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JOURNAL OF SYNTHETIC CRYSTALS ›› 2024, Vol. 53 ›› Issue (1): 38-50.

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Interface Defects of Perovskite Solar Cells and Their Suppression Methods

LI Hong1, LIAO Xin1,2, HOU Jing1, XU Zhong1   

  1. 1. College of Vanadium and Titanium, Panzhihua University, Panzhihua 617000, China;
    2. Emergency Rescue Service Center of Panzhihua, Panzhihua 617000, China
  • Received:2023-05-21 Online:2024-01-15 Published:2024-01-15

Abstract: At present, most high-efficiency organic-inorganic halide perovskite (OIHP) solar cells are made of polycrystalline perovskite films, and the surface or grain boundaries of these polycrystalline films often contain a large number of defects. The defects in the OIHP film will lead to non-radiative recombination of photogenerated carriers and induce the decomposition of the OIHP material, resulting in a decrease in the power conversion efficiency (PCE) and stability of the device. In this review, the types of defects in perovskite solar cells and the effects of defects on the performance of perovskite solar cells (PSCs) were analyzed. The progress of passivation of interface defects between electrode and charge transport layer or between charge transport layer and perovskite layer to obtain higher efficiency and stability of perovskite solar cells is introduced in detail. The design ideas of passivation molecules and the challenges facing the commercial application of perovskite photovoltaics are prospected.

Key words: perovskite solar cell, organic-inorganic halide perovskite, interface defect, defect passivation, electron transport layer, hole transport layer, power conversion efficiency

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