A Novel Three-Dimensional Ni (II) Complex: Synthesis, Crystal Structure and Detection for Fe3+, CrO2-4 and Cr2O2-7 in Water

Abstract

Abstract: A novel Ni (II) coordination polymer [Ni(pdc)(bib)(H₂O)]_n(Ni-CP) was synthesised by solvothermal method with 3,5-pyridyl dicarboxylic acid (3,5-H₂pdc), 1, 4-bis (1-imidazolyl) benzene (bib) and Ni(NO₃)₂, and characterized by single-crystal X-ray diffraction, powder X-ray diffraction, thermogravimetric, IR spectroscopic and fluorescence spectroscopy analysis. The results show that Ni-CP crystallized as a monoclinic system with C2/c space group. The asymmetric unit of Ni-CP was comprised of one Ni(II), two half bib ligands, one completely deprotonated 3,5-pdc^2- ligands and one coordinated water molecule. The environment around central Ni(II) can be described as irregular hexacoordination octahedral geometry of NiO₃N₃. The bib and 3,5-pdc^2- ligands were bridged by the bidentate coordination mode in the μ₂-η¹∶η¹ fashion and the tridentate coordination mode in the μ₃-η¹∶η¹∶η¹ fashion to form a three-dimensional network framework. From a topological point of view, the two-dimensional frame structure can be simplified to a 3-connected topology with a Schläfli symbol (4·8²). We consider the 3,5-pdc^2- ligands and Ni(II) as nodes and the bib ligands as connectors, forming a three-dimensional structure can be simplified to a 3,5-connected double nodes with topological symbols (4·6·8)(4·6²·8⁷). The porosity of Ni-CP is 17.4%. Ni-CP could selectively detect Fe³⁺, CrO^2-₄ and Cr₂O^2-₇ with detection limits of 4.275×10^-5, 2.681×10^-5, 2.681×10^-5 mol/L, respectively, and have a high quenching rate.

Key words: nickel(Ⅱ) complex, solvothermal method, crystal structure, topological structure, luminescence property, porosity

CLC Number:

AN Hangyi, HUANG Yanxi, WANG Airong, WANG Xiaoli, LI Jiaming, SHI Zhongfeng. A Novel Three-Dimensional Ni (II) Complex: Synthesis, Crystal Structure and Detection for Fe³⁺, CrO^2-₄ and Cr₂O^2-₇ in Water[J]. JOURNAL OF SYNTHETIC CRYSTALS, 2024, 53(9): 1599-1607.

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A Novel Three-Dimensional Ni (II) Complex: Synthesis, Crystal Structure and Detection for Fe³⁺, CrO^2-₄ and Cr₂O^2-₇ in Water

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