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人工晶体学报 ›› 2017, Vol. 46 ›› Issue (10): 1923-1929.

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泡沫镍负载Ag/MoO2直接电极的制备及其电化学性能

祁琰媛;郑申波;杨雪;周博;周洋;周静   

  1. 武汉理工大学材料研究与测试中心,武汉430070;武汉理工大学材料科学与工程学院,材料复合新技术国家重点实验室,武汉430070;武汉理工大学材料科学与工程学院,材料复合新技术国家重点实验室,武汉430070
  • 出版日期:2017-10-15 发布日期:2021-01-20
  • 基金资助:
    国家自然科学基金(51506155)

Synthesis and Electrochemical Properties of Ag/MoO2 Anchored on Ni Foam as Binder-Free Anode for Lithium Ion Batteries

QI Yan-yuan;ZHENG Shen-bo;YANG Xue;ZHOU Bo;ZHOU Yang;ZHOU Jing   

  • Online:2017-10-15 Published:2021-01-20

摘要: 采用水热法制备了不同Ag修饰量的Ag/MoO2纳米复合材料,并利用浸渍法将其负载在多孔泡沫镍(Nickel foam,NF)上制备成Ag/MoO2/NF无粘结剂型直接电极.在该电极中Ag/MoO2纳米颗粒均匀地负载在泡沫镍上形成了三维网络结构,其中MoO2纳米颗粒是由~10 nm的纳米晶组成.当Ag修饰量为5;时,Ag0.05/MoO2/NF具有最佳的电化学性能:在0.1 C的电流密度下,首次放电比容量高达1180 mAh/g,100次循环后仍保持805 mAh/g;且当电流密度由2 C降低至0.1 C时,比容量由468 mAh/g升高至820 mAh/g,表现出优异的储锂性能.

关键词: MoO2;水热法;Ag修饰;泡沫镍;锂离子电池;直接电极

Abstract: Ag/MoO2 nanocomposites with different Ag contents were synthesized by hydrothermal method , which were anchored on the porous Ni foam to prepare Ag/MoO2/NF as binder-free electrode via the dip-coating method .It was found that Ag/MoO2 nanocomposites consisted of many -10 nm nanocrystals were uniformly loaded on Ni foam with 3D network structure.When the Ag content is 5;, Ag0.05/MoO2/NF electrode has the optimal electrochemical properties .The initial discharge capacity is 1180 mAh/g at a current density of 0.1 C.It was worth noting that the discharge capacity still retains 805 mAh/g after 100 cycles.when the current density return to 0.1 C from 2 C (468 mAh/g), Ag0.05/MoO2/NF electrode delivers a high capacity of 820 mAh/g, indicating excellent lithium storage performance .

Key words: Ag/MoO2 nanocomposites with different Ag contents were synthesized by hydrothermal method , which were anchored on the porous Ni foam to prepare Ag/MoO2/NF as binder-free electrode via the dip-coating method .It was found that Ag/MoO2 nanocomposites consisted of many -10 nm nanocrystals were uniformly loaded on Ni foam with 3D network structure.When the Ag content is 5;, Ag0.05/MoO2/NF electrode has the optimal electrochemical properties .The initial discharge capacity is 1180 mAh/g at a current density of 0.1 C.It was worth noting that the discharge capacity still retains 805 mAh/g after 100 cycles.when the current density return to 0.1 C from 2 C (468 mAh/g), Ag0.05/MoO2/NF electrode delivers a high capacity of 820 mAh/g, indicating excellent lithium storage performance .

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