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Journal of Synthetic Crystals ›› 2025, Vol. 54 ›› Issue (9): 1654-1662.DOI: 10.16553/j.cnki.issn1000-985x.2025.0036

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Nano-Fe2O3/Bamboo Leaf Carbon Composite Anode Materials for High-Performance Lithium-Ion Batteries

WANG Jun(), JIN Yaoyao, HU Zhangtao, ZHENG Yi, ZHANG Han   

  1. School of Materials and Energy,Chongqing University of Science and Technology,Chongqing 401331,China
  • Received:2025-02-25 Online:2025-09-20 Published:2025-09-23

Abstract: The transition metal oxide Fe2O3, as an anode material for lithium-ion batteries, exhibits advantages such as high theoretical specific capacity (1 007 mAh/g), abundant reserves, and environmental friendliness. However, in practical applications, its performance is limited by low conductivity and significant volume expansion during cycling. Introducing a carbon matrix and nanostructuring are effective strategies to address these issues. The bamboo leaf carbon offers advantages of low cost and high yield. As a carbon matrix, it enhances the conductivity of the composite and buffers the volume expansion of the anode active material. In this study, bamboo leaves were used as a carbon source to prepare carbon materials. Nano-Fe2O3 was synthesized by hydrothermal method, and finally, a solvothermal method was employed to combine bamboo leaf-derived carbon with nano-Fe2O3, producing a nano-Fe2O3/bamboo leaf carbon composite anode material. Electrochemical tests reveal that the nano-Fe2O3/bamboo leaf carbon composite maintains a high specific capacity of 704.6 mAh/g after 203 cycles at a current density of 200 mA/g, while delivering a specific capacity of 472 mAh/g at a higher current density of 500 mA/g. The incorporation of bamboo leaf carbon improves the diffusion kinetics of lithium-ion insertion/extraction in the electrode material, and also increases the contribution of pseudocapacitive behavior to the capacity. This study provides a novel approach for utilizing biomass-derived carbon to enhance the reversible capacity and cycling stability of lithium-ion battery anode materials.

Key words: Fe2O3; bamboo leaf carbon; Li-ion battery; anode; reversible capacity; cycling stability

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