Two Supra Molecular Co(Ⅱ) Coordination Polymers Based on 2,5-Dimethoxyterephthalic Acid and Imidazole Derivatives: Crystal Structures and Photo-Catalytic Reactions

Abstract

Abstract: Two cobalt coordination polymers, namely{[Co(DTA) (1,4-DIB)(H₂O)]·H₂O}_n (1) and [Co(DTA)(1,3-BMIB)]_n(2) were constructed by 2,5-dimethoxyterephthalic acid (H₂DTA), Co(Ⅱ) ions and different imidazole derivatives 1,4-di(1H-imidazol-1-yl)benzene (1,4-DIB) and 1,3-bis(4-methyl-1H- imidazol-1-yl)benzene (1,3-BMIB) under hydrothermal reaction, respectively. Complexes 1 and 2 were characterized by single-crystal X-ray diffraction, powder X-ray diffraction, elemental analysis, thermo-gravimetric analysis and UV-Vis spectra. Single-crystal X-ray diffraction reveals that complexes 1 and 2 are three-dimensional supra molecular frameworks packed by two-dimensional layers. The powder X-ray diffraction confirms that complexes 1 and 2 are stable in water under UV light. The UV-Vis spectra indicate that complexes 1 and 2 are semiconductors with high absorbing ability for UV-Vis light. Photocatalytic tests further confirm the complex 1 and 2 have catalytic activity for the degradation of methylene blue (MB) in water.

Key words: Co(Ⅱ)-complex, three-dimensional supra-molecular structure, photo-catalytic activity, degradation, 2,5-dimethoxyterephthalic acid, imidazole derivative

CLC Number:

O641.4

SHI Mingfeng, GU Jianghong, LU Senyuan, XU Zhongxuan. Two Supra Molecular Co(Ⅱ) Coordination Polymers Based on 2,5-Dimethoxyterephthalic Acid and Imidazole Derivatives: Crystal Structures and Photo-Catalytic Reactions[J]. JOURNAL OF SYNTHETIC CRYSTALS, 2022, 51(3): 485-492.

References

[1] STOCK N, BISWAS S. Synthesis of metal-organic frameworks (MOFs): routes to various MOF topologies, morphologies, and composites[J]. Chemical Reviews, 2012, 112(2): 933-969.
[2] DING M, YANG L M, ZENG J H, et al. Orderly MOF-assembled hybrid monolithic stationary phases for nano-flow HPLC[J]. Analytical Chemistry, 2020, 92(24): 15757-15765.
[3] WEI Y S, ZHANG M, ZOU R Q, et al. Metal-organic framework-based catalysts with single metal sites[J]. Chemical Reviews, 2020, 120(21): 12089-12174.
[4] CHAKRABORTY G, PARK I H, MEDISHETTY R, et al. Two-dimensional metal-organic framework materials: synthesis, structures, properties and applications[J]. Chemical Reviews, 2021, 121(7): 3751-3891.
[5] VAN VLEET M J, WENG T T, LI X Y, et al. In situ, time-resolved, and mechanistic studies of metal-organic framework nucleation and growth[J]. Chemical Reviews, 2018, 118(7): 3681-3721.
[6] 黎彧,庄映芬,张艳来,等.由2,3-二羟基-对苯二甲酸配体构筑的锰(Ⅱ)和镉(Ⅱ)配位聚合物的合成、晶体结构、荧光及催化性质(英文)[J].无机化学学报,2021,37(6):1135-1142.
LI Y, ZHUANG Y F, ZHANG Y L, et al. Syntheses, crystal structures, luminescence and catalytic activity of manganese(Ⅱ) and cadmium(Ⅱ) coordination polymers based on 2, 3-dihydroxy-terephthalic acid[J]. Chinese Journal of Inorganic Chemistry, 2021, 37(6): 1135-1142.
[7] 刘朋,陈洪霞.两例相同混合配体构筑的Pb(Ⅱ)/Ag(Ⅰ)配位聚合物及其荧光性质[J].人工晶体学报,2021,50(8):1444-1451.
LIU P, CHEN H X. Two Pb(Ⅱ)/Ag(Ⅰ) coordination polymers constructed by the same mixed ligand and their fluorescence properties[J]. Journal of Synthetic Crystals, 2021, 50(8): 1444-1451(in Chinese).
[8] GETMAN R B, BAE Y S, WILMER C E, et al. Review and analysis of molecular simulations of methane, hydrogen, and acetylene storage in metal-organic frameworks[J]. Chemical Reviews, 2012, 112(2): 703-723.
[9] 张阳,王键.基于5-甲氧基间苯二甲酸构筑的两个金属配位聚合物:晶体结构、荧光和催化性质(英文)[J].无机化学学报,2018,34(3):589-596.
ZHANG Y, WANG J. Construction of two coordination polymers based on 5-methoxyisophthalic acid ligand: structures, luminescence and catalytic properties[J]. Chinese Journal of Inorganic Chemistry, 2018, 34(3): 589-596.
[10] 徐中轩,陈雪婷,徐仕菲,等.基于半刚性对映配体的螺旋单一手性配位聚合物[J].吉林大学学报(理学版),2021,59(2):415-420.
XU Z X, CHEN X T, XU S F, et al. Homochiral coordination polymers based on semirigid enantiomers[J]. Journal of Jilin University (Science Edition), 2021, 59(2): 415-420(in Chinese).
[11] 梁姗姗,张慧,郭京京,等.双联咪唑和对苯二甲酸构筑的二重穿插锌(Ⅱ)配位聚合物｛[Zn(bbi)(tpa)]_n｝的合成及其荧光性能[J].合成化学,2016,24(5):384-388.
LIANG S S, ZHANG H, GUO J J, et al. Synthesis and luminescent property of Zn(Ⅱ) coordination polymer constructed by bisimidazole and terephthalic acid[J]. Chinese Journal of Synthetic Chemistry, 2016, 24(5): 384-388(in Chinese).
[12] SCHWEDLER I, HENKE S, WHARMBY M T, et al. Mixed-linker solid solutions of functionalized pillared-layer MOFs - adjusting structural flexibility, gas sorption, and thermal responsiveness[J]. Dalton Transactions, 2016, 45(10): 4230-4241.
[13] CUI Y J, XU H, YUE Y F, et al. A luminescent mixed-lanthanide metal-organic framework thermometer[J]. Journal of the American Chemical Society, 2012, 134(9): 3979-3982.
[14] DOLOMANOV O V, BOURHIS L J, GILDEA R J, et al. OLEX2: a complete structure solution, refinement and analysis program[J]. Journal of Applied Crystallography, 2009, 42(2): 339-341.
[15] SHELDRICK G M. Crystal structure refinement with SHELXL[J]. Acta Crystallographica Section C, Structural Chemistry, 2015, 71(Pt 1): 3-8.
[16] DHARMARAJA C, NICHOLAS P E, RAMYA P, et al. Investigation on photocatalytic activity of ZnS/NiFe₂O₄ NCs under sunlight irradiation via a novel two-step synthesis approach[J]. Inorganic Chemistry Communications, 2021, 126: 108481.
[17] MENG X M, FAN C B, BI C F, et al. Syntheses, structural diversity and photocatalytic properties of various Co(Ⅱ) coordination polymers based on a “V”-shaped 1, 3-di(4'-carboxyl-phenyl)benzene acid and different imidazole bridging ligands[J]. Cryst Eng Comm, 2016, 18(16): 2901-2912.