KLi(HC3N3O3)·2H2O晶体的电光效应和生长研究

人工晶体学报 ›› 2023, Vol. 52 ›› Issue (7): 1302-1307.

• 激光与非线性光学晶体高通量制备与表征 • 上一篇下一篇

KLi(HC₃N₃O₃)·2H₂O晶体的电光效应和生长研究

颜涛, 范雨杰, 徐峰, 陈昱, 罗敏

中国科学院福建物质结构研究所,福州 350002

收稿日期:2023-05-14 出版日期:2023-07-15 发布日期:2023-08-16
通信作者: 罗敏,博士,研究员。E-mail:lm8901@fjirsm.ac.cn
作者简介:颜涛(1983—),男,山东省人,博士,副研究员。E-mail:yantao@fjirsm.ac.cn
基金资助:
国家重点研发计划(2021YFB3601503);国家自然科学基金(22222510,52202011);福建省自然科学基金(2021J01514);中国科学院青年创新促进会(2019303)

Electro-Optic Effect and Growth of KLi(HC₃N₃O₃)·2H₂O Crystal

YAN Tao, FAN Yujie, XU Feng, CHEN Yu, LUO Min

Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Received:2023-05-14 Online:2023-07-15 Published:2023-08-16

摘要/Abstract

摘要： 本文采用电光系数的粉末测试方法,探索发现了新型电光晶体KLi(HC₃N₃O₃)·2H₂O。根据粉末样品的红外反射光谱和拉曼光谱,计算获得晶格振动对电光系数的贡献值,再加上粉末倍频效应推算的有效非线性光学系数,最终计算出KLi(HC₃N₃O₃)·2H₂O的电光系数为2.37 pm/V,与商用电光晶体β-BBO相当。采用水溶液法进行晶体生长,测试不同原料生长晶体时的过热和过冷曲线,优化生长工艺,获得35 mm×25 mm×10 mm透明晶体。采用X射线定向技术辅以压电系数测量,确定了晶体形貌与各向异性生长速率的对应关系。

关键词: KLi(HC₃ N₃O₃)·2H₂O, 电光晶体, 电光系数, 水溶液法, 红外反射光谱, 拉曼光谱, 晶体生长

Abstract: In this work, a novel electro-optic crystal KLi(HC₃N₃O₃)·2H₂O was explored by powder method. The contribution of lattice vibration was calculated by infrared reflectance spectrum and Raman spectrum. The effective nonlinear optical coefficient was estimated from the powder second harmonic generation response. Consequently, the electro-optic coefficient of KLi(HC₃N₃O₃)·2H₂O is determined to be 2.37 pm/V, which is comparable to that of commercial β-BBO. The crystal was grown by aqueous solution method. Superheating and supercooling curves were measured for different raw materials. A transparent crystal with size of 35 mm×25 mm×10 mm was obtained after optimizing the growth process. The relationship between crystal morphology and anisotropic growth rate was confirmed by means of X-ray orientation and piezoelectric coefficient measurement.

Key words: KLi(HC₃ N₃O₃)·2H₂O, electro-optic crystal, electro-optic coefficient, aqueous solution method, infrared reflectance spectrum, Raman spectrum, crystal growth

中图分类号:

O78
O734

颜涛, 范雨杰, 徐峰, 陈昱, 罗敏. KLi(HC₃N₃O₃)·2H₂O晶体的电光效应和生长研究[J]. 人工晶体学报, 2023, 52(7): 1302-1307.

YAN Tao, FAN Yujie, XU Feng, CHEN Yu, LUO Min. Electro-Optic Effect and Growth of KLi(HC₃N₃O₃)·2H₂O Crystal[J]. JOURNAL OF SYNTHETIC CRYSTALS, 2023, 52(7): 1302-1307.

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KLi(HC₃N₃O₃)·2H₂O晶体的电光效应和生长研究

Electro-Optic Effect and Growth of KLi(HC₃N₃O₃)·2H₂O Crystal

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