弛豫铁电单晶的生长及性能优化研究进展

人工晶体学报 ›› 2022, Vol. 51 ›› Issue (9-10): 1643-1658.

所属专题：钙钛矿单晶与薄膜材料

弛豫铁电单晶的生长及性能优化研究进展

刘杨彬, 李谦, 肖若愚, 徐卓, 李飞

西安交通大学,多功能材料与结构教育部重点实验室,西安 710049

收稿日期:2022-08-30 出版日期:2022-10-15 发布日期:2022-11-02
通信作者: 徐卓,博士,教授。E-mail:xuzhuo@xjtu.edu.cn
李飞,博士,教授。E-mail:ful5@xjtu.edu.cn
作者简介:刘杨彬(1991—),男,陕西省人,博士研究生。E-mail:liu252573944@gmail.com。
徐卓,西安交通大学电信学院教授,电子陶瓷与器件教育部重点实验室副主任。1982年毕业于西北大学物理系,现任中国物理学会电介质物理专业委员会委员和中国电工学会工程电介质专业委员会委员,先后从事大学物理和理论物理教学工作和电子材料的研究工作,参加过国家自然科学基金重点项目、负责承担了军工配套项目、国防预研项目和国防预研基金、863重大项目和陕西省自然科学基金项目等10多项科研项目,曾获国家自然科学二等奖、教育部自然科学一等奖等多项学术奖励。
李飞,2006年本科毕业于西安交通大学电子科学与技术系,2012年获得西安交通大学微电子与固体电子学博士学位,并留校任教,现任《人工晶体学报》青年编委。长期从事铁电压电材料与器件研究,在弛豫铁电单晶高压电效应的起源、弛豫铁电单晶与陶瓷材料的高性能化等方面取得了一系列创新性研究成果,曾获国家自然科学二等奖、中国物理学会电介质物理专委会“优秀青年”、IEEE UFFC青年讲席学者、美国陶瓷学会Ross Coffin Purdy奖等学术荣誉。
基金资助:
国家自然科学基金(51922083)

Research Progress on the Growth and Property Optimization of Relaxor Ferroelectric Single Crystals

LIU Yangbin, LI Qian, XIAO Ruoyu, XU Zhuo, LI Fei

Electronic Materials Research Laboratory, Key Laboratory of the Ministry of Education, Xi’an Jiaotong University, Xi’an 710049, China

Received:2022-08-30 Online:2022-10-15 Published:2022-11-02

摘要/Abstract

摘要： 钙钛矿型(ABO₃)弛豫铁电单晶具有优异的机电耦合性能,被认为是研制下一代医疗超声换能器、高精度压电驱动器、水声换能器等机电耦合器件的核心关键材料。针对弛豫铁电单晶材料制备与物理性能方面尚存在的基础科学与工艺问题,本文综述了近些年弛豫铁电单晶生长与性能优化方面的研究进展,包括若干新的单晶生长方法用以改善弛豫铁电单晶的成分和性能均匀性,提升弛豫铁电单晶压电性能的系列新方法,通过铁电畴结构调控以获得高透光率的弛豫铁电单晶,以及高性能弛豫铁电单晶在电光技术领域的应用等。

关键词: 弛豫铁电体, 单晶生长, 布里奇曼法, 畴工程, 掺杂, 性能优化, 压电性能

Abstract: Relaxor ferroelectric single crystals with perovskite (ABO₃) structure possess excellent electromechanical coupling properties and are considered as the key materials of next-generation medical ultrasound transducers, high-precision piezoelectric actuators, and underwater acoustic transducers. According to the existing fundamental science and material preparation issues in relaxor ferroelectric crystals, this manuscript reviews the research progresses on the crystal growth and property optimization of relaxor ferroelectric singles in recent years. This review covers the following aspects: new crystal growth methods for enhancing the uniformity of composition and properties; new methods to improve the piezoelectric properties of relaxor ferroelectric single crystals; the control of ferroelectric domain structure to achieve high-light transmittance of relaxor ferroelectric crystals; the application of high-performance relaxor ferroelectric single crystals in the field of electro-optical technology.

Key words: relaxor ferroelectric, single crystal growth, Bridgman method, domain engineering, doping, property optimization, piezoelectric property

中图分类号:

TM22

刘杨彬, 李谦, 肖若愚, 徐卓, 李飞. 弛豫铁电单晶的生长及性能优化研究进展[J]. 人工晶体学报, 2022, 51(9-10): 1643-1658.

LIU Yangbin, LI Qian, XIAO Ruoyu, XU Zhuo, LI Fei. Research Progress on the Growth and Property Optimization of Relaxor Ferroelectric Single Crystals[J]. Journal of Synthetic Crystals, 2022, 51(9-10): 1643-1658.

参考文献

[1] ZHANG Z, XU J L, YANG L L, et al. Design and comparison of PMN-PT single crystals and PZT ceramics based medical phased array ultrasonic transducer[J]. Sensors and Actuators A: Physical, 2018, 283: 273-281.
[2] 莫喜平.第三讲让声纳系统耳目一新:新型水声换能器与换能器新技术[J].物理,2006,35(5):414-419.
MO X P. Innovations for sonar: new technology and designs for underwater acoustic transducers[J]. Physics, 2006, 35(5): 414-419(in Chinese).
[3] PENG C, WU H Y, KIM S, et al. Recent advances in transducers for intravascular ultrasound (IVUS) imaging[J]. Sensors, 2021, 21(10): 3540.
[4] HUANG Y, ZHANG S J, WANG P H, et al. Hi-fi stake piezo single crystal actuator[J]. Actuators, 2018, 7(3): 60.
[5] BAASANDORJ L, CHEN Z B. Recent developments on relaxor-PbTiO₃ ferroelectric crystals[J]. Crystals, 2021, 12(1): 56.
[6] ZHANG S J, LI F, JIANG X N, et al. Advantages and challenges of relaxor-PbTiO₃ ferroelectric crystals for electroacoustic transducers-A review[J]. Progress in Materials Science, 2015, 68: 1-66.
[7] SONG K X, LI Q, GUO H S, et al. Composition and electrical properties characterization of a 5” diameter PIN-PMN-PT single crystal by the modified Bridgman method[J]. Journal of Alloys and Compounds, 2021, 851: 156145.
[8] FAN H Q, ZHAO L L, TANG B, et al. Growth and characterization of PMNT relaxor-based ferroelectric single crystals by flux method[J]. Materials Science and Engineering: B, 2003, 99(1/2/3): 183-186.
[9] MATSUSHITATA M, ECHIZENYA K. Continuous feeding growth of ternary PIN-PMN-PT single crystals[C]. IEEE, 2014.
[10] ECHIZENYA K, MATSUSHITA M. Continuous feed growth and characterization of PMN-PT single crystals[C]//2011 IEEE International Ultrasonics Symposium. Orlando, FL, USA. IEEE,: 1813-1816.
[11] ECHIZENYA K, NAKAMURA K, MIZUNO K. PMN-PT and PIN-PMN-PT single crystals grown by continuous-feeding Bridgman method[J]. Journal of Crystal Growth, 2020, 531: 125364.
[12] KANG S J L, PARK J H, KO S Y, et al. Solid-state conversion of single crystals: the principle and the state-of-the-art[J]. Journal of the American Ceramic Society, 2015, 98(2): 347-360.
[13] 江民红,倪双阳,姚小玉,等.固相晶体生长技术的发展:从籽晶诱导到无籽晶生长[J].人工晶体学报,2020,49(6):965-978.
JIANG M H, NI S Y, YAO X Y, et al. Development of solid-state crystal growth technology: from seed-induced to seed-free growth[J]. Journal of Synthetic Crystals, 2020, 49(6): 965-978(in Chinese).
[14] KIM Y M, LEE S H, LEE H Y, et al. Measurement of all the material properties of PMN-PT single crystals grown by the solid-state-crystal-growth (SSCG) method[C]//IEEE Symposium on Ultrasonics. Honolulu, HI, USA. IEEE,: 1987-1990.
[15] ZHANG S J, LEE S M, KIM D H, et al. Characterization of Mn-modified Pb(Mg_1/3Nb_2/3)O₃-PbZrO₃-PbTiO₃ single crystals for high power broad bandwidth transducers[J]. Applied Physics Letters, 2008, 93(12): 122908.
[16] Ceracomp Company Ltd.Ceracomp-PMNT PSC Brochure [EB/OL].[2015-09-21]. http://www.ceracomp.com/.
[17] ZAWILSKI K T, DEMATTEI R C, FEIGELSON R S. Zone leveling of lead magnesium niobate-lead titanate crystals using RF heating[J]. Journal of Crystal Growth, 2005, 277(1/2/3/4): 393-400.
[18] LUO J, ZHANG S J, SHROUT T R, et al. Advances in manufacturing relaxor piezoelectric single crystals[C]//2007 Sixteenth IEEE International Symposium on the Applications of Ferroelectrics. Nara, Japan. IEEE: 557-560.
[19] LI F, CABRAL M J, XU B, et al. Giant piezoelectricity of Sm-doped Pb(Mg_1/3Nb_2/3)O₃-PbTiO₃ single crystals[J]. Science, 2019, 364(6437): 264-268.
[20] LEE H Y, ZHANG S J, SHROUT T R. Development of high TC PMN-PZT piezoelectric single crystals by the solid-state crystal growth (SSCG) technique[C]//2008 17th IEEE International Symposium on the Applications of Ferroelectrics. Santa Re, NM, USA. IEEE,: 1-2.
[21] CHEN H B, LIANG Z, LUO L H, et al. Bridgman growth, crystallographic characterization and electrical properties of relaxor-based ferroelectric single crystal PIMNT[J]. Journal of Alloys and Compounds, 2012, 518: 63-67.
[22] CHEN J W, LI X B, ZHAO X Y, et al. Compositional segregation, structural transformation and property-temperature relationship of high-Curie temperature Pb(In_1/2Nb_1/2)O₃-Pb(Mg_1/3Nb_2/3)O₃-PbTiO₃ single crystals[J]. Journal of Materials Science: Materials in Electronics, 2015, 26(12): 9316-9328.
[23] SRIMATHY B, KUMAR J. Effect of donor dopants on the properties of flux grown PZN-PT single crystals[J].Applied Physics A, 2021, 127(6): 1-7.
[24] LI F, LIN D B, CHEN Z B, et al. Ultrahigh piezoelectricity in ferroelectric ceramics by design[J]. Nature Materials, 2018, 17(4): 349-354.
[25] OH H T, JOO H J, KIM M C, et al. Effect of Mn on dielectric and piezoelectric properties of 71PMN-29PT[71Pb(Mg_1/3Nb_2/3)O₃-29PbTiO₃]single crystals and polycrystalline ceramics[J]. Journal of the Korean Ceramic Society, 2018, 55(2): 166-173.
[26] XIONG J J, WANG Z J, YANG X M, et al. Improvement of temperature-stability and piezoelectric performance of Pb(In_0.5Nb_0.5)O₃-PbTiO₃ crystals via Nd doping[J]. Ceramics International, 2021, 47(14): 19575-19581.
[27] LI C C, XU B, LIN D B, et al. Atomic-scale origin of ultrahigh piezoelectricity in samarium-doped PMN-PT ceramics[J]. Physical Review B, 2020, 101(14): 140102.
[28] LI Q, LIU Y B, LIU J F, et al. Enhanced piezoelectric properties and improved property uniformity in Nd-doped PMN-PT relaxor ferroelectric single crystals[J]. Advanced Functional Materials, 2022, 32(25): 2201719.
[29] XIONG J J, WANG Y Q, YANG X M, et al. Significant performance enhancement of Nd-doped Pb(In_0.5Nb_0.5)O₃-PbTiO₃ ferroelectric crystals[J]. CrystEngComm, 2022, 24(24): 4341-4345.
[30] 李飞,张树君,李振荣,等.弛豫铁电单晶的研究进展—压电效应的起源研究[J].物理学进展,2012,32(4):178-198.
LI F, ZHANG S J, LI Z R, et al. Recent development on relaxor-PbTiO₃ single crystals: the origin of high piezoelectric response[J]. Progress in Physics, 2012, 32(4): 178-198(in Chinese).
[31] WADA S, YAKO K, KAKEMOTO H, et al. Enhanced piezoelectric property of BaTiO₃ single crystals with the different domain sizes[J]. Key Engineering Materials, 2004, 269: 19-22.
[32] WADA S, YAKO K, KAKEMOTO H, et al. Enhanced piezoelectric properties of barium titanate single crystals with different engineered-domain sizes[J]. Journal of Applied Physics, 2005, 98(1): 014109.
[33] BELL A J, SHEPLEY P M, LI Y. Domain wall contributions to piezoelectricity in relaxor-lead titanate single crystals[J]. Acta Materialia, 2020, 195: 292-303.
[34] RAO W F, WANG Y U. Bridging domain mechanism for phase coexistence in morphotropic phase boundary ferroelectrics[J]. Applied Physics Letters, 2007, 90(18): 182906.
[35] SLUKA T, TAGANTSEV A K, DAMJANOVIC D, et al. Enhanced electromechanical response of ferroelectrics due to charged domain walls[J]. Nature Communications, 2012, 3: 748.
[36] ONDREJKOVIC P, MARTON P, GUENNOU M, et al. Piezoelectric properties of twinned ferroelectric perovskites with head-to-head and tail-to-tail domain walls[J]. Physical Review B, 2013, 88(2): 024114.
[37] WANG B, LI F, CHEN L Q. Inverse domain-size dependence of piezoelectricity in ferroelectric crystals[J]. Advanced Materials, 2021, 33(51): e2105071.
[38] LI F, WANG L H, JIN L, et al. Achieving single domain relaxor-PT crystals by high temperature poling[J]. CrystEngComm, 2014, 16(14): 2892-2897.
[39] XIONG J J, WANG Z J, YANG X M, et al. Performance enhancement of Pb(In_1/2Nb_1/2)O₃-PbTiO₃ ferroelectric single crystals using pulse poling[J]. Scripta Materialia, 2022, 215: 114694.
[40] YAMASHITA Y. Piezoelectric transducer, ultrasonic probe, and piezoelectric transducer manufacturing method: USA, 20150372219[Z]. 2015.
[41] QIU C R, WANG B, ZHANG N, et al. Transparent ferroelectric crystals with ultrahigh piezoelectricity[J]. Nature, 2020, 577(7790): 350-354.
[42] QIU C R, XU Z, AN Z Y, et al. In-situ domain structure characterization of Pb(Mg_1/3Nb_2/3)O₃-PbTiO₃ crystals under alternating current electric field poling[J]. Acta Materialia, 2021, 210: 116853.
[43] WAN H T, LUO C T, LIU C, et al. Alternating current poling on sliver-mode rhombohedral Pb(Mg_1/3Nb_2/3)O₃-PbTiO₃ single crystals[J]. Acta Materialia, 2021, 208: 116759.
[44] XU J L, DENG H, ZENG Z, et al. Piezoelectric performance enhancement of Pb(Mg_1/3Nb_2/3)O₃-0.25PbTiO₃ crystals by alternating current polarization for ultrasonic transducer[J]. Applied Physics Letters, 2018, 112(18): 182901.
[45] CHANG W Y, CHUNG C C, LUO C T, et al. Dielectric and piezoelectric properties of 0.7Pb(Mg_1/3Nb_2/3)O₃-0.3PbTiO₃ single crystal poled using alternating current[J]. Materials Research Letters, 2018, 6(10): 537-544.
[46] WAN H T, LUO C T, CHANG W Y, et al. Effect of poling temperature on piezoelectric and dielectric properties of 0.7Pb(Mg_1/3Nb_2/3)O₃-0.3PbTiO₃ single crystals under alternating current poling[J]. Applied Physics Letters, 2019, 114(17): 172901.
[47] LUO C T, WAN H T, CHANG W Y, et al. Effect of low-frequency alternating current poling on 5-mm-thick 0.7Pb(Mg_1/3Nb_2/3)O₃-0.3PbTiO₃ single crystals [J]. Applied Physics Letters, 2019, 115(26): 269901.
[48] WAN H T, LUO C T, CHUNG C C, et al. Enhanced dielectric and piezoelectric properties of Manganese-doped Pb(In_1/2Nb_1/2)O₃-Pb(Mg_1/3Nb_2/3)O₃-PbTiO₃ single crystals by alternating current poling[J]. Applied Physics Letters, 2021, 118(10): 102904.
[49] QIU C R, LIU J F, LI F, et al. Thickness dependence of dielectric and piezoelectric properties for alternating current electric-field-poled relaxor-PbTiO₃ crystals[J]. Journal of Applied Physics, 2019, 125(1): 014102.
[50] MA M, XIA S, SONG K X, et al. Enhanced dielectric and piezoelectric properties in the[001]-poled 0.25Pb(In_1/2Nb_1/2)O₃-0.43Pb(Mg_1/3Nb_2/3)O₃-0.32PbTiO₃ single crystal near morphotropic phase boundary by alternating current treatment[J]. Journal of Applied Physics, 2020, 127(6): 064106.
[51] LIU J F, QIU C R, QIAO L, et al. Impact of alternating current electric field poling on piezoelectric and dielectric properties of Pb(In_1/2Nb_1/2)O₃-Pb(Mg_1/3Nb_2/3)O₃-PbTiO₃ ferroelectric crystals[J]. Journal of Applied Physics, 2020, 128(9): 94104.
[52] ZHAO K, ZHENG M P, YAN X D, et al. Effect of direct current and alternating current poling on the piezoelectric properties of Ba_0.85Ca_0.15Ti_0.9Zr_0.1O₃ ceramics[J]. Journal of Materials Science: Materials in Electronics, 2021, 32(23): 27815-27822.
[53] EIMERL D. Electro-optic, linear, and nonlinear optical properties of KDP and its isomorphs[J]. Ferroelectrics, 1987, 72(1): 95-139.
[54] WEN X H, QI Y, MENG X Y. DFT study on the clamped linear electro-optic effect in KH₂PO₄[C]//Proceedings of 2011 International Conference on Electronics and Optoelectronics. Dalian, China. IEEE: V4-53.
[55] MASHKOVICH E A, SHUGUROV A I, OZAWA S, et al. Noncollinear electro-optic sampling of terahertz waves in a thick GaAs crystal[J]. IEEE Transactions on Terahertz Science and Technology, 2015, 5(5): 732-736.
[56] ZENG R, ZHUANG C J, NIU B, et al. Measurement of transient electric fields in air gap discharge with an integrated electro-optic sensor[J]. IEEE Transactions on Plasma Science, 2013, 41(4): 955-960.
[57] 罗豪甦,焦杰,陈瑞,等.弛豫铁电单晶的多功能特性及其器件应用[J].人工晶体学报,2021,50(5):783-802.
LUO H S, JIAO J, CHEN R, et al. Multifunctional properties and device applications of the relaxor ferroelectric single crystals[J]. Journal of Synthetic Crystals, 2021, 50(5): 783-802(in Chinese).
[58] 王继扬,黄林勇,覃方丽,等.电光晶体研究进展及其对称性究[J].物理学进展,2012,32(1):33-56.
WANG J Y, HUANG L Y, QIN F L, et al. Progress of the electro-optic crystal research and the symmetry dependence of electro-optic effect[J]. Progress in Physics, 2012, 32(1): 33-56(in Chinese).
[59] SMOLENSKII G A, BEREZHNOI A A, KRAINIK N N, et al. Electro-optical properties of perovskite-type ferroelectric crystals of complex composition[J]. Bulletin of the Academy of Sciences of the USSR. 1969, 33(2): 258-260.
[60] SMOLENSKII G A, BEREZHNOI A A, PISAREV R V, et al. Anomalous dispersion of the electro-optical effect in ferroelectric PbNi_1/2Nb_2/3O₃[J]. Fizika Tverdogo Tela. 1969, 11(5): 1120-1123.
[61] LU Y, CHENG Z Y, PARK S E, et al. Linear electro-optic effect of 0.88Pb(Zn_1/3Nb_2/3)O₃-0.12PbTiO₃ single crystal[J]. Japanese Journal of Applied Physics, 2000, 39(Part 1, No. 1): 141-145.
[62] LU Y, CHENG Z Y, BARAD Y, et al. Photoelastic effects in tetragonal Pb(Zn_1/3Nb_2/3)O₃-PbTiO₃ single crystals near the morphotropic phase boundary[J]. Journal of Applied Physics, 2001, 89(9): 5075-5078.
[63] BARAD Y, LU Y, CHENG Z Y, et al. Composition, temperature, and crystal orientation dependence of the linear electro-optic properties of Pb(Zn_1/3Nb_2/3)O₃-PbTiO₃ single crystals[J]. Applied Physics Letters, 2000, 77(9): 1247-1249.
[64] WAN X M, CHAN H L W, CHOY C L, et al. Optical properties of (1-x)Pb(Mg_1/3Nb_2/3)O_3-xPbTiO₃ single crystals studied by spectroscopic ellipsometry[J]. Journal of Applied Physics, 2004, 96(3): 1387-1391.
[65] WAN X M, LUO H S, WANG J, et al. Investigation on optical transmission spectra of (1-x)Pb(Mg_1/3Nb_2/3)O₃-xPbTiO₃ single crystals[J]. Solid State Communications, 2004, 129(6): 401-405.
[66] HE C J, ZHOU Z X, LIU D J, et al. Photorefractive effect in relaxor ferroelectric 0.62Pb(Mg_1/3Nb_2/3)O₃-0.38PbTiO₃ single crystal[J]. Applied Physics Letters, 2006, 89(26): 261111.
[67] HE C J, TANG Y X, ZHAO X Y, et al. Optical dispersion properties of tetragonal relaxor ferroelectric single crystals 0.65Pb(Mg_1/3Nb_2/3)O₃-0.35PbTiO₃[J]. Optical Materials, 2007, 29(8): 1055-1057.
[68] WU F M, YANG B, SUN E W, et al. Optical properties and dispersions of rhombohedral 0.24Pb(In_1/2Nb_1/2)O₃-0.49Pb(Mg_1/3Nb_2/3)O₃-0.27PbTiO₃ single domain single crystal[J]. Optical Materials, 2013, 36(2): 342-345.
[69] LIU X, TAN P, MA X, et al. Ferroelectric crystals with giant electro-optic property enabling ultracompact Q-switches[J]. Science, 2022, 376(6591): 371-377.

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Research Progress on the Growth and Property Optimization of Relaxor Ferroelectric Single Crystals

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