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人工晶体学报 ›› 2017, Vol. 46 ›› Issue (9): 1653-1659.

• •    下一篇

Cr,Nd:GSAG晶体生长、光谱及LD泵浦激光性能研究

许晋瑞;张庆礼;彭方;王小飞;窦仁勤;罗健乔;孙贵花;丁守军;孙敦陆   

  1. 中国科学院合肥物质科学研究院,安徽光学精密机械研究所,安徽省光子器件与材料重点实验室,合肥 230031;中国科学技术大学,合肥230026;中国科学院合肥物质科学研究院,安徽光学精密机械研究所,安徽省光子器件与材料重点实验室,合肥 230031
  • 出版日期:2017-09-15 发布日期:2021-01-20
  • 基金资助:
    国家自然科学基金(51502292,61405206)

Growth, Spectral Properties and LD Pumped Laser Performances of Cr,Nd:GSAG Crystal

XU Jin-rui;ZHANG Qing-li;PENG Fang;WANG Xiao-fei;DOU Ren-qin;LUO Jian-qiao;SUN Gui-hua;DING Shou-jun;SUN Dun-lu   

  • Online:2017-09-15 Published:2021-01-20

摘要: Cr,Nd:GSAG是一种性能优良的激光晶体,但是关于它的LD泵浦激光性能的研究很少.用提拉法生长了Cr,Nd:GSAG晶体,测定了它的化学成分、结构,初步测试了它的激光性能.晶体的(111)面X射线摇摆曲线半高全宽为0.055°.采用Rietveld方法精修X射线粉末衍射谱得到了Cr,Nd:GSAG晶体的原子结构参数、温度因子等.Cr,Nd:GSAG的最强吸收峰位于808.6nm处,吸收截面为3.38×10-20cm2.808nm光激发下,Cr,Nd:GSAG的最强发射峰位于1060nm,发射截面为6.04×10-20cm2,并测得激光上能级4F3/2的荧光寿命为274μs.利用808nm连续波LD泵浦实现了1060nm的激光输出,在输入功率为8.88W时,最大输出功率为0.513W,斜效率为6.73;,光-光转换效率为5.78;.此外还讨论了Cr,Nd:GSAG晶体中的Cr3+与Nd3+之间的能量传递机理.

关键词: Cr,Nd:GSAG晶体;光谱;LD泵浦

Abstract: Cr,Nd:GSAG is one type of laser crystal with high performances , but there are few research on its lasing properties by LD pumping .In this work, a Cr,Nd:GSAG crystal was grown by Czochralaki method , its chemical composition , structure and lasing performances were investigated .By measuring the X-ray rocking curve of (111) crystallographic plane of Cr ,Nd:GSAG crystal, the full at half maximum ( FWHM) of the diffraction peak is 0.055°.Its atomic structural parameters and temperature factors were obtained by Rietveld refinement to X-ray diffraction data .The strongest absorption peak of Cr ,Nd:GSAG crystal locates at 808.6 nm and the absorption cross section is 3.38 ×10 -20 cm2 .The strongest emission peak of Cr ,Nd:GSAG crystal under 808 nm excitation locates at 1060 nm and the stimulated emission cross section is 6.04 ×10 -20 cm2 .The fluorescence lifetime of laser upper level 4 F3/2 was measured to be 274 μs.A 1060 nm laser output was achieved by 808 nm LD pumping in the continuous-wave mode .The maximum output power of 0.513 W is obtained with an incident pump power of 8.88 W, corresponding to a slope efficiency of 6.73; and an optical-to-optical conversion efficiency of 5.78;.Besides, energy transfer mechanism between Cr 3+and Nd3+in Cr,Nd:GSAG crystal was discussed .

Key words: Cr,Nd:GSAG is one type of laser crystal with high performances , but there are few research on its lasing properties by LD pumping .In this work, a Cr,Nd:GSAG crystal was grown by Czochralaki method , its chemical composition , structure and lasing performances were investigated .By measuring the X-ray rocking curve of (111) crystallographic plane of Cr ,Nd:GSAG crystal, the full at half maximum ( FWHM) of the diffraction peak is 0.055°.Its atomic structural parameters and temperature factors were obtained by Rietveld refinement to X-ray diffraction data .The strongest absorption peak of Cr ,Nd:GSAG crystal locates at 808.6 nm and the absorption cross section is 3.38 ×10 -20 cm2 .The strongest emission peak of Cr ,Nd:GSAG crystal under 808 nm excitation locates at 1060 nm and the stimulated emission cross section is 6.04 ×10 -20 cm2 .The fluorescence lifetime of laser upper level 4 F3/2 was measured to be 274 μs.A 1060 nm laser output was achieved by 808 nm LD pumping in the continuous-wave mode .The maximum output power of 0.513 W is obtained with an incident pump power of 8.88 W, corresponding to a slope efficiency of 6.73; and an optical-to-optical conversion efficiency of 5.78;.Besides, energy transfer mechanism between Cr 3+and Nd3+in Cr,Nd:GSAG crystal was discussed .

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