Construction and Electrochemical Properties of Co/Ni Coordination Polymer Based on Flexible Phenyldiacetate

Abstract

Abstract: Two coordination polymers ([Co(tib)(mpda)(H₂O)₂]·H₂O, [Ni(tib)(mpda)(H₂O)₂]·H₂O) were synthesized based on flexible phenyldiacetic acid, and characterized by elemental analysis, infrared spectroscopy, thermogravimetric analysis and X-ray single crystal diffraction. In the structure of [Ni(tib)(mpda)(H₂O)₂]·H₂O, the tib ligands coordinate as three nodes with Co(II) ions to form a 2D grid plane; cis-mpda ligands are attached to the 2D grid face as end-bases; through the O—H…O interaction between the mpda virgin carboxyl O and the coordinated water molecule (bond length of O1…O3 is 0.262 4 nm, ∠O5—H5A…O2=155.41°), a three-dimensional supramolecular network structure is formed. Two coordination polymers belong to the heterogeneous crystal structure. The specific surface areas of the two coordination polymers are 54 and 58 m²/g, respectively. [Ni(tib)(mpda)(H₂O)₂]·H₂O has a complete cyclic voltammetric curve (reduction and oxidation potentials are 0.205 and 0.563 V, respectively) and good scanning rate.

Key words: flexible benzodiacetic acid, coordination polymer, hydro-thermal synthesis, crystal structure, electrochemical property

CLC Number:

O641

LIN Taohai, ZHANG Jun, GE Qing, ZHANG Gangqiang, ZHANG Meili. Construction and Electrochemical Properties of Co/Ni Coordination Polymer Based on Flexible Phenyldiacetate[J]. JOURNAL OF SYNTHETIC CRYSTALS, 2024, 53(3): 534-540.

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