纳米Y2O3粉体酸洗处理对透明陶瓷光学质量的影响

人工晶体学报 ›› 2024, Vol. 53 ›› Issue (11): 1990-1996.

纳米Y₂O₃粉体酸洗处理对透明陶瓷光学质量的影响

刘小龙¹, 付仲超¹, 吴南¹, 龙海波¹, 邵岑^2,3, 任轶⁴, 侯朝霞¹, 张乐^2,3

1.沈阳大学机械工程学院,沈阳 110044;
2.江苏师范大学物理与电子工程学院,徐州 221116;
3.江苏锡沂高新材料产业技术研究院,徐州 221400;
4.福建省金龙稀土股份有限公司,龙岩 366300

收稿日期:2024-09-10 出版日期:2024-11-15 发布日期:2024-12-09
通信作者: 付仲超,博士,讲师。E-mail:zhongchaofu@syu.edu.cn
作者简介:刘小龙(2003—),男,甘肃省人。E-mail:645620880@qq.com
基金资助:
国家自然科学基金(52302146);国家重点研发计划(2021YFB3501700);沈阳大学大学生创新创业训练计划项目(S202411035089)

Influence of Acid-Washing Treatment of Y₂O₃ Nanopowder on the Optical Properties of Transparent Ceramics

LIU Xiaolong¹, FU Zhongchao¹, WU Nan¹, LONG Haibo¹, SHAO Cen^2,3, REN Yi⁴, HOU Zhaoxia¹, ZHANG Le^2,3

1. School of Mechanical Engineering, Shenyang University, Shenyang 110044, China;
2. School of Physics Electronic Engineering, Jiangsu Normal University, Xuzhou 221116, China;
3. Jiangsu Xiyi Advanced Materials Research Institute of Industrial Technology, Xuzhou 221400, China;
4. Fujian Golden Dragon Rare-Earth Co., Ltd., Longyan 366300, China

Received:2024-09-10 Online:2024-11-15 Published:2024-12-09

摘要/Abstract

摘要： Y₂O₃透明陶瓷具有优良的光学和物理化学性能,在固体激光器、透明窗口等领域有广阔的应用前景。粉体分散性一直是研究者在透明陶瓷制备过程中关注的重要方面,本文以国产商业纳米Y₂O₃粉体为原料,通过机械分散结合HF酸洗的方式提高粉体分散性,湿法成型后真空烧结,制备具有较高光学性能的Y₂O₃透明陶瓷。结果表明,超声结合酸洗的方式可有效提升粉体分散性和烧结活性,粉体D₅₀从3.5 μm降低至1.4 μm,制备得到Y₂O₃透明陶瓷的光学性能有明显提升,400 nm处透过率从酸洗前的65.5%提升至酸洗后的71.5%,为Y₂O₃透明陶瓷在固体激光器和窗口领域的应用提供可靠的制备工艺及理论基础。

关键词: Y₂O₃, 粉体, 分散性, 酸洗, 透明陶瓷, 烧结

Abstract: Y₂O₃ transparent ceramics have broad applications including solid-state lasers, transparent windows, etc., owing to its excellent optical and physical-chemical properties. The dispersity of the powder among the fabrication process of transparent ceramics has attracted much attention from researchers for decades. In this paper, domestic commercial nanopowder was adopted as the starting material, and the dispersion of the powder was improved through mechanical force combined with HF acid-washing. Y₂O₃ transparent ceramics with high transmittance were achieved by slip casting and vacuum sintering. The results show that ultrasonic combined with HF acid-washing is an effective way to improve the dispersibility and sinterability of the powder, the D₅₀ of the powder reduces from 3.5 μm to 1.4 μm. The transmittance of the Y₂O₃ ceramic at 400 nm is improved from 65.5% to 71.5% for the sample after ultrasonic combined with HF acid-washing process. The results lay a solid foundation of preparation technology and theoretical basis for the application of Y₂O₃ transparent ceramics on solid-state lasers and transparent window materials.

Key words: Y₂O₃, powder, dispersity, acid-washing, transparent ceramics, sintering

中图分类号:

TQ174.75

刘小龙, 付仲超, 吴南, 龙海波, 邵岑, 任轶, 侯朝霞, 张乐. 纳米Y₂O₃粉体酸洗处理对透明陶瓷光学质量的影响[J]. 人工晶体学报, 2024, 53(11): 1990-1996.

LIU Xiaolong, FU Zhongchao, WU Nan, LONG Haibo, SHAO Cen, REN Yi, HOU Zhaoxia, ZHANG Le. Influence of Acid-Washing Treatment of Y₂O₃ Nanopowder on the Optical Properties of Transparent Ceramics[J]. JOURNAL OF SYNTHETIC CRYSTALS, 2024, 53(11): 1990-1996.

参考文献

[1] XIAO Z H, YU S J, LI Y M, et al. Materials development and potential applications of transparent ceramics: a review[J]. Materials Science and Engineering: R: Reports, 2020, 139: 100518.
[2] WANG S F, ZHANG J, LUO D W, et al. Transparent ceramics: processing, materials and applications[J]. Progress in Solid State Chemistry, 2013, 41(1/2): 20-54.
[3] 李江, 姜楠, 徐圣泉, 等. 红外透明MgO-Y₂O₃纳米复相陶瓷研究进展[J]. 硅酸盐学报, 2016, 44(9): 1302-1314.
LI J, JIANG N, XU S Q, et al. Resent development on infrared transparent MgO-Y₂O₃ nanocomposite ceramics[J]. Journal of the Chinese Ceramic Society, 2016, 44(9): 1302-1314 (in Chinese).
[4] YIN D L, WANG J, WANG Y, et al. Fabrication of Er∶Y₂O₃ transparent ceramics for 2.7 μm mid-infrared solid-state lasers[J]. Journal of the European Ceramic Society, 2020, 40(2): 444-448.
[5] LIU Z Y, IKESUE A, LI J. Research progress and prospects of rare-earth doped sesquioxide laser ceramics[J]. Journal of the European Ceramic Society, 2021, 41(7): 3895-3910.
[6] LIU L X, HOU W T, LIU J, et al. Spectroscopic characterization of Yb³⁺-doped sesquioxide transparent ceramics[J]. Journal of Luminescence, 2024, 275: 120830.
[7] HUANG Z Y, DENG J R, WANG H M, et al. A new method for the preparation of transparent Y₂O₃ nanocrystalline ceramic with an average grain size of 20 nm[J]. Scripta Materialia, 2020, 182: 57-61.
[8] WANG J, ZHANG J, NING K J, et al. Densification of zirconia doped yttria transparent ceramics using co-precipitated powders[J]. Ceramics International, 2016, 42(9): 10770-10778.
[9] LIU L K, ZHU Q H, ZHU Q Q, et al. Fabrication of fine-grained undoped Y₂O₃ transparent ceramic using nitrate pyrogenation synthesized nanopowders[J]. Ceramics International, 2019, 45(5): 5339-5345.
[10] NI M, WANG J, MA J, et al. Synthesis of yttria nanopowder with poly acrylic acid as dispersant for highly transparent yttria ceramics[J]. Journal of the American Ceramic Society, 2022, 105(3): 2029-2037.
[11] CHERNOMORETS D G, PIANCASTELLI A, ESPOSITO L, et al. Effect of milling parameters on the morphology and sinterability of the yttrium oxide powders for transparent ceramics[J]. Open Ceramics, 2023, 15: 100391.
[12] WANG J, ZHANG J, LUO D W, et al. Densification and microstructural evolution of yttria transparent ceramics: the effect of ball milling conditions[J]. Journal of the European Ceramic Society, 2015, 35(3): 1011-1019.
[13] 常玉坤, 王涛, 何娇, 等. 纳米Y₂O₃悬浮液流变性能及注浆成型研究[J]. 人工晶体学报, 2020, 49(10): 1911-1916.
CHANG Y K, WANG T, HE J, et al. Rheological behavior and slip casting of nano Y₂O₃ aqueous suspension[J]. Journal of Synthetic Crystals, 2020, 49(10): 1911-1916 (in Chinese).
[14] 赵瑾, 毛小建, 章健, 等. 自发凝固成型制备透明陶瓷研究进展[J]. 现代技术陶瓷, 2024, 45(1/5): 12-23.
ZHAO J, MAO X J, ZHANG J, et al. Progress in preparation of transparent ceramics by spontaneous coagulation casting[J]. Advanced Ceramics, 2024, 45(1/2): 12-23 (in Chinese).
[15] OLHERO S M, GANESH I, TORRES P M C, et al. Aqueous colloidal processing of ZTA composites[J]. Journal of the American Ceramic Society, 2009, 92(1): 9-16.
[16] JIN L L, ZHOU G H, SHIMAI S, et al. ZrO₂-doped Y₂O₃ transparent ceramics via slip casting and vacuum sintering[J]. Journal of the European Ceramic Society, 2010, 30(10): 2139-2143.
[17] HOU X R, ZHOU S M, JIA T T, et al. Structural, thermal and mechanical properties of transparent Yb∶(Y_0.97Zr_0.03)₂O₃ ceramic[J]. Journal of the European Ceramic Society, 2011, 31(5): 733-738.
[18] HOU X R, ZHOU S M, LI W J, et al. Study on the effect and mechanism of zirconia on the sinterability of yttria transparent ceramic[J]. Journal of the European Ceramic Society, 2010, 30(15): 3125-3129.
[19] YOSHIDA H, KODO M, SOGA K, et al. Doping effect on sinterability of polycrystalline yttria: from the viewpoint of cation diffusivity[J]. Journal of the European Ceramic Society, 2012, 32(12): 3103-3114.
[20] BERNARD-GRANGER G, GUIZARD C, SAN-MIGUEL L. Sintering behavior and optical properties of yttria[J]. Journal of the American Ceramic Society, 2007, 90(9): 2698-2702.
[21] LI X K, XU Y Y, MAO X J, et al. Investigation of optical, mechanical, and thermal properties of ZrO₂-doped Y₂O₃ transparent ceramics fabricated by HIP[J]. Ceramics International, 2018, 44(2): 1362-1369.
[22] HUANG Y H, JIANG D L, ZHANG J X, et al. Sintering of transparent yttria ceramics in oxygen atmosphere[J]. Journal of the American Ceramic Society, 2010, 93(10): 2964-2967.
[23] CAO Y F, LI H Y, ZHENG X Y, et al. Simultaneous precipitation of Zr⁴⁺ and Y³⁺ ions induced refinement of precursors and powders in fabrication of Zr⁴⁺ doped Y₂O₃ transparent ceramics[J]. Optical Materials, 2023, 139: 113802.
[24] GAN L, PARK Y J, ZHU L L, et al. Fabrication and properties of La₂O₃-doped transparent yttria ceramics by hot-pressing sintering[J]. Journal of Alloys and Compounds, 2017, 695: 2142-2148.
[25] LI X K, MAO X J, FENG M H, et al. Fabrication of transparent La-doped Y₂O₃ ceramics using different La₂O₃ precursors[J]. Journal of the European Ceramic Society, 2016, 36(10): 2549-2553.
[26] NING K J, WANG J, LUO D W, et al. New double-sintering aid for fabrication of highly transparent ytterbium-doped yttria ceramics[J]. Journal of the European Ceramic Society, 2016, 36(1): 253-256.
[27] ZHANG L, BEN Y, WU J D, et al. Alumina assisted grain refinement and physical performance enhancement of yttria transparent ceramics by two-step sintering[J]. Materials Science and Engineering: A, 2017, 684: 466-469.
[28] WANG Z Y, ZHANG L, YANG H, et al. Effect of γ-Al₂O₃ additives on the microstructure of Y₂O₃ ceramics[J]. Journal of Materials Science: Materials in Electronics, 2016, 27(4): 3384-3389.
[29] LI X K, ZHU Q Q, XU Y Y, et al. Optical and thermal properties of TiO₂-doped Y₂O₃ transparent ceramics synthesized by hot isostatic pressing[J]. Journal of the American Ceramic Society, 2019, 102(4): 2021-2028.
[30] MENDELSON M I. Average grain size in polycrystalline ceramics[J]. Journal of the American Ceramic Society, 1969, 52(8): 443-446.
[31] CROCOMBETTE J P, JOLLET F. Site selectivity in ZrO₂-doped Y₂O₃ evidenced by X-ray absorption spectra calculations[J]. Journal of Physics: Condensed Matter, 1994, 6(40): 8341-8348.

纳米Y₂O₃粉体酸洗处理对透明陶瓷光学质量的影响

Influence of Acid-Washing Treatment of Y₂O₃ Nanopowder on the Optical Properties of Transparent Ceramics

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	陈继虎, 路亚妮. 粉体还原对硒化亚铜热电性能的影响[J]. 人工晶体学报, 2024, 53(8): 1464-1470.
[2]	李晴, 姜珍兴, 王莹, 马杰, 王俊, 刘鹏, 章健, 范金太, 于浩海, 张怀金, 唐定远. Yb∶Lu₂O₃透明陶瓷的制备及激光性能研究[J]. 人工晶体学报, 2024, 53(11): 1884-1891.
[3]	刘子玉, 郑雯雯, 冯亚刚, 叶君豪, 刘鹏, 杨现锋, 李江. 不同掺杂浓度Er∶Lu₂O₃透明陶瓷的制备与性能研究[J]. 人工晶体学报, 2024, 53(11): 1892-1900.
[4]	冯亚刚, 田丰, 刘子玉, 刘奕炀, 吴乐翔, 李廷松, 李江. 层状复合结构YAG/Yb∶YAG透明陶瓷的制备与性能研究[J]. 人工晶体学报, 2024, 53(11): 1901-1908.
[5]	黄秋凤, 邓志强, 陈剑, 郭旺, 邓种华, 刘著光, 黄集权. Cr掺杂YAG透明陶瓷的价态调控及光学性能研究[J]. 人工晶体学报, 2024, 53(11): 1909-1917.
[6]	刘强, 李想, 郭礼豪, TOCI Guido, PIRRI Angela, PATRIZI Barbara, VANNINI Matteo, 吴俊林, 李江. Yb∶CaF₂透明陶瓷的压力辅助烧结及其性能研究[J]. 人工晶体学报, 2024, 53(11): 1918-1926.
[7]	陈杰, 沈世纪, 田燕娜, 周圣明. 铽铝石榴石磁光陶瓷真空固相反应制备及格位取代研究进展[J]. 人工晶体学报, 2024, 53(11): 1927-1935.
[8]	冯桂青, 徐刘伟, 袁亚舟, 郑熠, 黄鑫, 陈旻, 王帅华, 吴少凡. 稀土离子过量掺杂TSAG及YAG/TSAG复合结构透明陶瓷的制备与性能研究[J]. 人工晶体学报, 2024, 53(11): 1944-1955.
[9]	吴文杰, 何代华, 程思远, 何夕云. PLZT透明陶瓷的微区组分调控及梯度设计与电光性能研究[J]. 人工晶体学报, 2024, 53(11): 1956-1963.
[10]	王亚祺, 付大石, 王亚男, 秦亚琳, 张永成. 无铅0.96KNNTS_x-0.04BNKZ透明压电陶瓷的制备及其光电性能研究[J]. 人工晶体学报, 2024, 53(11): 1964-1971.
[11]	汪开强, 杨康, 靖正阳, 陈博文, 涂兵田, 王皓. Zn_1.1Ga_1.8Ge_0.1O₄透明陶瓷烧结过程的动力学研究[J]. 人工晶体学报, 2024, 53(11): 1972-1980.
[12]	曲胜箫, 穆浩洁, 杨亮, 李晓东, 史树君, 孙旭东. 基于双分散剂协同作用胶态成型制备氧化钇透明陶瓷[J]. 人工晶体学报, 2024, 53(11): 1981-1989.
[13]	刘作冬, 潘其悦, 刘瑞, 曹悦, 李思雅, 王嘉顺, 于永生, 刘鹏, 井强山. Y³⁺∶CaF₂透明陶瓷的制备及其显微结构研究[J]. 人工晶体学报, 2024, 53(11): 1997-2003.
[14]	郭浩然, 闫晖, 单英春, 高铭泽, 徐久军, 李江涛. Pechini法制备Y₂O₃的煅烧温度对无压烧结AlON陶瓷透光性的影响[J]. 人工晶体学报, 2024, 53(11): 2004-2012.
[15]	雷牧云, 李祯, 王颖, 何敬晖, 王立弟, 庞珍丽. 镁铝尖晶石透明陶瓷吸收系数研究[J]. 人工晶体学报, 2024, 53(11): 2013-2021.