Hygroscopicity and Thermal Expansion Properties of (ZrCa)xY2-2xW3O12 Solid Solution

Abstract

Abstract: (ZrCa)_xY_2-2xW₃O₁₂(x =0, 0.1, 0.2, 0.3, 0.4, 0.5, 0.6, 0.7, 0.8, 0.9 and 1.0) are developed with a simple solid state method, and characterized for crystal structure, hygroscopicity and thermal expansion by X-ray diffraction, Raman spectroscopy, thermal analysis and dilatometer. The results show that the hygrosopicity of solid solution decreases obviously, and the coefficient of thermal expansion (CTE) changes regularly after complete release of the crystal water with the increase of (ZrCa)⁶⁺ content. A near-zero thermal expansion (ZTE) is realized for (ZrCa)_0.6Y_0.8W₃O₁₂ as x=0.6, and the linear CTE (a_l) is measured to be 2.79×10^-7 K^-1(453~1 000 K).

Key words: solid solution, negative thermal expansion, (ZrCa)_xY_2-2xW₃O₁₂, hygrosopicity, Raman spectroscopy

CLC Number:

O469
TB39

WANG Xianli, FU Linjie, YU Zhanjun, CHEN Dongxia, DUAN Xiangyang. Hygroscopicity and Thermal Expansion Properties of (ZrCa)_xY_2-2xW₃O₁₂ Solid Solution[J]. JOURNAL OF SYNTHETIC CRYSTALS, 2024, 53(5): 899-903.

References

[1] EVANS J S O, HU Z, JORGENSEN J D, et al. Compressibility, phase transitions, and oxygen migration in zirconium tungstate, ZrW₂O₈[J]. Science, 1997, 275(5296): 61-65.
[2] 王献立, 付林杰, 许坤. 负热膨胀材料的研究及应用[J]. 信息记录材料, 2018, 19(12): 38-39.
WANG X L, FU L J, XU K. The study and applying of negative thermal expansion materials[J]. Information Recording Materials, 2018, 19(12): 38-39 (in Chinese).
[3] 石业平, 袁保合, 梁二军. P替代对ZrV₂O₇介电与电导性能的影响[J]. 人工晶体学报, 2019, 48(10): 1938-1944.
SHI Y P, YUAN B H, LIANG E J. Effect of P substitution on dielectric and conductive properties of ZrV₂O₇[J]. Journal of Synthetic Crystals, 2019, 48(10): 1938-1944 (in Chinese).
[4] LIANG E J. Negative thermal expansion materials and their applications: a survey of recent patents[J]. Recent Patents on Materials Science, 2010, 3(2): 106-128.
[5] TUCKER M G, GOODWIN A L, DOVE M T, et al. Negative thermal expansion in ZrW₂O₈: mechanisms, rigid unit modes, and neutron total scattering[J]. Physical Review Letters, 2005, 95(25): 255501.
[6] HAO X K, WANG M Y, LIU X S, et al. High configurational entropy for low phase transition temperature and thermal expansion of A₂M₃O₁₂ oxide ceramics[J]. Ceramics International, 2023, 49(20): 33051-33056.
[7] 付林杰, 王献立, 王伟鹏, 等. ZrSc_xAl_1-xW₂VO₁₂(x=0, 0.3, 0.5, 0.7, 1)陶瓷材料的热膨胀性能研究[J]. 人工晶体学报, 2019, 48(9): 1703-1706+1711.
FU L J, WANG X L, WANG W P, et al. Thermal expansion property of ZrSc_xAl_1-xW₂VO₁₂ ceramic materials(x=0, 0.3, 0.5, 0.7, 1)[J]. Journal of Synthetic Crystals, 2019, 48(9): 1703-1706+1711 (in Chinese).
[8] ARI M, JARDIM P M, MARINKOVIC B A, et al. Thermal expansion of Cr_2xFe_2-2xMo₃O₁₂, Al_2xFe_2-2xMo₃O₁₂ and Al_2xCr_2-2xMo₃O₁₂ solid solutions[J]. Journal of Solid State Chemistry, 2008, 181(6): 1472-1479.
[9] VARGA T, MOATS J L, USHAKOV S V, et al. Thermochemistry of A₂M₃O₁₂ negative thermal expansion materials[J]. Journal of Materials Research, 2007, 22(9): 2512-2521.
[10] RONG W L, LIU F A, WANG X M, et al. Crystal growth and negative thermal expansion properties of a Y₂Mo₄O₁₅ single crystal[J]. RSC Advances, 2023, 13(19): 13006-13013.
[11] WANG L, WANG F, YUAN P F, et al. Negative thermal expansion correlated with polyhedral movements and distortions in orthorhombic Y₂Mo₃O₁₂[J]. Materials Research Bulletin, 2013, 48(7): 2724-2729.
[12] LIANG E J, LIANG Y, ZHAO Y, et al. Low-frequency phonon modes and negative thermal expansion in A(MO₄)₂ (A=Zr, Hf and M=W, Mo) by Raman and Terahertz time-domain spectroscopy[J]. The Journal of Physical Chemistry A, 2008, 112(49): 12582-12587.
[13] YOUNG L, ALVAREZ P T, LIU H F, et al. Extremely low temperature crystallization in the A₂M₃O₁₂ family of negative thermal expansion materials[J]. European Journal of Inorganic Chemistry, 2016, 2016(8): 1251-1256.
[14] LIU H F, ZHANG H, HUANG F Y, et al. Preparation of In_0.5Sc_1.5Mo₃O₁₂ nanofibers and its negative thermal expansion property[J]. Ceramics International, 2023, 49(19): 31627-31633.
[15] 杨海涛, 刁志聪, 尚福亮, 等. Y_2-xSm_xW₃O₁₂固溶体的制备及热膨胀性能研究[J]. 中国钨业, 2010, 25(5): 40-43.
YANG H T, DIAO Z C, SHANG F L, et al. Thermal expansion properties of solid solution Y_2-xSm_xW₃O₁₂[J]. China Tungsten Industry, 2010, 25(5): 40-43 (in Chinese).
[16] 程永光, 刘献省, 宋文博, 等. Y_2-x(LiMg)_xMo₃O₁₂固溶体吸水性与热膨胀性能研究[J]. 光散射学报, 2014, 26(3): 258-264.
CHENG Y G, LIU X S, SONG W B, et al. Hygroscopicity and thermal expansion properties of Y_2-x(LiMg)_xMo₃O₁₂ solid solutions[J]. The Journal of Light Scattering, 2014, 26(3): 258-264 (in Chinese).
[17] LIANG E J, HUO H L, WANG J P, et al. Effect of water species on the phonon modes in orthorhombic Y₂(MoO₄)₃ revealed by Raman spectroscopy[J]. The Journal of Physical Chemistry C, 2008, 112(16): 6577-6581.
[18] SUMITHRA S, UMARJI A M. Hygroscopicity and bulk thermal expansion in Y₂W₃O₁₂[J]. Materials Research Bulletin, 2005, 40(1): 167-176.
[19] WOODCOCK D A, LIGHTFOOT P, RITTER C. Negative thermal expansion in Y₂(WO₄)₃[J]. Journal of Solid State Chemistry, 2000, 149(1): 92-98.

Hygroscopicity and Thermal Expansion Properties of (ZrCa)_xY_2-2xW₃O₁₂ Solid Solution

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