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人工晶体学报 ›› 2023, Vol. 52 ›› Issue (10): 1733-1744.

• 综合评述 •    下一篇

半导体用大尺寸单晶金刚石衬底制备及加工研究现状

刘俊杰1,2, 关春龙1, 易剑2, 宋惠2, 江南2, 西村一仁2   

  1. 1.河南工业大学材料科学与工程学院,郑州 450001;
    2.中国科学院宁波材料技术与工程研究所,海洋材料及相关技术重点实验室,浙江省海洋材料与防护技术重点实验室,宁波 315201
  • 收稿日期:2023-05-09 发布日期:2023-10-18
  • 通信作者: 关春龙,博士,副教授。E-mail:chunlong_guan@haut.edu.cn。易剑,博士,高级工程师。E-mail:yijian@nimte.ac.cn。
  • 作者简介:刘俊杰(1999—),男,河南省人,硕士研究生。E-mail:liujunjie@nimte.ac.cn
  • 基金资助:
    宁波市重大科技攻关项目(2021ZDYF020196,2021ZDYF020198);中国科学院青年基金(JCPYJJ-22030)

Research Status of Preparation and Processing of Large-Size Single Crystal Diamond Substrates for Semiconductors

LIU Junjie1,2, GUAN Chunlong1, YI Jian2, SONG Hui2, JIANG Nan2, KAZUHITO Nishimura2   

  1. 1. School of Materials Science and Engineering, Henan University of Technology, Zhengzhou 450001, China;
    2. Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Key Laboratory of Marine Materials and Related Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China
  • Received:2023-05-09 Published:2023-10-18

摘要: 单晶金刚石具有超宽的禁带宽度、低的介电常数、高的击穿电压、高的热导率、高的本征电子和空穴迁移率,以及优越的抗辐射性能,是目前已知的最有前景的宽禁带高温半导体材料,被誉为“终极半导体”。但单晶金刚石在半导体上的大规模应用还有很多技术难题急需解决。本文聚焦大尺寸(英寸级)单晶金刚石衬底的化学气相沉积合成、剥离切片及研磨抛光技术,通过对近年来的相关文献进行整理,综述了相关方面的国内外研究现状。在此基础上,对未来单晶金刚石半导体材料的制备、剥离和研磨抛光进行了展望。

关键词: 单晶金刚石, 大尺寸, 沉积, 剥离, 研磨抛光, 半导体

Abstract: Single crystal diamond has ultra-wide band gap, low dielectric constant, high breakdown voltage, high thermal conductivity, high intrinsic electron and hole mobility, and excellent radiation resistance, making it the most promising wide band gap high temperature semiconductor material known so far, known as the “ultimate semiconductor”. However, there are still many technical problems to be solved in the large-scale application of single crystal diamond on semiconductors. This paper focuses on the chemical vapor deposition synthesis, stripping section and grinding and polishing technology of large size (inch) single crystal diamond substrates. By sorting out the relevant literature in recent years, the related research status at home and abroad are reviewed. On this basis, the preparation, stripping, grinding and polishing of single crystal diamond semiconductor materials in the future are prospected.

Key words: single crystal diamond, large size, deposition, lift-off, grinding and polishing, semiconductor

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