Synthesis, Crystal Structure and Properties of Nickel Coordination Polymer with 1,3,5-Tris(Carboxymethoxyl)Benzene

Abstract

Abstract: A novel metal coordination polymer [Ni(TB)₂(H₂O)₂]_n·2H₂O (H₃TB=1,3,5-tris (carboxymethoxyl)benzene) was constructed under solvothermal conditions, with 1,3,5-tris(carboxymethoxyl)benzene as the directional ligand, reacted with nickel acetate. The structure of polymer was characterized by elemental analysis, IR and X-ray single crystal diffraction. The thermal stability, fluorescence properties and Hirshfeld surface forces were also studied. Single crystal structure analysis show that, the crystal system and space group of the complex is triclinic and $P \overline{1}$. The central ion Ni(Ⅱ) of the complex is six coordinated by with O atoms of carboxylic acid from four different 1,3,5-tris(carboxymethoxyl)benzene ligands, O atoms of two water molecules to give a octahedral geometry NiO₆. A one-dimensional chain configuration with holes is formed by the coordination of oxygen atom with 1,3,5-tris (methoxycarboxyl) benzene. The fluorescence and TG results show that the complex have good fluorescence properties and thermal stability. Hirshfeld surface analysis results reveal that the O…H/H…O interactions is 39.0% contribution to the total Hirshfeld surface of the complex molecules, while H…H and O…O interactions is 25.9% and 13.6%, respectively.

Key words: 1,3,5-tris(carboxymethoxyl)benzene, crystal structure, fluorescence property, thermal stability, Hirshfeld surface

CLC Number:

O641.4

HUANG Qiuping, ZENG Zhenfang, ZHENG Yanfei, LI Lan, HUANG Wei, WEI Youhuan. Synthesis, Crystal Structure and Properties of Nickel Coordination Polymer with 1,3,5-Tris(Carboxymethoxyl)Benzene[J]. JOURNAL OF SYNTHETIC CRYSTALS, 2021, 50(5): 877-883.

References

[1] CHEN G H, LI H Z, HE Y P, et al. Ti₄(embonate)₆ based cage-cluster construction in a stable metal-organic framework for gas sorption and separation[J]. Crystal Growth & Design, 2020, 20(1): 29-32.
[2] ZHANG Y, CHEN Z H, LIU X, et al. Efficient SO₂ removal using a microporous metal-organic framework with molecular sieving effect[J]. Industrial & Engineering Chemistry Research, 2020, 59(2): 874-882.
[3] YANG Y L, ZHONG W, MA R N, et al. Engineering the surface of cuprous oxide via surface coordination for efficient catalysis on aerobic oxidation of benzylic alcohols under ambient conditions[J]. Applied Surface Science, 2021, 543: 148840.
[4] 翟丽军,牛宇岚,郝小艳,等.两个基于π-共轭二羧酸构筑的配位聚合物的晶体结构、磁性及光催化性能[J].无机化学学报,2018,34(10):1936-1942.
ZHAI L J, NIU L Y, HAO X Y, et al. Crystal structures, magnetic property, and photocatalytic activity of two coordination polymers base on π-conjugated benzenedicarboxylic acid[J]. Chinese Journal of Inorganic Chemistry, 2018, 34(10): 1936-1942(in Chinese).
[5] GU J Z, WEN M, CAI Y, et al. Metal-organic architectures assembled from multifunctional polycarboxylates: hydrothermal self-assembly, structures, and catalytic activity in alkane oxidation[J]. Inorganic Chemistry, 2019, 58(4): 2403-2412.
[6] WANG S C, WANG K, KONG X F, et al. DMF as methine source: copper-catalyzed direct annulation of hydrazides to 1, 3, 4-oxadiazoles[J]. Advanced Synthesis & Catalysis, 2019, 361(17): 3986-3990.
[7] ZHANG S H, ZHANG Y D, ZOU H H, et al. A family of cubane cobalt and nickel clusters: syntheses, structures and magnetic properties[J]. Inorganica Chimica Acta, 2013, 396: 119-125.
[8] ZHAO X, WANG S, ZHANG L, et al. 8-hydroxyquinolinate-based metal-organic frameworks: synthesis, tunable luminescent properties, and highly sensitive detection of small molecules and metal ions[J]. Inorganic Chemistry, 2019, 58(4): 2444-2453.
[9] ZHANG S H, WANG J M, ZHANG H Y, et al. Highly efficient electrochemiluminescence based on 4-amino-1, 2, 4-triazole Schiff base two-dimensional Zn/Cd coordination polymers[J]. Dalton Transactions, 2017, 46(2): 410-419.
[10] ZHANG C, XIAO Y, QIN Y, et al. A novel highly efficient adsorbent {[Co₄(L)₂(μ3-OH)₂(H₂O)₃(4, 4′-bipy)₂]·(H₂O)₂}_n: synthesis, crystal structure, magnetic and arsenic (V) absorption capacity[J]. Journal of Solid State Chemistry, 2018, 261: 22-30.
[11] 邱燕璇,朱铭芙,麦映璇,等.一维镉(Ⅱ)配合物[Cd(H₂ASA)₂(H₂O)₂]_n的合成、晶体结构及光致变色性质[J].人工晶体学报,2020,49(7):1258-1263.
QIU Y X, ZHU M F, MAI Y X, et al. Synthesis, crystal structure and photochromic property of a one-dimensional Cd(Ⅱ) complex [Cd(H₂ASA)₂(H₂O)₂]_n[J]. Journal of Synthetic Crystals, 2020, 49(7): 1258-1263(in Chinese).
[12] 战佩英.基于苯并咪唑-5-羧酸和对苯二甲酸配体构筑的二维镉配位聚合物的合成、晶体结构及荧光性质[J].无机化学学报,2014,30(7):1629-1634.
ZHAN P Y. Synthesis, structure and photoluminescent property of one 2D cadmium complex based on 1H-benzimidazole-5-carboxylic acid and 1, 4-benzenedicarboxylic acid[J]. Chinese Journal of Inorganic Chemistry, 2014, 30(7): 1629-1634(in Chinese).
[13] 赵振新,程琪,张浩浩,等.基于5-硝基间苯二甲酸配体的六核Co(Ⅱ)配合物的合成、结构及磁性[J].人工晶体学报,2019,48(11):2092-2098.
ZHAO Z X, CHENG Q, ZHANG H H, et al. Synthesis, structures and magnetic properties of hexanuclear Co(Ⅱ) coordination compounds based on 5-nitroisophthalic acid ligand[J]. Journal of Synthetic Crystals, 2019, 48(11): 2092-2098(in Chinese).
[14] 郑长征,任立娣,丁涛,等.基于柔性芳香羧酸配体的三维镉(Ⅱ)配位聚合物的合成、晶体结构及荧光性质[J].人工晶体学报,2014,43(4):1009-1014.
ZHENG C Z, REN L D, DING T, et al. Synthesis, crystal structure and fluorescence properties of 3D cadmium(Ⅱ) coordination polymer based on flexible aromatic carboxylic acid ligand[J]. Journal of Synthetic Crystals, 2014, 43(4): 1009-1014(in Chinese).
[15] 黎彧,蒋汇锋,成晓玲,等.由含硫二羧酸配体构筑的钴(Ⅱ)和(Ⅱ)锰配位聚合物的合成、晶体结构及光催化性质[J].无机化学学报,2021,37(2):361-367.
LI Y, JIANG H F, CHENG X L, et al. Syntheses, crystal structures, and photocatalytic properties of cobalt(Ⅱ) and manganese(Ⅱ) coordination polymers assembled from 4-((carboxymethyl)thio)benzoic acid[J]. Chinese Journal of Inorganic Chemistry, 2021, 37(2): 361-367(in Chinese).
[16] SHELDRICK G M. A short history of SHELX[J]. Acta Crystallographica Section A Foundations of Crystallography, 2008, 64(1): 112-122.
[17] DOLOMANOV O V, BOURHIS L J, GILDEA R J, et al. OLEX2: a complete structure solution, refinement and analysis program[J]. Journal of Applied Crystallography, 2009, 42(2): 339-341.
[18] 邱东方,郭应臣,冯玉全,等.配合物[M(C₁₄H₁₀N₄)₂·HPO₄]·0.25H₂O(M=Cd,Mn)的水热合成、晶体结构及荧光性质[J].无机化学学报,2010,26(9):1663-1668.
QIU D F, GUO Y C, FENG Y Q, et al. Hydrothermal syntheses, crystal structures and photoluminescence property of complexes [M(C₁₄H₁₀N₄)₂·HPO₄]·0.25H₂O(M=Cd, Mn)[J]. Chinese Journal of Inorganic Chemistry, 2010, 26(9): 1663-1668(in Chinese).
[19] 韩佳星,刘峥,梁楚欣,等.以吡啶-2,5-二羧酸或噻吩-2,5-二羧酸为配体的过渡金属配合物的合成、晶体结构及性质[J].无机化学学报,2019,35(4):605-612.
HAN J X, LIU Z, LIANG C X, et al. Syntheses, crystal structures and properties of transition metal complexes based on pyridine-2, 5-dicarboxylic acid or thiophene-2, 5-dicarboxylic acid ligand[J]. Chinese Journal of Inorganic Chemistry, 2019, 35(4): 605-612(in Chinese).
[20] SPACKMAN M A, JAYATILAKA D. Hirshfeld surface analysis [J]. Cryst Eng Comm, 2009, 11(1): 19-32.
[21] 黄秋萍,曾振芳,黄秋婵,等.一维链状锌配合物的合成、晶体结构及性质研究[J].化学试剂,2020,42(10):1207-1212.
HUANG Q P, ZENG Z F, HUANG Q C, et al. Synthesis, crystal structure and property of one-dimensional chain zinc complex[J]. Chemical Reagents, 2020, 42(10): 1207-1212(in Chinese).