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人工晶体学报 ›› 2009, Vol. 38 ›› Issue (4): 998-1003.

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La3+,Al3+共掺杂纳米ZnO光催化降解活性艳蓝X-BR研究

周银;王宇;卢士香;徐文国;苏苏   

  1. 北京理工大学理学院,北京,100081;成都市公安消防支队司令部,成都,610000;北京理工大学理学院,北京,100081
  • 出版日期:2009-08-15 发布日期:2021-01-20
  • 基金资助:
    This work was supported by the 111 Project B07012 of China

Photocatalytic Degradation of Reactive Brilliant Blue X-BR with La3+,Al3+ Co-doped ZnO Nano-particles

ZHOU Yin;WANG Yu;LU Shi-xiang;XU Wen-guo;SU Su   

  • Online:2009-08-15 Published:2021-01-20

摘要: 采用溶胶-凝胶法制备了不掺杂和掺杂铝离子、镧离子以及两种离子共掺杂的ZnO,并用X射线衍射(XRD),高分辨透射电镜(HRTEM),紫外-可见(UV-Vis)吸收光谱对其进行了表征.用紫外灯作为光源,一定浓度的活性艳蓝X-BR溶液为光催化反应模型污染物,研究了各种离子掺杂ZnO的光催化性能,考察了掺杂量对降解率的影响.结果表明,镧离子和铝离子掺杂浓度为2 at;和3 at;的共搀杂ZnO的光催化性能最好;在室温下,加入催化剂浓度为0.1 g/L,降解时间为45 min时,对活性艳蓝X-BR溶液的降解率达到96.63;.

关键词: 溶胶-凝胶;纳米氧化锌;光催化降解;镧铝共掺杂

Abstract: Nanoparticles of ZnO doped with La3+, Al3+, co-doped with La3+ and Al3+ were prepared by the sol-gel method. The samples were characterized by X-ray diffraction (XRD), high resolution transmission electron microscope(HRTEM) and UV-Vis absorption spectroscopy. The photocatalytic performance of different ZnO particles was studied using ultraviolet lamp as illumination device and reactive brilliant blue X-BR as stimulant pollutant.The highest photoactivity was obtained at optimal concentration (2 at; La3+ and 3 at; Al3+). The degradation rate of reactive brilliant blue X-BR could get to 96.63; in 45 min at room temperature under the concentration of catalyst was 0.1g/L.

Key words: Nanoparticles of ZnO doped with La3+, Al3+, co-doped with La3+ and Al3+ were prepared by the sol-gel method. The samples were characterized by X-ray diffraction (XRD), high resolution transmission electron microscope(HRTEM) and UV-Vis absorption spectroscopy. The photocatalytic performance of different ZnO particles was studied using ultraviolet lamp as illumination device and reactive brilliant blue X-BR as stimulant pollutant.The highest photoactivity was obtained at optimal concentration (2 at; La3+ and 3 at; Al3+). The degradation rate of reactive brilliant blue X-BR could get to 96.63; in 45 min at room temperature under the concentration of catalyst was 0.1g/L.

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