元素级ZnS高温性能研究

人工晶体学报 ›› 2023, Vol. 52 ›› Issue (12): 2222-2227.

元素级ZnS高温性能研究

崔洪梅^1,2, 张旭^1,2, 陈琳³, 苏健¹, 宋雷^1,2, 马天翼^1,2, 钱纁^1,2, 韦中华^1,2

1.中材人工晶体研究院有限公司,北京 100018;
2.北京中材人工晶体研究院有限公司,北京 100018;
3.中国人民解放军93160部队,北京 101300

收稿日期:2023-09-27 出版日期:2023-12-15 发布日期:2023-12-26
作者简介:崔洪梅(1980—),女,山东省人,博士,高级工程师。E-mail:hmcui@163.com

High-Temperature Performances of Chemical Vapor Depositon Elemental ZnS

CUI Hongmei^1,2, ZHANG Xu^1,2, CHEN Lin³, SU Jian¹, SONG Lei^1,2, MA Tianyi^1,2, QIAN Xun^1,2, WEI Zhonghua^1,2

1. Sinoma Synthetic Crystals Co., Ltd., Beijing 100018, China;
2. Beijing Sinoma Synthetic Crystals Co., Ltd., Beijing 100018, China;
3. Unit 93160 of the PLA, Beijing 101300, China

Received:2023-09-27 Online:2023-12-15 Published:2023-12-26

摘要/Abstract

摘要： 作为一种重要的中长波红外窗口材料,元素级ZnS具有良好的光学性能和力学性能。目前,高超声速飞行器的发展迫切需要开展元素级ZnS红外窗口的高温性能研究。本文研究了不同温度下元素级ZnS的高温性能,结果表明,元素级ZnS的辐射率随着波长增大而增加,且同一波长下随温度的升高而增加,500 ℃时,在3～5.5 μm平均法向光谱辐射率小于0.05,7～10.5 μm平均法向光谱辐射率小于0.10。在2～9.5 μm,温度对透过率影响并不大,在9.5 μm后,随着温度的升高,透过率明显降低。折射率、热光系数和线膨胀系数随温度的升高而增大。温度对弯曲强度几乎无影响,弹性模量随温度升高而降低,800 ℃时的弹性模量与室温下的相比下降约30%。

关键词: 化学气相沉积, 高温性能, 元素级ZnS, 光学透过率, 弹性模量

Abstract: As a kind of medium and long wave infrared optical material, elemental ZnS has excellent optical and mechanical properties. At present, the development of hypersonic vehicle urgently requires research on the high-temperature performance of elemental ZnS infrared windows.The high-temperature performance of elemental ZnS at different temperatures were studied in this paper, and the results show that the emissivity of elemental ZnS increases with the increase of wavelength, and increases with the increase of temperature at the same wavelength. At 500 ℃, the average normal optical spectrum emissivity is less than 0.05 at 3～5.5 μm, and less than 0.10 at 7～10.5 μm. In the range of 2～9.5 μm, the temperature has little effect on the transmittance, but after 9.5 μm, the transmittance decreases significantly as the temperature increases. The refractive index, thermal optical coefficient, and expansion coefficient increase with increasing temperature. Temperature has almost no effect on bending strength. The elastic modulus decreases with increasing temperature, the elastic modulus at 800 ℃ decreases by about 30% compared to that at room temperature.

Key words: chemical vapor desposition, high-temperature performance, elemental ZnS, transmittance, elastic modulus

中图分类号:

TN213
O782

崔洪梅, 张旭, 陈琳, 苏健, 宋雷, 马天翼, 钱纁, 韦中华. 元素级ZnS高温性能研究[J]. 人工晶体学报, 2023, 52(12): 2222-2227.

CUI Hongmei, ZHANG Xu, CHEN Lin, SU Jian, SONG Lei, MA Tianyi, QIAN Xun, WEI Zhonghua. High-Temperature Performances of Chemical Vapor Depositon Elemental ZnS[J]. JOURNAL OF SYNTHETIC CRYSTALS, 2023, 52(12): 2222-2227.

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