
人工晶体学报 ›› 2026, Vol. 55 ›› Issue (7): 1022-1043.DOI: 10.16553/j.cnki.issn1000-985x.2026.0057
李乾1,2,3(
), 周峰1,2,3,4, 刘显明1,2,3(
), 雷小华1,2,3, 章鹏1,2,3, 许亨艺1,2,3
收稿日期:2026-04-07
出版日期:2026-07-20
发布日期:2026-08-04
通信作者:
刘显明,博士,教授。E-mail:xianming65@163.com作者简介:李乾(1997—),男,河南省人,博士研究生。E-mail:19132055101@163.com基金资助:
LI Qian1,2,3(
), ZHOU Feng1,2,3,4, LIU Xianming1,2,3(
), LEI Xiaohua1,2,3, ZHANG Peng1,2,3, XU Hengyi1,2,3
Received:2026-04-07
Online:2026-07-20
Published:2026-08-04
摘要: 蓝宝石单晶光纤兼具耐高温、耐腐蚀、抗辐照和宽光谱透射等优异特性,是极端环境光学传感的重要候选材料。然而,现有蓝宝石单晶光纤多为无包层结构,存在模式约束能力弱、传输损耗较高和环境敏感性强等问题,这制约了其实际工程应用。包层化处理通过在蓝宝石单晶光纤外部或内部构建低折射率导光约束结构,改善传输性能、提升器件化水平并拓展应用场景。本文系统综述了蓝宝石单晶光纤包层化技术的研究进展,将现有技术归纳为外添型包层化技术、内改型包层化技术和微结构型包层化技术三类,重点梳理了各类技术的实现原理、制备工艺、代表性工作及性能特点,并对不同包层路线的发展现状、技术特点及适用潜力进行了比较分析。在此基础上,进一步面向极端环境传输与传感应用,展望了蓝宝石单晶光纤包层化技术的发展方向。
中图分类号:
李乾, 周峰, 刘显明, 雷小华, 章鹏, 许亨艺. 蓝宝石单晶光纤包层化技术的演进与前瞻[J]. 人工晶体学报, 2026, 55(7): 1022-1043.
LI Qian, ZHOU Feng, LIU Xianming, LEI Xiaohua, ZHANG Peng, XU Hengyi. Cladding Technologies for Sapphire Single-Crystal Fiber: Evolution and Prospects[J]. Journal of Synthetic Crystals, 2026, 55(7): 1022-1043.
图1 蓝宝石单晶光纤包层化技术分类示意图。(a)外添型包层化技术;(b)内改型包层化技术;(c)微结构型包层化技术
Fig.1 Schematic classification of sapphire single-crystal fiber cladding techniques. (a) External additive cladding technique; (b) internal modification cladding technique; (c) micro-structured cladding technique
图3 MgAl2O4尖晶石包层的结构表征及高温传输性能[35]。(a)1 000和1 300 ℃退火后微观截面形貌;(b)MgO-Al2O3二元相图;(c)高温气氛循环传输损耗测试系统;(d)数值孔径测试结果;(e)高温气氛循环下的传输损耗变化
Fig.3 Structural characterization and high-temperature transmission performance of MgAl2O4 spinel cladding[35]. (a) Cross-sectional morphologies after annealing at 1 000 and 1 300 ℃; (b) MgO-Al2O3 binary phase diagram; (c) high-temperature gas-cycling transmission loss measurement system; (d) numerical aperture measurement results; (e) transmission loss variation under high-temperature gas-cycling
图4 聚合物前驱体法制备的MgAl2O4包层及包层化前后的数值孔径对比[38]。(a)MgAl2O4包层的SEM照片;(b)~(d)入射距离分别为2、4和10 mm时,蓝宝石单晶光纤包层化前后的数值孔径对比
Fig.4 MgAl2O4 cladding prepared by polymeric precursor method and comparison of numerical aperture before and after cladding[38]. (a) SEM image of MgAl2O4 cladding; (b)~(d) comparison of numerical aperture of sapphire single-crystal fibers before and after cladding at input distances of 2, 4 and 10 mm, respectively
图5 熔融铝浸涂-阳极氧化法。(a)技术路线图[40];(b)实验装置示意图[39];(c)包层截面形貌及元素分布[40];(d)SERS响应[40]
Fig.5 Molten-aluminum dip-coating and subsequent anodization. (a) Technical roadmap[40]; (b) schematic diagram of experimental setup[39]; (c) cross-sectional morphology and elemental distribution of cladding[40]; (d) SERS responses[40]
图6 PVD制备的蓝宝石单晶光纤包层。(a)采用溅射和电子束蒸发制备的ZrO2、Mo、W和Cr包层[30];(b)采用GLAD制备的Al2O3包层[42]
Fig.6 Sapphire single-crystal fiber claddings prepared by PVD. (a) ZrO2, Mo, W and Cr coatings prepared by sputtering and eletron-beam evaporation[30]; (b) Al2O3 cladding prepared by GLAD[42]
图7 CVD制备的蓝宝石单晶光纤包层。(a)基于LPCVD和ALD制备的hBN、Al2O3包层[44?46];(b)BN、BN/SiBCN及(BN/SiBCN)2包层结构[47?49];(c)采用Mist-CVD制备的MgAl2O4包层[50]
Fig.7 Sapphire single-crystal fiber claddings prepared by CVD. (a) hBN and Al2O3 claddings prepared by LPCVD and ALD[44?46]; (b) BN, BN/SiBCN and (BN/SiBCN)2 cladding structures[47?49]; (c) MgAl2O4 cladding prepared by Mist-CVD[50]
图8 晶体-玻璃复合光纤及其芯-包界面微结构[51]。(a)制备工艺示意图;(b)光纤端面、芯区放大、侧视图及蓝宝石c轴取向示意图;(c)蓝宝石单晶纤芯/玻璃包层界面的HRTEM照片、傅里叶变换及反傅里叶变换表征
Fig.8 Hybrid crystal-glass fiber and its core-cladding interfacial microstructure[51]. (a) Schematic diagram of fabrication process; (b) fiber endface, enlarged core region, side-view, and c-axis orientation schematic diagram of sapphire; (c) HRTEM images Fourier-transform and inverse-Fourier-transform characterizations of sapphire single-crystal fiber core/glass cladding interface
图9 晶体芯/晶体包层光纤[54]。(a)实验装置示意图;(b)Ti∶Al2O3纤芯/Al2O3晶体包层光纤横截面;(c)1 600 ℃保温10 h前后光纤端面形貌对比
Fig.9 Crystalline-core/crystalline-cladding fibers[54]. (a) Schematic diagram of experimental setup; (b) cross-section of Ti∶Al2O3 fiber core/Al2O3 crystalline-cladding fiber; (c) comparison of fiber end-face morphology before and after holding at 1 600 ℃ for 10 h
| Technique | Year | Institution | Advantage | Disadvantage |
|---|---|---|---|---|
| Suspension dip-coating-sintering method | 1993 | Drexel University & NASA Lewis Research Center[ | Simple; low-cost; thickness-tunable; suitable for thick coatings | Prone to pores/cracks; sensitive to slurry and sintering conditions |
| 1994 | Drexel University & NASA Lewis Research Center[ | |||
| 1995 | NASA[ | |||
| Solution dip-coating and staged curing | 1994 | Rutgers University[ | Simple; high efficiency; scalable coating | Limited temperature resistance; thermal mismatch; poor long-term stability |
| Sol-gel dip-coating and subsequent thermal treatment | 1994 | Rutgers University[ | Composition-tunable; uniform coating; mature process | Multi-cycle deposition; porous defects; limited high-temperature stability |
| 1994 | NASA Lewis Research Center[ | |||
| 1997 | NASA Lewis Research Center[ | |||
| 2000 | Zhejiang University & Fang Yuan technical Incorporation[ | |||
| 2008 | General Electric Company[ | |||
| 2022 | NETL[ | |||
Surface reaction- conversion method | 2005 | UT-Battelle, LLC[ | Strong bonding; in situ cladding; large NA reduction | Very high temperature; poor control of thickness; core distortion risk |
| Polymeric precursor method | 2013 | University of Cincinnati & Missouri University of Science and Technology[ | Good precursor homogeneity; low formation temperature; stable coating | Low efficiency; repeated cycles required; thermal stability still limited |
| Molten-aluminum dip-coating and subsequent anodization | 2015—2016 | Stevens Institute of Technology & Academy of Sciences of the Czech Republic[ | In situ oxide conversion; useful for functional coatings | Poor uniformity control; rough/porous interface; higher scattering loss |
| UV-assisted curing and forming technique | 2024 | Harbin Engineering University[ | Good shape control; thick cladding | Eccentricity, pores, and cracks likely; stability not fully verified |
| PVD | 1993 | University of California & Max-Planck-Institut für Metallforschung & Pratt & Whitney Company[ | High purity; precise thickness control; suitable for thin functional films | Slow; expensive; limited uniformity on curved surfaces |
| 2021 | Iowa State University & SSAB Americas[ | |||
| CVD | 1990 | Virginia Polytechnic Institute and State University[ | Dense and uniform coatings; controllable thickness; multilayer capable | Complex equipment; high process requirements; high-temperature degradation |
| 1993 | University of California & Max-Planck-Institut für Metallforschung & Pratt & Whitney Company[ | |||
| 2008 | General Electric Company[ | |||
| 2019 | Jilin University[ | |||
| 2019 | Northwestern Polytechnical University & Southwest University[ | |||
| 2020 | Northwestern Polytechnical University & Changcheng Institute of Metrology and Measurement & Southwest University[ | |||
| 2024 | Northwestern Polytechnical University & AECC Sichuan Gas Turbine Establishment[ | |||
| 2025 | Shandong University[ | |||
| Melt extrusion | 1993 | Rutgers University[ | Simple; fast; continuous thick coating | Poor thermal resistance; mainly suitable as a protective layer |
| 1994 | Rutgers University[ | |||
LHPG-based hybrid crystal-glass fiber fabrication | 2016 | National Dong Hwa University & National Taiwan Ocean University & National chi nan university[ | Direct core-cladding formation; good interface quality | Glass cladding limits ultrahigh-temperature use; process is complex |
| Liquid sapphire single-crystal fiber cladding | 2022 | Wuhan University of Technology[ | Simple; refractive index tunable | Poor thermal stability; difficult for practical continuous cladding |
Crystalline-core/ crystalline-clad fiber | 2025 | The Pennsylvania State University & General Opto Solutions, LLC[ | All-crystalline structure; best thermal match; high-temperature stability | Complex; low efficiency; limited length; coupling is difficult |
表1 外添型包层化技术对比
Table 1 Comparison of external additive cladding techniques
| Technique | Year | Institution | Advantage | Disadvantage |
|---|---|---|---|---|
| Suspension dip-coating-sintering method | 1993 | Drexel University & NASA Lewis Research Center[ | Simple; low-cost; thickness-tunable; suitable for thick coatings | Prone to pores/cracks; sensitive to slurry and sintering conditions |
| 1994 | Drexel University & NASA Lewis Research Center[ | |||
| 1995 | NASA[ | |||
| Solution dip-coating and staged curing | 1994 | Rutgers University[ | Simple; high efficiency; scalable coating | Limited temperature resistance; thermal mismatch; poor long-term stability |
| Sol-gel dip-coating and subsequent thermal treatment | 1994 | Rutgers University[ | Composition-tunable; uniform coating; mature process | Multi-cycle deposition; porous defects; limited high-temperature stability |
| 1994 | NASA Lewis Research Center[ | |||
| 1997 | NASA Lewis Research Center[ | |||
| 2000 | Zhejiang University & Fang Yuan technical Incorporation[ | |||
| 2008 | General Electric Company[ | |||
| 2022 | NETL[ | |||
Surface reaction- conversion method | 2005 | UT-Battelle, LLC[ | Strong bonding; in situ cladding; large NA reduction | Very high temperature; poor control of thickness; core distortion risk |
| Polymeric precursor method | 2013 | University of Cincinnati & Missouri University of Science and Technology[ | Good precursor homogeneity; low formation temperature; stable coating | Low efficiency; repeated cycles required; thermal stability still limited |
| Molten-aluminum dip-coating and subsequent anodization | 2015—2016 | Stevens Institute of Technology & Academy of Sciences of the Czech Republic[ | In situ oxide conversion; useful for functional coatings | Poor uniformity control; rough/porous interface; higher scattering loss |
| UV-assisted curing and forming technique | 2024 | Harbin Engineering University[ | Good shape control; thick cladding | Eccentricity, pores, and cracks likely; stability not fully verified |
| PVD | 1993 | University of California & Max-Planck-Institut für Metallforschung & Pratt & Whitney Company[ | High purity; precise thickness control; suitable for thin functional films | Slow; expensive; limited uniformity on curved surfaces |
| 2021 | Iowa State University & SSAB Americas[ | |||
| CVD | 1990 | Virginia Polytechnic Institute and State University[ | Dense and uniform coatings; controllable thickness; multilayer capable | Complex equipment; high process requirements; high-temperature degradation |
| 1993 | University of California & Max-Planck-Institut für Metallforschung & Pratt & Whitney Company[ | |||
| 2008 | General Electric Company[ | |||
| 2019 | Jilin University[ | |||
| 2019 | Northwestern Polytechnical University & Southwest University[ | |||
| 2020 | Northwestern Polytechnical University & Changcheng Institute of Metrology and Measurement & Southwest University[ | |||
| 2024 | Northwestern Polytechnical University & AECC Sichuan Gas Turbine Establishment[ | |||
| 2025 | Shandong University[ | |||
| Melt extrusion | 1993 | Rutgers University[ | Simple; fast; continuous thick coating | Poor thermal resistance; mainly suitable as a protective layer |
| 1994 | Rutgers University[ | |||
LHPG-based hybrid crystal-glass fiber fabrication | 2016 | National Dong Hwa University & National Taiwan Ocean University & National chi nan university[ | Direct core-cladding formation; good interface quality | Glass cladding limits ultrahigh-temperature use; process is complex |
| Liquid sapphire single-crystal fiber cladding | 2022 | Wuhan University of Technology[ | Simple; refractive index tunable | Poor thermal stability; difficult for practical continuous cladding |
Crystalline-core/ crystalline-clad fiber | 2025 | The Pennsylvania State University & General Opto Solutions, LLC[ | All-crystalline structure; best thermal match; high-temperature stability | Complex; low efficiency; limited length; coupling is difficult |
图10 氢离子注入实现蓝宝石单晶光纤包层化。(a)原理示意图[58];(b)实验装置[59];(c)光纤端面光场分布[58];(d)不同退火温度下注入层截面TEM照片[58]
Fig.10 Sapphire single-crystal fiber cladding realized by hydrogen ion implantation. (a) Schematic diagram of principle[58];(b) experimental setup[59]; (c) optical field distribution of fiber end-face[58]; (d) cross-sectional TEM images of implanted layer at different annealing temperatures[58]
图11 6Li(n,α)3H反应离子注入蓝宝石单晶光纤内包层及其模式调控特性。(a)原理示意图[60];(b)辐照后蓝宝石单晶光纤截面折射率分布示意图[62];(c)不同模式剥除条件下的远场输出分布[62];(d)包层化后蓝宝石单晶光纤的OFDR响应[62]
Fig.11 Internal cladding in sapphire single-crystal fibers formed by 6Li(n,α)3H reaction-based ion implantation and its mode-control characteristics. (a) Schematic diagram of principle[60]; (b) schematic diagram of refractive-index distribution in cross-section of irradiated sapphire single-crystal fiber[62]; (c) far-field output distributions under different mode-stripping conditions[62]; (d) OFDR response of sapphire single-crystal fiber after cladding[62]
图13 TypeⅡ凹陷包层波导及其实现方式。(a)逐点刻写[69?70];(b)逐环刻写装置光路[72];(c) 逐环刻写布拉格型包层光路的Zemax仿真[73]
Fig.13 TypeⅡ depressed-cladding waveguides and their fabrication schemes. (a) Point-by-point inscription[69?70]; (b) optical layout of ring-by-ring inscription setup[72]; (c) Zemax simulation of optical layout for ring-by-ring inscription of Bragg-type cladding[73]
图14 飞秒激光直写蓝宝石单晶光纤Type II凹陷包层与FBG的一体化结构。(a) HSFBG[74];(b) RSFBG[75];(c)逐环刻写装置[76];(d)、(e) HBGW[77?78];(f) DSFBG[79]
Fig.14 Integrated structures of Type II depressed-cladding and FBG by femtosecond laser direct written sapphire single-crystal fibers. (a) HSFBG[74]; (b) RSFBG[75]; (c) Ring-by-ring grating inscription device[76]; (d), (e) HBGW[77?78]; (f) DSFBG[79]
| Technique | Year | Institution | Advantage | Disadvantage |
|---|---|---|---|---|
| Two-step laser melting technique | 1977 | Bell laboratories[ | Monolithic crystalline structure | Parameter-sensitive; prone to surface defects; limited structural tunability |
Hydrogen ion implantation | 2013 | State University of New York[ | Controllable cladding location; strong optical confinement | Parameter-sensitive; low efficiency; limited cladding uniformity |
6Li(n,α)3H reaction-based ion implantation | 2017 | The Ohio State University[ | High-temperature stability; potential for distributed sensing | Harsh experimental conditions; complex process; limited higher-order-mode suppression |
| 2022 | The Ohio State University & Luna Innovations Inc. & Idaho National Laboratory[ | |||
| Type I directly written waveguides | 2022 | Beijing Institute of Technology[ | Direct core writing; simple structure; suitable for local waveguide fabrication | Narrow process window; limited thermal stability; poor repeatability |
Type II depressed-cladding waveguides | 2022 | University of Oxford & Rolls-Royce Plc[ | Flexible design; depressed-cladding structure; potential for single-mode guidance | High propagation loss; crack-prone; narrow process window and high cost |
| 2024 | University of Oxford & Rolls-Royce Plc & Shandong University & Jiangsu Jingying Optoelectronics Technology Co. Ltd.[ | |||
| 2025 | Chongqing university[ | |||
| 2025 | Chongqing university[ | |||
| 2021 | Jilin University & Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences & Tsing-Hua University[ | Integrated cladding and grating; combined mode control and sensing; high device integration | Mostly short local devices; low efficiency; difficult long-length consistency and low-loss coupling | |
| 2023 | Huazhong University of Science and Technology[ | |||
| 2023 | Zhejiang Lab[ | |||
| 2023 | Shenzhen University[ | |||
| 2025 | Shenzhen University & Hiwing Technology Academy of CASIC[ | |||
| 2026 | North University of China & Xiamen University[ |
表2 内改型包层化技术对比
Table 2 Comparison of internal modification cladding techniques
| Technique | Year | Institution | Advantage | Disadvantage |
|---|---|---|---|---|
| Two-step laser melting technique | 1977 | Bell laboratories[ | Monolithic crystalline structure | Parameter-sensitive; prone to surface defects; limited structural tunability |
Hydrogen ion implantation | 2013 | State University of New York[ | Controllable cladding location; strong optical confinement | Parameter-sensitive; low efficiency; limited cladding uniformity |
6Li(n,α)3H reaction-based ion implantation | 2017 | The Ohio State University[ | High-temperature stability; potential for distributed sensing | Harsh experimental conditions; complex process; limited higher-order-mode suppression |
| 2022 | The Ohio State University & Luna Innovations Inc. & Idaho National Laboratory[ | |||
| Type I directly written waveguides | 2022 | Beijing Institute of Technology[ | Direct core writing; simple structure; suitable for local waveguide fabrication | Narrow process window; limited thermal stability; poor repeatability |
Type II depressed-cladding waveguides | 2022 | University of Oxford & Rolls-Royce Plc[ | Flexible design; depressed-cladding structure; potential for single-mode guidance | High propagation loss; crack-prone; narrow process window and high cost |
| 2024 | University of Oxford & Rolls-Royce Plc & Shandong University & Jiangsu Jingying Optoelectronics Technology Co. Ltd.[ | |||
| 2025 | Chongqing university[ | |||
| 2025 | Chongqing university[ | |||
| 2021 | Jilin University & Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences & Tsing-Hua University[ | Integrated cladding and grating; combined mode control and sensing; high device integration | Mostly short local devices; low efficiency; difficult long-length consistency and low-loss coupling | |
| 2023 | Huazhong University of Science and Technology[ | |||
| 2023 | Zhejiang Lab[ | |||
| 2023 | Shenzhen University[ | |||
| 2025 | Shenzhen University & Hiwing Technology Academy of CASIC[ | |||
| 2026 | North University of China & Xiamen University[ |
图15 蓝宝石光子晶体光纤。(a)全蓝宝石光子晶体光纤[83];(b)空气孔型蓝宝石光子晶体光纤[85]
Fig.15 Sapphire photonic crystal fibers. (a) All-sapphire photonic crystal fiber[83]; (b) air-hole sapphire photonic crystal fiber[85]
图16 分段包层蓝宝石单晶光纤。(a) Windmill型分段包层蓝宝石单晶光纤及其模场分布[87];(b)star-wheel型分段包层蓝宝石单晶光纤及其模场分布[90];(c)多边形周期分段包层蓝宝石单晶光纤[93]
Fig.16 Segmented cladding sapphire single-crystal fibers. (a) Windmill segmented cladding sapphire single-crystal fibers and their modal field distributions[87]; (b) star-wheel segmented cladding sapphire single-crystal fibers and their modal field distributions[90]; (c) polygonal periodic segmented cladding sapphire single-crystal fiber[93]
| Technique | Year | Institution | Advantage | Disadvantage |
|---|---|---|---|---|
Sapphire photonic crystal fiber | 2010 | Virginia Polytechnic Institute and State University[ | High design flexibility; effective mode and dispersion control | Complex fabrication; poor hole stability at high temperature; difficult structural control |
| 2015 | Xidian University[ | |||
| 2024 | Huazhong University of Science and Technology[ | |||
Segmented cladding sapphire single-crystal fiber | 2015 | Virginia Polytechnic Institute and State University[ | High structural flexibility; large-core single-mode potential; effective mode filtering; strong dispersion engineering capability | Mostly theoretical; high machining precision required; poor long-length consistency |
| 2016 | Virginia Polytechnic Institute and State University[ | |||
| 2018 | Graduate University of Advanced Technology, Department of Physics and Photonics, Kerman, Iran & Yazd University[ | |||
| 2021 | Wuhan University of Technology & Quaid-i-Azam university[ | |||
| 2022 | Beijing Institute of Technology[ |
表3 微结构型包层化技术对比
Table 3 Comparison of micro-structured cladding techniques
| Technique | Year | Institution | Advantage | Disadvantage |
|---|---|---|---|---|
Sapphire photonic crystal fiber | 2010 | Virginia Polytechnic Institute and State University[ | High design flexibility; effective mode and dispersion control | Complex fabrication; poor hole stability at high temperature; difficult structural control |
| 2015 | Xidian University[ | |||
| 2024 | Huazhong University of Science and Technology[ | |||
Segmented cladding sapphire single-crystal fiber | 2015 | Virginia Polytechnic Institute and State University[ | High structural flexibility; large-core single-mode potential; effective mode filtering; strong dispersion engineering capability | Mostly theoretical; high machining precision required; poor long-length consistency |
| 2016 | Virginia Polytechnic Institute and State University[ | |||
| 2018 | Graduate University of Advanced Technology, Department of Physics and Photonics, Kerman, Iran & Yazd University[ | |||
| 2021 | Wuhan University of Technology & Quaid-i-Azam university[ | |||
| 2022 | Beijing Institute of Technology[ |
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