铜基硫化物光催化改性研究进展

摘要/Abstract

摘要： 铜基硫化物禁带宽度窄,具有局域表面等离子体共振效应,对可见光有良好的吸收能力,且储量丰富、无毒,这些优势使铜基硫化物光催化剂引起了研究者们的广泛关注。然而,铜基硫化物光生电子和空穴复合速率高,可见光利用效率低,阻碍了其在光催化领域的应用,因此研究者们尝试了不同的改性策略提高其光催化性能。本文综述了铜基硫化物的改性策略,主要论述了形貌调控、晶相调控、半导体异质结等方式对铜基硫化物光催化性能的改性,分析了不同改性方法对铜基硫化物光催化性能提高的作用,以及铜基硫化物在光催化降解有机污染物、光解水产氢、光催化还原CO₂等方面的应用,并对铜基硫化物改性研究方向做出了展望。

关键词: 铜基硫化物, 光催化, 降解, 光生载流子, 异质结, 纳米复合材料

Abstract: Copper based sulfide photocatalysts have attracted extensive attention of researchers due to their narrow band gap, local surface plasmon resonance effect, good absorption ability to visible light, rich in reserves and non-toxic properties. However, the high recombination rate of photogenerated electrons and holes, and the low utilization efficiency of visible light hinder their application in the field of photocatalysis. Therefore, researchers have tried different modification strategies to improve their photocatalytic performance. This paper focuses on the modification strategies of copper based sulfides, mainly discusses the modification of the photocatalytic performance of copper based sulfides by morphology regulation, crystal phase regulation, and semiconductor heterojunction, etc., and analyzes the effect of different modification methods on the improvement of the photocatalytic performance. The application of copper based sulfides in the photocatalytic degradation of organic pollutants, photocatalytic splitting water for hydrogen production, photocatalytic reduction of CO₂, etc. are discussed, and the development direction of copper based sulfide modification is prospected.

Key words: copper based sulfide, photocatalytic, degradation, photocarrier, heterojunction, nanocomposite

中图分类号:

余海燕, 梁海欧, 白杰, 李春萍. 铜基硫化物光催化改性研究进展[J]. 人工晶体学报, 2023, 52(3): 394-404.

YU Haiyan, LIANG Haiou, BAI Jie, LI Chunping. Research Progress of Photocatalytic Modification of Copper Based Sulfides[J]. Journal of Synthetic Crystals, 2023, 52(3): 394-404.

参考文献

[1] SAYED M, YU J G, LIU G, et al. Non-noble plasmonic metal-based photocatalysts[J]. Chemical Reviews, 2022, 122(11): 10484-10537.
[2] 王启明, 王迪, 孙洪全, 等. 制备方法对量子点敏化太阳能电池CuS纳米晶对电极微观结构和性能的影响[J]. 硅酸盐学报, 2020, 48(3): 434-441.
WANG Q M, WANG D, SUN H Q, et al. Microstructure and property of CuS nanocrystalline counter electrode in quantum dot sensitized cells[J]. Journal of the Chinese Ceramic Society, 2020, 48(3): 434-441 (in Chinese).
[3] SANDS T D, WASHBURN J, GRONSKY R. High resolution observations of copper vacancy ordering in chalcocite (Cu₂S) and the transformation to djurleite (Cu_1.97 to 1.94 S)[J]. Physica Status Solidi (a), 1982, 72(2): 551-559.
[4] KAR P, FARSINEZHAD S, ZHANG X J, et al. Anodic Cu₂S and CuS nanorod and nanowall arrays: preparation, properties and application in CO₂ photoreduction[J]. Nanoscale, 2014, 6(23): 14305-14318.
[5] 胡铭华, 田华, 贺军辉. 硫化铜空心纳米球的融硫修饰及其对水中Hg²⁺的高选择性吸附富集[J]. 无机化学学报, 2020, 36(4): 695-702.
HU M H, TIAN H, HE J H. Sulfur-infused modification and highly selective enrichment of Hg²⁺ from aqueous solutions of CuS hollow nanospheres[J]. Chinese Journal of Inorganic Chemistry, 2020, 36(4): 695-702 (in Chinese).
[6] ROY P, SRIVASTAVA S K. Nanostructured copper sulfides: synthesis, properties and applications[J]. CrystEngComm, 2015, 17(41): 7801-7815.
[7] COMIN A, MANNA L. New materials for tunable plasmonic colloidal nanocrystals[J]. Chemical Society Reviews, 2014, 43(11): 3957-3975.
[8] 陈建金, 齐东丽, 刘俊, 等. 射频磁控溅射制备高In组分Al_1-xIn_xN薄膜及其光学性能[J]. 硅酸盐学报, 2021, 49(9): 1970-1975.
CHEN J J, QI D L, LIU J, et al. Growth and optical properties of In-rich Al_1-xIn_xN films by radio-frequency magnetron sputtering[J]. Journal of the Chinese Ceramic Society, 2021, 49(9): 1970-1975 (in Chinese).
[9] LU X Y, DENG F, LIU M, et al. The regulation on visible-light photocatalytic activity of CuInS₂ by different Cu/In molar ratio[J]. Materials Chemistry and Physics, 2018, 212: 372-377.
[10] NAKAMURA Y, ISO Y, ISOBE T. Bandgap-tuned CuInS₂/ZnS core/shell quantum dots for a luminescent downshifting layer in a crystalline silicon solar module[J]. ACS Applied Nano Materials, 2020, 3(4): 3417-3426.
[11] HADKE S, HUANG M L, CHEN C, et al. Emerging chalcogenide thin films for solar energy harvesting devices[J]. Chemical Reviews, 2022, 122(11): 10170-10265.
[12] XU W, XIE Z Z, HAN W J, et al. Rational design of interfacial energy level matching for CuGaS₂ based photocatalysts over hydrogen evolution reaction[J]. International Journal of Hydrogen Energy, 2022, 47(23): 11853-11862.
[13] SHAHZAD K, TAHIR M B, SAGIR M, et al. Synthesis of novel p-n heterojunction Cu₂SnS₃/Ti³⁺-TiO₂ for the complete tetracycline degradation in few minutes and photocatalytic activity under simulated solar irradiation[J]. Ceramics International, 2021, 47(22): 31337-31348.
[14] WANG J Y, BO T T, SHAO B Y, et al. Effect of S vacancy in Cu₃SnS₄ on high selectivity and activity of photocatalytic CO₂ reduction[J]. Applied Catalysis B: Environmental, 2021, 297: 120498.
[15] MAICUS M, LOPEZ E, SANCHEZ M C, et al. Magnetostatic energy calculations in two- and three-dimensional arrays of ferromagnetic prisms[J]. IEEE Transactions on Magnetics, 1998, 34(3): 601-607.
[16] HASANVANDIAN F, ZEHTAB SALMASI M, MORADI M, et al. Enhanced spatially coupling heterojunction assembled from CuCo₂S₄ yolk-shell hollow sphere capsulated by Bi-modified TiO₂ for highly efficient CO₂ photoreduction[J]. Chemical Engineering Journal, 2022, 444: 136493.
[17] MAO M, XU J, YU X B, et al. A Z-type heterojunction of bimetal sulfide CuNi₂S₄ and CoWO₄ for catalytic hydrogen evolution[J]. Dalton Transactions, 2020, 49(19): 6457-6470.
[18] JIANG R R, LU G H, NKOOM M, et al. Mineralization and toxicity reduction of the benzophenone-1 using 2D/2D Cu₂WS₄/BiOCl Z-scheme system: simultaneously improved visible-light absorption and charge transfer efficiency[J]. Chemical Engineering Journal, 2020, 400: 125913.
[19] RAZA A, SHEN H L, HAIDRY A A. Novel Cu₂ZnSnS₄/Pt/g-C₃N₄ heterojunction photocatalyst with straddling band configuration for enhanced solar to fuel conversion[J]. Applied Catalysis B: Environmental, 2020, 277: 119239.
[20] 鲍二蓬, 张硕卿, 邹吉军, 等. 特殊形貌光催化剂的研究进展[J]. 化学工业与工程, 2021, 38(2): 19-29.
BAO E P, ZHANG S Q, ZOU J J, et al. Research progress on special-morphology photocatalysts[J]. Chemical Industry and Engineering, 2021, 38(2): 19-29 (in Chinese).
[21] EKIMOV A I, EFROS A L, ONUSHCHENKO A A. Quantum size effect in semiconductor microcrystals[J]. Solid State Communications, 1985, 56(11): 921-924.
[22] LI S, GE Z H, ZHANG B P, et al. Mechanochemically synthesized sub-5 nm sized CuS quantum dots with high visible-light-driven photocatalytic activity[J]. Applied Surface Science, 2016, 384: 272-278.
[23] 岳阳阳, 韦毅, 邓明龙, 等. 构造CuO/Cu₂S复合微纳米晶材料及其光催化性能研究[J]. 化工新型材料, 2020, 48(7): 114-118+123.
YUE Y Y, WEI Y, DENG M L, et al. Study on preparation and photocatalytic property of CuO/Cu₂S micro-nanocrystal composite[J]. New Chemical Materials, 2020, 48(7): 114-118+123 (in Chinese).
[24] ZHANG Y M, YANG X Y, WANG Y L, et al. Insight into l-cysteine-assisted growth of Cu₂S nanoparticles on exfoliated MoS₂ nanosheets for effective photoreduction removal of Cr(VI)[J]. Applied Surface Science, 2020, 518: 146191.
[25] KAPURIA N, PATIL N N, RYAN K M, et al. Two-dimensional copper based colloidal nanocrystals: synthesis and applications[J]. Nanoscale, 2022, 14(8): 2885-2914.
[26] ZOU J, LIAO G D, JIANG J Z, et al. Controllable interface engineering of g-C₃N₄/CuS heterojunction photocatalysts[J]. Social Science Electronic Publishing, 2019, 32: 178.
[27] LIU Z M, LIU J, HUANG Y B, et al. From one-dimensional to two-dimensional wurtzite CuGaS₂ nanocrystals: non-injection synthesis and photocatalytic evolution[J]. Nanoscale, 2018, 11(1): 158-169.
[28] LI Y M, LIU J, LI X Y, et al. Evolution of hollow CuInS₂ nanododecahedrons via kirkendall effect driven by cation exchange for efficient solar water splitting[J]. ACS Applied Materials & Interfaces, 2019, 11(30): 27170-27177.
[29] DING Y, CHEN Y J, GUAN Z F, et al. Hierarchical CuS@ZnIn₂S₄ hollow double-shelled p-n heterojunction octahedra decorated with fullerene C₆₀ for remarkable selectivity and activity of CO₂ photoreduction into CH₄[J]. ACS Applied Materials & Interfaces, 2022, 14(6): 7888-7899.
[30] 欧金花, 胡波年, 周唤宇, 等. 透明Cu₂S@氮掺杂碳纳米片用于双面量子点敏化太阳能电池对电极的性能[J]. 硅酸盐学报, 2020, 48(10): 1581-1588.
OU J H, HU B N, ZHOU H Y, et al. Performance of transparent Cu₂S@N-doped carbon film as counter electrode for bifacial quantum dot solar cells[J]. Journal of the Chinese Ceramic Society, 2020, 48(10): 1581-1588 (in Chinese).
[31] SANTAMARIA-PEREZ D, GARBARINO G, CHULIA-JORDAN R, et al. Pressure-induced phase transformations in mineral chalcocite, Cu₂S, under hydrostatic conditions[J]. Journal of Alloys and Compounds, 2014, 610: 645-650.
[32] YANG X, JIANG S Q, ZHANG H C, et al. Pressure-induced structural phase transition and electrical properties of Cu₂S[J]. Journal of Alloys and Compounds, 2018, 766: 813-817.
[33] CAO Q, CHE R C, CHEN N. Scalable synthesis of Cu₂S double-superlattice nanoparticle systems with enhanced UV/visible-light-driven photocatalytic activity[J]. Applied Catalysis B: Environmental, 2015, 162: 187-195.
[34] TELKHOZHAYEVA M, KONAR R, LAVI R, et al. Phase-dependent photocatalytic activity of bulk and exfoliated defect-controlled flakes of layered copper sulfides under simulated solar light[J]. ACS Sustainable Chemistry & Engineering, 2021, 9(48): 16103-16114.
[35] 张转芳, 唐林, 孙立, 等. CuS/GO纳米复合材料的制备及光催化降解性能[J]. 精细化工, 2019, 36(2): 237-242.
ZHANG Z F, TANG L, SUN L, et al. Preparation of CuS/GO nanocomposite and its photocatalytic degradation activity[J]. Fine Chemicals, 2019, 36(2): 237-242 (in Chinese).
[36] FAKHRAVAR S, FARHADIAN M, TANGESTANINEJAD S. Excellent performance of a novel dual Z-scheme Cu₂S/Ag₂S/BiVO₄ heterostructure in metronidazole degradation in batch and continuous systems: immobilization of catalytic particles on α-Al₂O₃ fiber[J]. Applied Surface Science, 2020, 505: 144599.
[37] 申久英, 刘碧雯, 赵宇翔, 等. CuS-Bi₂WO₆/活性纳米碳纤维的制备及其光催化性能[J]. 复合材料学报, 2022, 39(3): 1163-1172.
SHEN J Y, LIU B W, ZHAO Y X, et al. Preparation and photocatalytic properties CuS-Bi₂WO₆/carbon nanofibers composites[J]. Acta Materiae Compositae Sinica, 2022, 39(3): 1163-1172 (in Chinese).
[38] 李仁杰, 李园利, 李茜娅, 等.CuInS₂/CdS基掺杂纳米晶的晶体结构、光谱性质及性能调控研究[J]. 化学研究与应用, 2021, 33(4): 699-707.
LI R J, LI Y L, LI X Y, et al. Crystal structure, spectral properties and performance tailoring of CuInS₂/CdS based doped colloidal nanocrystals[J]. Chemical Research and Application, 2021, 33(4): 699-707 (in Chinese).
[39] ZHANG X J, GUO Y C, TIAN J, et al. Controllable growth of MoS₂ nanosheets on novel Cu₂S snowflakes with high photocatalytic activity[J]. Applied Catalysis B: Environmental, 2018, 232: 355-364.
[40] KAUSHIK B, YADAV S, RANA P, et al. Precisely engineered type II ZnO-CuS based heterostructure: a visible light driven photocatalyst for efficient mineralization of organic dyes[J]. Applied Surface Science, 2022, 590: 153053.
[41] YUE Y M, ZHANG P X, WANG W, et al. Enhanced dark adsorption and visible-light-driven photocatalytic properties of narrower-band-gap Cu₂S decorated Cu₂O nanocomposites for efficient removal of organic pollutants[J]. Journal of Hazardous Materials, 2020, 384: 121302.
[42] TANG Q Y, CHEN W F, LV Y R, et al. Z-scheme hierarchical Cu₂S/Bi₂WO₆ composites for improved photocatalytic activity of glyphosate degradation under visible light irradiation[J]. Separation and Purification Technology, 2020, 236: 116243.
[43] ZHANG R, YU J R, ZHANG T Q, et al. A novel snowflake dual Z-scheme Cu₂S/RGO/Bi₂WO₆ photocatalyst for the degradation of bisphenol A under visible light and its effect on crop growth[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2022, 641: 128526.
[44] LEMOS DE SOUZA M, PEREIRA DOS SANTOS D, CORIO P. Localized surface plasmon resonance enhanced photocatalysis: an experimental and theoretical mechanistic investigation[J]. RSC Advances, 2018, 8(50): 28753-28762.
[45] 张轩, 郑丽君. 光解水制氢单相催化剂研究进展[J]. 化工进展, 2021, 40(S1): 215-222.
ZHANG X, ZHENG L J. Process of single phase photocatalysts for hydrogen production[J]. Chemical Industry and Engineering Progress, 2021, 40(S1): 215-222 (in Chinese).
[46] MANZI A, SIMON T, SONNLEITNER C, et al. Light-induced cation exchange for copper sulfide based CO₂ reduction[J]. Journal of the American Chemical Society, 2015, 137(44): 14007-14010.
[47] KIM Y, PARK K Y, JANG D M, et al. Synthesis of Au-Cu₂S core-shell nanocrystals and their photocatalytic and electrocatalytic activity[J]. The Journal of Physical Chemistry C, 2010, 114(50): 22141-22146.
[48] ZHANG R, WANG H Y, LI Y Y, et al. Investigation on the photocatalytic hydrogen evolution properties of Z-scheme Au NPs/CuInS₂/NCN-CN_x composite photocatalysts[J]. ACS Sustainable Chemistry & Engineering, 2021, 9(21): 7286-7297.
[49] 刘果, 吴维成, 卢圆圆, 等. 低温下制备具有高光催化降解罗丹明B活性的CuS/TiO₂复合材料[J]. 人工晶体学报, 2016, 45(6): 1567-1573.
LIU G, WU W C, LU Y Y, et al. Preparation of CuS/TiO₂ composites with high photocatalytic activity at low temperature for degradation of rodamine B[J]. Journal of Synthetic Crystals, 2016, 45(6): 1567-1573 (in Chinese).
[50] 张克杰, 李宇, 夏源, 等. 核壳结构CdS/CuS纳米复合材料的制备及光催化性能[J]. 高等学校化学学报, 2019, 40(3): 489-497.
ZHANG K J, LI Y, XIA Y, et al. Synthesis and photocatalytic performance of CdS/CuS core-shell nanocomposites[J]. Chemical Journal of Chinese Universities, 2019, 40(3): 489-497 (in Chinese).
[51] 曾斌, 曾武军, 刘万锋. 通用法制备石墨烯/硫化铜微米花和石墨烯/硫化亚锡微米花及在水污染处理中的应用[J]. 人工晶体学报, 2019, 48(3): 494-498.
ZENG B, ZENG W J, LIU W F. Graphene/CuS microflower and graphene/SnS microflower prepared by general method and its application in the water treatment[J]. Journal of Synthetic Crystals, 2019, 48(3): 494-498 (in Chinese).
[52] 曾斌, 曾武军, 刘万锋. 绿色合成石墨烯负载硫化铜/硫化镉多级纳米球及在水污染处理中的应用[J].人工晶体学报, 2019, 48(10): 1907-1911.
ZENG B, ZENG W J, LIU W F. Green synthesis of graphene-CuS/Cd S hierarchical nanospheres and its application in the water treatment[J]. Journal of Synthetic Crystals, 2019, 48(10): 1907-1911 (in Chinese).
[53] 赵晶晶, 张正中, 陈小浪, 等. 微波诱导组装CuS@MoS₂核壳纳米管及其光催化类芬顿反应研究[J]. 化学学报, 2020, 78(9): 961-967.
ZHAO J J, ZHANG Z Z, CHEN Z L, et al. Microwave-induced assembly of CuS@MoS₂ core-shell nanotubes and study on their photocatalytic Fenton-like reactions[J]. Acta Chimica Sinica, 2020, 78(9): 961-967 (in Chinese).
[54] KAUSHIK B, RANA P, SOLANKI K, et al. In-situ synthesis of 3-D hierarchical ZnFe₂O₄ modified Cu₂S snowflakes: exploring their bifunctionality in selective photocatalytic reduction of nitroarenes and methyl orange degradation[J]. Journal of Photochemistry and Photobiology A: Chemistry, 2022, 433: 114165.
[55] YANG J H, FANG L, GAN X H, et al. Efficient degradation of sulfamethoxazole under visible light irradiation by polyaniline/copper sulfide composite photocatalyst[J]. Environmental Science and Pollution Research, 2022, 29(24): 36502-36511.
[56] CHEN Q S, ZHOU H Q, WANG J C, et al. Activating earth-abundant insulator BaSO₄ for visible-light induced degradation of tetracycline[J]. Applied Catalysis B: Environmental, 2022, 307: 121182.
[57] ZOU J, LIAO G D, WANG H T, et al. Controllable interface engineering of g-C₃N₄/CuS nanocomposite photocatalysts[J]. Journal of Alloys and Compounds, 2022, 911: 165020.
[58] JAFARINEJAD A, BASHIRI H, SALAVATI-NIASARI M. Sonochemical synthesis and characterization of CuInS₂ nanostructures using new sulfur precursor and their application as photocatalyst for degradation of organic pollutants under simulated sunlight[J]. Arabian Journal of Chemistry, 2022, 15(8): 104007.
[59] GUO J R, WANG L P, WEI X, et al. Direct Z-scheme CuInS₂/Bi₂MoO₆ heterostructure for enhanced photocatalytic degradation of tetracycline under visible light[J]. Journal of Hazardous Materials, 2021, 415: 125591.
[60] WANG T, MEN Q Y, LIU X Q, et al. A staggered type of 0D/2D CuInS₂/NiAl-LDH heterojunction with enhanced photocatalytic performance for the degradation of 2, 4-Dichlorophenol[J]. Separation and Purification Technology, 2022, 294: 121215.
[61] LIU C Q, ZHANG B, LIU E Z, et al. Nano composite of CuInS₂/ZnO with improved photocatalytic activity of degradation and hydrogen production[J]. Optical Materials, 2020, 109: 110379.
[62] CHEN Q H, ZHANG M M, LI J Y, et al. Construction of immobilized 0D/1D heterostructure photocatalyst Au/CuS/CdS/TiO₂ NBs with enhanced photocatalytic activity towards moxifloxacin degradation[J]. Chemical Engineering Journal, 2020, 389: 124476.
[63] BHOI Y P, MISHRA B G. Photocatalytic degradation of alachlor using type-II CuS/BiFeO₃ heterojunctions as novel photocatalyst under visible light irradiation[J]. Chemical Engineering Journal, 2018, 344: 391-401.
[64] IERVOLINO G, VAIANO V, SANNINO D, et al. Hydrogen production from glucose degradation in water and wastewater treated by Ru-LaFeO₃/Fe₂O₃ magnetic particles photocatalysis and heterogeneous photo-Fenton[J]. International Journal of Hydrogen Energy, 2018, 43(4): 2184-2196.
[65] WANG Y Z, CHEN D, QIN L S, et al. Hydrogenated ZnIn₂S₄ microspheres: boosting photocatalytic hydrogen evolution by sulfur vacancy engineering and mechanism insight[J]. Physical Chemistry Chemical Physics: PCCP, 2019, 21(45): 25484-25494.
[66] REDDY D A, KIM Y, GOPANNAGARI M, et al. Recent advances in metal-organic framework-based photocatalysts for hydrogen production[J]. Sustainable Energy & Fuels, 2021, 5(6): 1597-1618.
[67] GUO W W, KIM J, KIM H, et al. Cu-Co-P electrodeposited on carbon paper as an efficient electrocatalyst for hydrogen evolution reaction in anion exchange membrane water electrolyzers[J]. International Journal of Hydrogen Energy, 2021, 46(38): 19789-19801.
[68] HOU J W, HUANG B X, KONG L C, et al. One-pot hydrothermal synthesis of CdS-CuS decorated TiO₂ NTs for improved photocatalytic dye degradation and hydrogen production[J]. Ceramics International, 2021, 47(21): 30860-30868.
[69] LUO J H, LIN Z X, ZHAO Y, et al. The embedded CuInS₂ into hollow-concave carbon nitride for photocatalytic H₂O splitting into H₂ with S-scheme principle[J]. Chinese Journal of Catalysis, 2020, 41(1): 122-130.
[70] FAN H T, WU Z, LIU K C, et al. Fabrication of 3D CuS@ZnIn₂S₄ hierarchical nanocages with 2D/2D nanosheet subunits p-n heterojunctions for improved photocatalytic hydrogen evolution[J]. Chemical Engineering Journal, 2022, 433: 134474.
[71] XIN X, SONG Y R, GUO S H, et al. In-situ growth of high-content 1T phase MoS₂ confined in the CuS nanoframe for efficient photocatalytic hydrogen evolution[J]. Applied Catalysis B: Environmental, 2020, 269: 118773.
[72] VEMPULURU N R, KANAKKAMPALAYAM KRISHNAN C, PARNAPALLI R, et al. Solar hydrogen generation from organic substance using earth abundant CuS-NiO heterojunction semiconductor photocatalyst[J]. Ceramics International, 2021, 47(7): 10206-10215.
[73] MAHADIK M A, PATIL R P, CHAE W S, et al. Microwave-assisted rapid synthesis of Cu₂S∶ZnIn₂S₄ marigold-like nanoflower heterojunctions and enhanced visible light photocatalytic hydrogen production via Pt sensitization[J]. Journal of Industrial and Engineering Chemistry, 2022, 108: 203-214.
[74] RAO V N, RAVI P, SATHISH M, et al. Titanate quantum dots-sensitized Cu₂S nanocomposites for superficial H₂ production via photocatalytic water splitting[J]. International Journal of Hydrogen Energy, 2022, 47(95): 40379-40390.
[75] WU Y L, ZHANG H Y, LI Y J, et al. Partial phosphating of Ni-MOFs and Cu₂S snowflakes form 2D/2D structure for efficiently improved photocatalytic hydrogen evolution[J]. International Journal of Hydrogen Energy, 2022, 47(86): 36530-36542.
[76] WANG G R, QUAN Y K, YANG K C, et al. EDA-assisted synthesis of multifunctional snowflake-Cu₂S/CdZnS S-scheme heterojunction for improved the photocatalytic hydrogen evolution[J]. Journal of Materials Science & Technology, 2022, 121: 28-39.
[77] HOU F Y, LIU F, WU H C, et al. In situ synthesis of Cu₃P/P-doped g-C₃N₄ tight 2D/2D heterojunction boosting photocatalytic H₂ evolution[J]. Chinese Journal of Chemistry, 2023, 41(2): 173-180.
[78] SARILMAZ A, GENC E, ASLAN E, et al. Photocatalytic hydrogen evolution via solar-driven water splitting by CuSbS₂ with different shapes[J]. Journal of Photochemistry and Photobiology A: Chemistry, 2020, 400: 112706.
[79] YU H Y, LIANG H O, BAI J, et al. Controllable growth of coral-like CuInS₂ on one-dimensional SiO₂ nanotube with super-hydrophilicity for enhanced photocatalytic hydrogen evolution[J]. International Journal of Hydrogen Energy, 2022, 47(66): 28410-28422.
[80] WANG Y, PENG J R, XU Y F, et al. Facile fabrication of CdSe/CuInS₂ microflowers with efficient photocatalytic hydrogen production activity[J]. International Journal of Hydrogen Energy, 2022, 47(13): 8294-8302.

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