欢迎访问《人工晶体学报》官方网站,今天是 2025年7月24日 星期四 分享到:

人工晶体学报 ›› 2008, Vol. 37 ›› Issue (6): 1542-1545.

• • 上一篇    下一篇

3,5-二氯水杨醛缩异亮氨酸邻菲啰啉铜(Ⅱ)三元配合物的合成与晶体结构表征

刘峥;夏金虹;王永燎;韦春   

  1. 桂林工学院材料与化学工程系,桂林,541004;桂林电子科技大学电子工程学院,桂林,541004
  • 出版日期:2008-12-15 发布日期:2021-01-20
  • 基金资助:
    国家自然科学基金(50763001)

Synthesis and Crystal Structure Characterization of 3,5-dichloro Salicylaldehyde Isoleucine Phenanthroline Copper(Ⅱ)Ternary Complex

LIU Zheng;XIA Jin-hong;WANG Yong-liao;WEI Chun   

  • Online:2008-12-15 Published:2021-01-20

摘要: 采用分步溶液法,在碱性条件下合成出了3,5-二氯水杨醛缩异亮氨酸邻菲啰啉铜(Ⅱ)三元配合物,并培养出[Cu3L3(Phen)3].5H2O单晶(其中H2L=3,5-二氯水杨醛席夫碱缩异亮氨酸),其晶体结构经元素分析,红外光谱及X射线单晶衍射表征.

关键词: 氨基酸席夫碱;合成;晶体结构

Abstract: The 3,5-dichloro salicylaldehyde isoleucine phenanthroline copper(Ⅱ)ternary complex was composed in step-by-step method in alkaline solution,and the single crystal[Cu3L3(Phen)3].5H2O(H2L=2-[(3,5-Dichloro-2-hydroxy-benzylidene)-amino]-3-methyl-pentanoic acid)was determined from the ternary complex.The structure of the single crystal has been characterized by elemental analysis,IR and X-ray single crystal diffraction.

Key words: The 3,5-dichloro salicylaldehyde isoleucine phenanthroline copper(Ⅱ)ternary complex was composed in step-by-step method in alkaline solution,and the single crystal[Cu3L3(Phen)3].5H2O(H2L=2-[(3,5-Dichloro-2-hydroxy-benzylidene)-amino]-3-methyl-pentanoic acid)was determined from the ternary complex.The structure of the single crystal has been characterized by elemental analysis,IR and X-ray single crystal diffraction.

中图分类号: