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人工晶体学报 ›› 2009, Vol. 38 ›› Issue (5): 1211-1215.

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均相共沉淀法制备氧化锌基红色荧光粉

胡文远;刘勋;杨定明;魏贤华   

  1. 西南科技大学材料科学与工程学院,绵阳,621010
  • 出版日期:2009-10-15 发布日期:2021-01-20
  • 基金资助:
    国家自然科学基金(50802078);西南科技大学青年预研基金(06ZX3129)

Preparation of ZnO Nano-phosphor Powders by Homogeneous Co-precipitation Method

HU Wen-yuan;LIU Xun;YANG Ding-ming;WEI Xian-hua   

  • Online:2009-10-15 Published:2021-01-20

摘要: 以Zn(NO_3)_2·2H_2O、CO(NH_2)_2 、Eu(NO_3)_3·6H_2O和LiNO_3·2H_2O为原料,采用均相共沉淀制备了粒径为20~40 nm的Eu,Li共掺的纳米ZnO荧光粉,用SEM、XRD、TG-DSC、FL等检测手段对样品进行了表征.结果表明:样品的荧光性能与热处理温度及Eu,Li的掺杂比例密切相关,掺杂的ZnO荧光粉呈现出Eu的特征发射,其发射主峰位于611 nm处.

关键词: 均相共沉淀;ZnO;纳米;荧光

Abstract: The nano-phosphor powders of Eu, Li co-doped ZnO were prepared by homogeneous co-precipitation and thermal decomposition method using Zn(NO_3)_2·2H_2O,CO(NH_2)_2,Eu(NO_3)_3·6H_2O and LiNO_3·2H_2O as raw materials. The characteristics of samples were investigated by means of TG-DSC, XRD, SEM, FL. The results showed that the samples exhibited normal size distribution, whose size was about 20~40 nm. The photoluminescence intensity of samples was interrelated with thermal decomposition temperature, ratio of Li and Eu. The maximum emission spectra peak of samples was at λ_(em)=611 nm with 463 nm excitation, corresponding to ~5D_0→~7F_2 transition of Eu.

Key words: The nano-phosphor powders of Eu, Li co-doped ZnO were prepared by homogeneous co-precipitation and thermal decomposition method using Zn(NO_3)_2·2H_2O,CO(NH_2)_2,Eu(NO_3)_3·6H_2O and LiNO_3·2H_2O as raw materials. The characteristics of samples were investigated by means of TG-DSC, XRD, SEM, FL. The results showed that the samples exhibited normal size distribution, whose size was about 20~40 nm. The photoluminescence intensity of samples was interrelated with thermal decomposition temperature, ratio of Li and Eu. The maximum emission spectra peak of samples was at λ_(em)=611 nm with 463 nm excitation, corresponding to ~5D_0→~7F_2 transition of Eu.

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