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人工晶体学报 ›› 2024, Vol. 53 ›› Issue (5): 818-823.

• 研究论文 • 上一篇    下一篇

TOPCon太阳电池单面沉积Poly-Si的工艺研究

代同光, 谭新, 宋志成, 郭永刚, 袁雅静, 倪玉凤, 汪梁   

  1. 青海黄河上游水电开发有限责任公司西安太阳能电力分公司,西安 710100
  • 收稿日期:2023-09-11 出版日期:2024-05-15 发布日期:2024-05-21
  • 作者简介:代同光(1986—),男,山东省人,工程师。E-mail:tg334334@163.com

Single-Sided Deposition of Poly-Si in TOPCon Solar Cells

DAI Tongguang, TAN Xin, SONG Zhicheng, GUO Yonggang, YUAN Yajing, NI Yufeng, WANG Liang   

  1. Xi’an Solar Power Branch, QingHai Huanghe Hydropower Development Co., Ltd., Xi’an 710100, China
  • Received:2023-09-11 Online:2024-05-15 Published:2024-05-21

摘要: 目前隧穿氧化层钝化接触(TOPCon)电池制造技术越来越成熟,所耗成本不断降低。行业内普遍采用低压化学气相沉积(LPCVD)方式进行双面沉积或单面沉积。单面沉积存在Poly-Si绕镀问题,严重影响电池片转化效率和外观质量,同时正面绕镀层去除难度较大,在用碱溶液去除绕镀层的同时,存在绕镀层去除不彻底或者非绕镀区域P+层被腐蚀的风险,导致P+发射极受损,严重影响电池片外观质量与性能。双面沉积可避免上述问题,但产能减少一半,制造成本增加。本文对单面沉积Poly-Si工艺及绕镀层去除工艺进行研究,在TOPCon电池正面及背面制作了一层合适厚度的氧化层掩膜,搭配合适的清洗工艺、去绕镀清洗工艺,既可有效地去除P+层绕镀的Poly-Si,也可很好地保护正面P+层及背面掺杂Poly-Si层不受破坏,同时可大幅提升产能。

关键词: TOPCon太阳电池, Poly-Si绕镀层, 低压化学气相沉积, BSG, PSG, 腐蚀速率

Abstract: At present, the technology of tunnel oxide passivated contact (TOPCon) solar cells is becoming more and more mature, and the manufacturing cost is decreasing. TOPCon cell technology has been applied in the process of manufacture. Low-pressure chemical vapor deposition (LPCVD) is widely used in the industry for double-sided deposition or single-sided deposition. Single-sided deposition has the problem of Poly-Si winding coating, which seriously affects the efficiency and appearance quality of solar cells. It is difficult to remove the winding coating on the front side. While removing the winding coating in alkali solution, there is a risk of incomplete removal of the winding coating or corrosion risk of P+ layer in non-winding plating area. As a result, the P+ emitter is damaged, which seriously affects the appearance quality and performance of solar cells. Double-sided deposition can avoid the above risks, but the production capacity will be reduced by half, the manufacturing cost will increase. In this paper, the single-sided deposition of Poly-Si process and the removal process of the winding coating were studied. A layer of oxide coating with appropriate thickness is made on the front and back of TOPCon solar cells. With appropriate cleaning process and unwinding plating cleaning process, the Poly-Si winding coated with P+ layer can be effectively removed, and the front P+ layer and the doped Poly-Si layer on the back can be well protected from damage, and the production capacity can be greatly improved.

Key words: TOPCon solar cell, Poly-Si winding coating, low pressure chemical vapor deposition, BSG, PSG, corrosion rate

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