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人工晶体学报 ›› 2009, Vol. 38 ›› Issue (5): 1059-1062.

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Li_(0.067)Na_(0.933)Tb(MoO_4)_2磁光晶体的生长与磁光性能

郭飞云;庄乃锋;赵斌;陈建中   

  1. 福州大学化学化工学院,福州,350002
  • 出版日期:2009-10-15 发布日期:2021-01-20
  • 基金资助:
    国家自然科学基金(50772023);福建省自然科学基金(2007J0148);国家光电子晶体材料研究中心开放基金(2005DC105003)

Growth and Magneto-optical Properties of Li_(0.067)Na_(0.933)Tb(MoO_4)_2 Crystal

GUO Fei-yun;ZHUAGN Nai-feng;ZHAO Bin;CHEN Jian-zhong   

  • Online:2009-10-15 Published:2021-01-20

摘要: 采用Czochralski法生长了Li_(0.067)Na_(0.933)Tb(MoO_4)_2晶体,并测试了Li~+在NaTb(MoO_4)_2晶体中的有效分凝系数.由粉末X射线衍射数据计算了晶体的晶胞参数.室温下,采用消光法测试了Li_(0.063)Na_(0.933)Tb(MoO_4)_2晶体在532 nm、633 nm和1064 nm处的费尔德常数,分别为-293.6 rad·m~(-1)·T~(-1)、-200.5 rad·m~(-1)·T~(-1)和-68.6 rad·m~(-1)·T~(-1),与纯NaTb(MoO_4)_2相比,其费尔德常数均有所增加.结果表明,在1064 nm处Li_(0.067)Na_(0.933)Tb(MoO_4)_2晶体有较高的磁光优值.

关键词: 磁光晶体;提拉法;费尔德常数;磁光优值

Abstract: Li_(0.067)Na_(0.933)Tb(MoO_4)_2 magneto-optical crystal was grown by the Czochralski method. The effective segregation coefficient of Li~+ in NaTb(MoO_4)_2 was measured. The lattice parameters of the crystal were determined by XRD data. Verdet constants of Li 0.067Na0.933Tb(MoO4)2 crystal at the wavelength 532 nm, 633 nm and 1064 nm were investigated by the extinction method at room temperature. They are -293.6 rad·m~(-1)·T~(-1),-200.5 rad·m~(-1)·T~(-1) and -68.6 rad·m~(-1)·T~(-1), respectively, and are larger than that of pure NaTb(MoO_4)_2 at corresponding wavelengths. The results showed that Li_(0.067)Na_(0.933)Tb(MoO_4)_2 has a larger magneto-optical figure of merit at 1064 nm wavelength.

Key words: Li_(0.067)Na_(0.933)Tb(MoO_4)_2 magneto-optical crystal was grown by the Czochralski method. The effective segregation coefficient of Li~+ in NaTb(MoO_4)_2 was measured. The lattice parameters of the crystal were determined by XRD data. Verdet constants of Li 0.067Na0.933Tb(MoO4)2 crystal at the wavelength 532 nm, 633 nm and 1064 nm were investigated by the extinction method at room temperature. They are -293.6 rad·m~(-1)·T~(-1),-200.5 rad·m~(-1)·T~(-1) and -68.6 rad·m~(-1)·T~(-1), respectively, and are larger than that of pure NaTb(MoO_4)_2 at corresponding wavelengths. The results showed that Li_(0.067)Na_(0.933)Tb(MoO_4)_2 has a larger magneto-optical figure of merit at 1064 nm wavelength.

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