/ceramic composites[J]. Ceramics International, 2002, 28(2): 123-130.
[30] 娄广辉, 何峰, 钮峰. Li₂O-Al₂O₃-SiO₂系统微晶玻璃的研究进展[J]. 国外建材科技, 2004, 25(2): 9-12.
LOU G H, HE F, NIU F. Research progress of Li₂O-Al₂O₃-SiO₂ system glass-ceramics[J]. Foreign Building Materials Science and Technology, 2004, 25(2): 9-12 (in Chinese).
[31] 李德培.反射镜用材料及其有关问题[J]. 光仪技术, 1992, 13(4): 32-39.
LI D P. Materials for Reflectors and Related Issues[J]. Optical Instrument Technology,1992, 13(4):32-39 (in Chinese).
[32] 袁剑雄, 曹明. 锂铝硅系微晶玻璃研究与应用现状[J]. 中国陶瓷工业, 2005, 12(6): 29-31.
YUAN J X, CAO M. Research and application prospect of Las glass ceramics[J]. China Ceramic Industry, 2005, 12(6): 29-31 (in Chinese).
[33] 陈雪梅, 莫大洪, 李赛, 等. 零膨胀微晶玻璃晶化工艺研究[J]. 建筑玻璃与工业玻璃. 2022(9): 10-13.
CHEN X M, MO D H, LI S, et al. Research on zero-expansion glass-ceramic crystallization process[J]. Architectural Glass and Functional Glass.2022(9):10-13 (in Chinese).
[34] 范仕刚. 超低膨胀微晶玻璃: 助力空天探测,实现关键材料自主可控[J]. 硅酸盐通报, 2021, 40(11): 3877.
FAN S G. Ultra-low expansion glass-ceramics-help space exploration and realize independent control of key materials[J]. Bulletin of the Chinese Ceramic Society, 2021, 40(11): 3877 (in Chinese).
[35] 赵春霞, 范仕刚, 张丽红, 等. 高品质超低膨胀透明微晶玻璃实现批量化生产[J]. 硅酸盐通报, 2021, 40(9): 3185-3187.
ZHAO C X, FAN S G, ZHANG L H, et al. High quality ultra-low expansion transparent glass-ceramics achieve mass production[J]. Bulletin of the Chinese Ceramic Society, 2021, 40(9): 3185-3187 (in Chinese).
[36] 赵莹, 陆雷, 张乐军, 等. 锂铝硅系统微晶玻璃的析晶及热处理工艺研究[J]. 中国陶瓷, 2007, 43(4): 10-14.
ZHAO Y, LU L, ZHANG L J, et al. Research on crystallization and heat treatment process of Li₂O-Al₂O₃-SiO₂ glass-ceramics[J]. China Ceramics, 2007, 43(4): 10-14 (in Chinese).
[37] 王钦, 王娜, 黄欣, 等. 微晶玻璃研究进展[J]. 无机盐工业, 2022, 54(8): 1-11.
WANG Q, WANG N, HUANG X, et al. Research progress on glass-ceramics[J]. Inorganic Chemicals Industry, 2022, 54(8): 1-11 (in Chinese).
[38] DOEHRING T, HARTMANN P, JEDAMZIK R, et al. Status of ZERODUR mirror blank production at SCHOTT[C]//Optics and Photonics 2005. Proc SPIE 5869, Optical Manufacturing and Testing VI, San Diego, California, USA. 2005, 5869: 5-13.
[39] THORSTEN D. Forty years of zerodur mirror substrates for astronomy review and outlook[J]. Proc. SPIE, 2008: 70183.
[40] HULL T, HARTMANN P, CLARKSON A R, et al. Lightweight high-performance 1-4 meter class spaceborne mirrors: emerging technology for demanding spaceborne requirements[C]//SPIE Proceedings, Modern Technologies in Space- and Ground-based Telescopes and Instrumentation. San Diego, California, USA. SPIE, 2010: 77390.
[41] 刘韬, 周一鸣, 江月松. 国外空间反射镜材料及应用分析[J]. 航天返回与遥感, 2013, 34(5): 90-99.
LIU T, ZHOU Y M, JIANG Y S. Research and application of foreign space mirror materials[J]. Spacecraft Recovery & Remote Sensing, 2013, 34(5): 90-99 (in Chinese).
[42] 佚名, 光之眼: 碳化硅反射镜[J]. 硅酸盐通报, 2020, 39(9): 3043.
ANONYMITY. The eye of light—silicon carbide mirror[J]. Bulletin of the Chinese Ceramic Society, 2020, 39(9): 3043 (in Chinese).
[43] 蒋亚丝. 光学玻璃进展(八): 大型天文望远镜镜坯玻璃[J]. 玻璃与搪瓷, 2018, 46(5): 49-51.
JIANG Y S. Progress in optical glass(8)—glass mirror blank for large astronomic telescope[J]. Glass & Enamel, 2018, 46(5): 49-51 (in Chinese).
[44] 石成利. 透明微晶玻璃的研究与应用现状及其发展趋势[J]. 陶瓷, 2012(8): 44-46.
SHI C L. Research and application status and development trend of transparent glass-ceramics[J]. Ceramics, 2012(8): 44-46 (in Chinese).
[45] 纪鈜腾, 毛元昊, 陈丁博, 等. 激光陀螺原理、现状及展望[J]. 导航与控制, 2022, 21(5-6): 221-240.
JI H T, MAO Y H, CHEN D B, et al. Fundamental principle, current status and prospect of ring laser gyroscope[J]. Navigation and Control, 2022, 21(5-6): 221-240 (in Chinese).
[46] 翟二江, 郭文阁, 徐学东, 等. 大型激光陀螺仪的研究进展[J]. 激光与红外, 2021, 51(6): 705-709.
ZHAI E J, GUO W G, XU X D, et al. Research progress of large laser gyroscope[J]. Laser & Infrared, 2021, 51(6): 705-709 (in Chinese).
[47] 陈福, 桑磊, 高淑兰, 等. Sol-Gel法制备LAS微晶玻璃的研究现状与应用进展[J]. 玻璃, 2009, 36(9): 3-6.
CHEN F, SANG L, GAO S L, et al. Development of LAS system glass-ceramic prepared by sol-gel method[J]. Glass, 2009, 36(9): 3-6 (in Chinese).