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人工晶体学报 ›› 2007, Vol. 36 ›› Issue (5): 1136-1141.

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CTAB与SDBS对碳酸锶粒子生长形态调控及机理研究

张明轩;霍冀川;王海滨;刘树信;雷永林;崔彩萍   

  1. 西南科技大学应用化学研究所,绵阳,621010;绵阳师范学院,绵阳,621002
  • 出版日期:2007-10-15 发布日期:2021-01-20
  • 基金资助:
    the Key Scientific and Technological Project of Sichuan Province(03GG021-002)

Regulation and Mechanism of CTAB and SDBS on SrCO3 Particles Morphology

ZHANG Ming-xuan;HUO Ji-chuan;WANG Hai-bin;LIU Shu-xin;LEI Yong-lin;CUI Cai-ping   

  • Online:2007-10-15 Published:2021-01-20

摘要: 以表面活性剂CTAB和SDBS为化学添加剂,采用化学共沉淀法对碳酸锶晶体的生长形态进行调控,成功地制备出了实心的树枝状和花瓣为空心的花状碳酸锶粉体,并用X射线衍射(XRD)、扫描电子显微镜(SEM)和傅里叶变换红外光谱(FT-IR)等分析手段对样品进行了表征;最后重点对化学添加剂可能产生的影响机理进行了初步的探讨.结果表明,CTAB和SDBS在晶体生长的过程中能起到显著的影响作用,两者对粒子分散性能的作用效果相反,而且后者对晶体(013)和(213)晶面表面能降低的贡献明显大于前者.

关键词: SrCO3;生长形态;化学添加剂;树枝状;花状;CTAB;SDBS;机理

Abstract: Solid dendritic and hollow flower-like SrCO3 particles have been synthesized via adding suffactants CTAB and SDBS as chemical additives to regulate the morphology of the crystal. The samples were characterized by X-ray diffraction (XRD), scanning electronic microscope (SEM) and Fourier transform infrared spectrograph (FT-IR); the preliminary effect mechanisms of chemical additives to SrCO3 crystal have been discussed chiefly in the end. Results show that CTAB and SDBS could play a significant role in influencing the particles' property, which take an opposite action to the property of the particles'dispersion and the latter has a stronger ability in reducing the surface energy of the (013) and (213) crystal faces than the former.

Key words: Solid dendritic and hollow flower-like SrCO3 particles have been synthesized via adding suffactants CTAB and SDBS as chemical additives to regulate the morphology of the crystal. The samples were characterized by X-ray diffraction (XRD), scanning electronic microscope (SEM) and Fourier transform infrared spectrograph (FT-IR); the preliminary effect mechanisms of chemical additives to SrCO3 crystal have been discussed chiefly in the end. Results show that CTAB and SDBS could play a significant role in influencing the particles' property, which take an opposite action to the property of the particles'dispersion and the latter has a stronger ability in reducing the surface energy of the (013) and (213) crystal faces than the former.

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