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人工晶体学报 ›› 2017, Vol. 46 ›› Issue (2): 338-343.

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多孔镁基板上纳米厚度氢氧化镁叠片的水热合成研究

赵欣;李梦   

  1. 中国民用航空飞行学院,广汉,618307
  • 出版日期:2017-02-15 发布日期:2021-01-20
  • 基金资助:
    Science and Technology Innovation Guide Funds of Civil Aviation Bureau of China(20150212)

Synthesis of Interconnected Nanometer Thick Magnesium Hydroxide Platelets on Porous Magnesium Substrate by Hydrothermal Method

ZHAO Xin;LI Meng   

  • Online:2017-02-15 Published:2021-01-20

摘要: 通过水热法在烧结的多孔镁基板上制备了纳米厚度的氢氧化镁(Mg(OH)2)叠片.分别用SEM及XRD表征了水热合成过程中基板的形貌和物相变化.结果表明,将水热合成的反应时间控制在20 ~ 40 min之内,可以制备出具有100 nm左右厚度的、不同紧密程度的Mg(OH)2叠片.水热合成的反应时间超过40 min,Mg(OH)2叠片将会逐渐从基板表面生长合并为块状晶体.同时,对水热反应过程中氢氧化镁晶体的形核和长大机理进行了探讨.

关键词: 氢氧化镁;水热法;烧结多孔镁基板;花朵状聚集体

Abstract: Interconnected nanometer thick platelets of magnesium hydroxide (Mg (OH) 2) were prepared on a sintered porous magnesium substrate by a hydrothermal method.Morphology and phase evolutions of the substrates during the reaction are investigated using scanning electron microscope (SEM) and X-ray diffraction (XRD).The results show that different denseness levels of interconnected magnesium hydroxide platelets with thicknesses of ~ 100 nm can be obtained by controlling the reaction time of the hydrothermal process within 20-40 min.Interconnected magnesium hydroxide platelets will grow and merge gradually into bulk crystal from the surface of the substrate.The nucleation and crystal growth mechanism of Mg(OH)2 during the hydrothermal reaction were discussed as well.

Key words: Interconnected nanometer thick platelets of magnesium hydroxide (Mg (OH) 2) were prepared on a sintered porous magnesium substrate by a hydrothermal method.Morphology and phase evolutions of the substrates during the reaction are investigated using scanning electron microscope (SEM) and X-ray diffraction (XRD).The results show that different denseness levels of interconnected magnesium hydroxide platelets with thicknesses of ~ 100 nm can be obtained by controlling the reaction time of the hydrothermal process within 20-40 min.Interconnected magnesium hydroxide platelets will grow and merge gradually into bulk crystal from the surface of the substrate.The nucleation and crystal growth mechanism of Mg(OH)2 during the hydrothermal reaction were discussed as well.

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