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人工晶体学报 ›› 2017, Vol. 46 ›› Issue (9): 1798-1802.

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C3N4-CaTi2O4(OH)2复合粉体的溶剂热制备及光催化性能

董伟霞;包启富;严常青;邱柏欣;章丝丝   

  1. 景德镇陶瓷大学材料科学与工程学院,景德镇,333403
  • 出版日期:2017-09-15 发布日期:2021-01-20
  • 基金资助:
    国家自然青年科学基金(51502119);江西省重大自然科学基金(20152ACB21022,20161BBH80048);江西省教育厅项目(GJJ14629)

Solverthermal Preparation of C3N4-CaTi2O4(OH)2 Powder and Its Photocatalytic Properties

DONG Wei-xia;BAO Qi-fu;YAN Chang-qing;QIU Bo-xin;ZHANG Si-si   

  • Online:2017-09-15 Published:2021-01-20

摘要: 利用无水氯化钙-钛酸四正丁酯-无水乙醇体系,通过加入一定摩尔配比的C3N4粉体用溶剂热法制备了C3N4-CaTi2O4(OH)2复合材料粉体.利用X射线衍射(XRD),比表面积(BET)和扫描电子显微镜(SEM)对样品的显微结构进行检测分析,并利用紫外-可见吸收光度计分析了样品对光的吸收特性,研究不同摩尔配比的C3N4粉体复合量对CaTi2O4(OH)2样品的物相结构、微观形貌以及其光催化性能的影响,并考察了不同光源对所制备样品性能的影响.实验结果表明:C3N4粉体的引入显著提高了CaTi2O4(OH)2样品的光催化活性,且当CaTi2O4(OH)2:C3N4物质的量之比为1:0.75时,复合样品的光催化降解率在250nm光源照射下K可达到最大值0.02338min-1.

关键词: C3N4-CaTi2O4(OH)2复合材料;溶剂热法;光催化性能

Abstract: C3 N4-CaTi2 O4 ( OH) 2 composite powders were prepared by the addition of a certain molar ratio of C3 N4 powder using anhydrous calcium chloride-TBOT-anhydrous ethanol system by solvothermal method.The microstructure of the samples were characterized by X-ray diffraction ( XRD ) , specific surface area ( BET ) and scanning electron microscopy ( SEM ) .And the absorption properties of the samples were analyzed by ultraviolet-visible absorption spectrophotometer .Effects of different C 3 N4 composite on phase , microstructure and photocatalytic properties of CaTi 2 O4 ( OH ) 2 samples were studied.The experimental results show that: the introduction of C 3 N4 powder significantly enhance the photocatalytic activity of CaTi 2 O4 ( OH ) 2 samples and the sample has the highest photocatalytic performance(K=0.02338 min-1) in 250 nm when CaTi2O4(OH)2:C3N4 composite molar ratio is 1:0.75.

Key words: C3 N4-CaTi2 O4 ( OH) 2 composite powders were prepared by the addition of a certain molar ratio of C3 N4 powder using anhydrous calcium chloride-TBOT-anhydrous ethanol system by solvothermal method.The microstructure of the samples were characterized by X-ray diffraction ( XRD ) , specific surface area ( BET ) and scanning electron microscopy ( SEM ) .And the absorption properties of the samples were analyzed by ultraviolet-visible absorption spectrophotometer .Effects of different C 3 N4 composite on phase , microstructure and photocatalytic properties of CaTi 2 O4 ( OH ) 2 samples were studied.The experimental results show that: the introduction of C 3 N4 powder significantly enhance the photocatalytic activity of CaTi 2 O4 ( OH ) 2 samples and the sample has the highest photocatalytic performance(K=0.02338 min-1) in 250 nm when CaTi2O4(OH)2:C3N4 composite molar ratio is 1:0.75.

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