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JOURNAL OF SYNTHETIC CRYSTALS ›› 2017, Vol. 46 ›› Issue (9): 1767-1772.

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Piezoelectrical and Dielectrical Properties of CeO2 Doped KNN-LiNbO3 Based Lead-free Piezoceramics

LI Zhen-yu;GAN Guo-you;XU Teng-wei;GUO Gen-sheng;DU Jing-hong;ZHANG Jia-min;YAN Ji-kang;YI Jian-hong   

  • Online:2017-09-15 Published:2021-01-20

Abstract: Ternary system piezoelectric ceramic materiais 0.98K0.5 Na0.5 NbO3-0.02LiNbO3 -xCeO2 (0. 98KNN-0.02LN+xCeO2 ) were fabricated using solid state sintered technology .The effects of additive contents ranging from 0.00 to 4mol; on structural characteristics and electrical properties of 0.98K0.5 Na0.5 NbO3-0.02LiNbO3 lead-free piezoelectric ceramics doped with CeO 2 were investigated.The crystal structure of the ceramics changes from orthorhombic phase to tetragonal phase when content of CeO 2 change from x =0.00 to x =0.01 and x =0.02 to x =0.04, and the coexistence of orthorhombic-tetragonal phases are observed when x=0.00 and x=0.02.The results show that when adding a small amount of CeO 2 , it show the characteristics of the acceptor doping and when adding amount of CeO 2 , results show the characteristics of the sintering additives .The optimization comprehensive property was at the addition of 2mol;CeO2 sinter temperature 1080℃.The main parameters for the composition of x=0.02 are:d33 =104 pC/N, Qm =2201, kp =0.24423,εr =804.2, tanδ=8.748;.

Key words: Ternary system piezoelectric ceramic materiais 0.98K0.5 Na0.5 NbO3-0.02LiNbO3 -xCeO2 (0. 98KNN-0.02LN+xCeO2 ) were fabricated using solid state sintered technology .The effects of additive contents ranging from 0.00 to 4mol; on structural characteristics and electrical properties of 0.98K0.5 Na0.5 NbO3-0.02LiNbO3 lead-free piezoelectric ceramics doped with CeO 2 were investigated.The crystal structure of the ceramics changes from orthorhombic phase to tetragonal phase when content of CeO 2 change from x =0.00 to x =0.01 and x =0.02 to x =0.04, and the coexistence of orthorhombic-tetragonal phases are observed when x=0.00 and x=0.02.The results show that when adding a small amount of CeO 2 , it show the characteristics of the acceptor doping and when adding amount of CeO 2 , results show the characteristics of the sintering additives .The optimization comprehensive property was at the addition of 2mol;CeO2 sinter temperature 1080℃.The main parameters for the composition of x=0.02 are:d33 =104 pC/N, Qm =2201, kp =0.24423,εr =804.2, tanδ=8.748;.

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