Analysis of Luminescence Performance of New Red Phosphor K5Gd(MoO4)4:xSm3+,yEu3+
LI Mingming, XIONG Feibing, YANG Weibin, HU Zhengkai, BAI Xin, LI Jing, LIN Yaqing, HUANG Junxiong
2024, 53(12):
2150-2159.
Asbtract
(
7 )
PDF (15429KB)
(
0
)
References |
Related Articles |
Metrics
A series of K5Gd (MoO4)4:xSm3+(x=0~0.10) and K5Gd (MoO4)4:0.04Sm3+, yEu3+(y=0.03~0.15) red phosphors were synthesized by high-temperature solid-phase method in this paper. The photoluminescence spectra, fluorescence emission spectra, and fluorescence quenching performance of the phosphor were analyzed by X-ray diffraction (XRD), fluorescence excitation spectra, thermal quenching analysis system, and steady-state transient spectrometer. Results show that the samples synthesized by doping Eu3+and Sm3+into K5Gd (MoO4)4 don't contain impurity phases, and the crystal structure remains unchanged. Under the excitation of 405 nm ultraviolet light, K5Gd (MoO4)4:0.04Sm3+and K5Gd (MoO4)4:0.04Sm3+, 0.12Eu3+can emit excellent red light with the CIE coordinates of (0.6088, 0.3904) and (0.637 3, 0.359 2). In the K5Gd(MoO4)4:xSm3+(x=0~0.10) samples, as the Sm3+doping concentration increases, the luminescence intensity of the phosphor first increases and then decreases, the optimal doping concentration is x=0.04. In the K5Gd(MoO4)4:0.04Sm3+,yEu3+(y=0.03~0.15) samples, the luminescence intensity of Eu3+first increases and then decreases with increasing Eu3+ doping concentration, and concentration quenching occur at y=0.12. When the temperature reaches 373 K, the fluorescence intensity of the K5Gd(MoO4)4:0.04Sm3+phosphor sample is 94.69% of that at 293 K, while the fluorescence intensity of the K5Gd(MoO4)4:0.04Sm3+, 0.12Eu3+phosphor sample is 76.3% of that at 293 K, indicating their good thermal stability. The color coordinate graph shows that, doping of Eu3+ leads to the color coordinate shifts slightly from the orange red region to the pure red region. Both K5Gd(MoO4)4:xSm3+ and K5Gd(MoO4)4:0.04Sm3+, yEu3+phosphor samples have the potential to be used as red phosphors for white light LED.