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JOURNAL OF SYNTHETIC CRYSTALS ›› 2023, Vol. 52 ›› Issue (6): 1052-1066.

Special Issue: 半导体薄膜与外延技术

• Novel Thin Film Materials • Previous Articles     Next Articles

Atomic Layer Deposition and Its Impact on Transparent Conductive Films

DUAN Chao1, LI Kun1, GAO Gang1, YANG Lei2, XU Liangge1, HAO Gang1,3, ZHU Jiaqi1,3,4   

  1. 1. National Key Laboratory of Special Environment of Composite Technology, Harbin Institute of Technology, Harbin 150001, China;
    2. Analysis and Testing Center of Harbin Institute of Technology, Harbin 150001, China;
    3. Zhengzhou Research Institute, Harbin Institute of Technology, Zhengzhou 450000, China;
    4. Key Laboratory of Micro-systems and Micro-structures Manufacturing for Ministry of Education, Harbin Institute of Technology, Harbin 150001, China
  • Received:2023-03-31 Online:2023-06-15 Published:2023-06-30

Abstract: As device sizes in the IC industry are getting smaller and surfaces become more complex, more and more requirements are proposed on coatings, and atomic layer deposition has gained widespread attention due to its unique advantages of conformality and self-limiting growth. This paper focuses on atomic layer deposition of transparent conductive films. Firstly, some of the commonly used coating methods are briefly introduced, and details of the atomic layer deposition of thin films are reviewed, including chemical adsorption followed by surface chemical reactions. Two factors influencing the self-limiting growth of atomic layer deposition, namely deposition temperature and precursor gas flow rate, are discussed. Secondly, the morphology and composition of the films prepared by atomic layer deposition are analyzed, and the advantages are strengthened, using indium oxide as a representative example. The optoelectronic properties of some common transparent conductive films prepared by different methods, such as indium oxide, tin oxide, zinc oxide and their doped films are also summarized. Thirdly, the application range of atomic layer deposition are reviewed. It is found that high quality films can be prepared on large size substrates, such as large planar and curvature substrates, with uniform film thickness, good conformality and insignificant changes in film properties. When coating on small size substrates, such as powders, trenches and micro-nano structures, the conformality of atomic layer deposition is still obtained, with uniform film thickness and high quality film. Finally, the advantages of atomic layer deposition for thin films are summarized and its unique potential is discussed.

Key words: atomic layer deposition, transparent conductive film, coating method, morphology, composition, optoelectronic property

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