Bi26-x-yMxNyO40(M, N=Fe, Co, Gd)软铋矿薄膜的制备和强磁光效应

人工晶体学报 ›› 2021, Vol. 50 ›› Issue (9): 1655-1661.

Bi_26-x-yM_xN_yO₄₀(M, N=Fe, Co, Gd)软铋矿薄膜的制备和强磁光效应

高腾^1,2, 邢锟^1,2, 吴功辉^1,2, 陈新^1,2, 胡晓琳^1,2, 庄乃锋^1,2

1.福州大学化学学院,福州 350108;
2.福州大学光功能晶态材料研究所,福州 350108

收稿日期:2021-06-01 出版日期:2021-09-15 发布日期:2021-10-15
通讯作者: 庄乃锋,教授。E-mail:nfzhuang@fzu.edu.cn
作者简介:高腾(1995—),男,湖北省人,博士研究生。E-mail:1959024625@qq.com
基金资助:
国家自然科学基金(61875039,51772052);福建省自然科学基金(2019J01206)

Preparation and Strong Magneto-Optical Effect of Bi_26-x-yM_xN_yO₄₀ (M, N=Fe, Co, Gd) Sillenite Type Films

GAO Teng^1,2, XING Kun^1,2, WU Gonghui^1,2, CHEN Xin^1,2, HU Xiaolin^1,2, ZHUANG Naifeng^1,2

1. College of Chemical, Fuzhou University, Fuzhou 350108, China;
2. Institute of Optical Crystalline Materials, Fuzhou University, Fuzhou 350108, China

Received:2021-06-01 Online:2021-09-15 Published:2021-10-15

摘要/Abstract

摘要： 磁光材料是现代光通信产业中不可或缺的关键功能材料。为了实现光通信器件的小型化,高质量磁光薄膜材料受到关注。软铋矿型Bi₂₅FeO₄₀具有高对称性的立方晶体结构,单位体积所含铋离子浓度高,理论上应具有较强的磁光效应,但却因为磁性偏弱、制备困难等缺点而限制了其应用。本文采用射频磁控溅射法,在掺钇二氧化锆(YSZ)基底上沉积获得具有立方相软铋矿型结构的Bi_26-x-yM_xN_yO₄₀ (M, N=Fe, Co, Gd)磁光薄膜,并对其形貌、磁性、透过率、磁圆二色信号等进行表征。结果表明,薄膜均较为平整,厚度约为190 nm,在近红外区的透过率约为60%~70%。薄膜的磁性随着掺杂离子含量的提高逐渐增强。Bi_13.6Gd_2.7Co_4.0Fe_5.7O₄₀/YSZ薄膜具有强磁光效应,在716 nm处的磁圆二色光谱信号高达到1 710 deg/cm,有望应用于集成光隔离器等光通信器件中。

关键词: 磁光效应, 磁圆二色光谱, Bi_26-x-yM_xN_yO₄₀薄膜, 软铋矿, 磁控溅射法, 磁性质

Abstract: Magneto-optical materials are the indispensable and key functional materials in the field of modern optical communication. For the miniaturization of devices, high quality magneto-optical thin films have attracted much attention. The sillenite type Bi₂₅FeO₄₀ has a cubic crystal structure with high symmetry. The concentration of bismuth ions per unit volume is high, so it should have a strong magneto-optical effect in theory. However, its application is restricted due to low magnetism and difficulty in preparation. In this paper, Bi_26-x-yM_xN_yO₄₀ (M, N=Fe, Co, Gd) magneto-optical thin films with cubic sillenite type were deposited on yttrium-doped zirconium dioxide (YSZ) substrate by the magnetron sputtering method. Their morphology, magnetic properties, transmittance, and magnetic circle dichroism were discussed. Smooth surface morphology of the films was observed by atom force microscope. The thickness of the films is about 190 nm. The valence states of bismuth, iron and cobalt in the films are all +3, and other valence states are not observed, so they are meeting the charge balance. The transmittance in the near infrared region is about 60% to 70%. At room temperature, the films show superparamagnetic effect, and the magnetic properties gradually increase with the increase of doping ion concentration. And the saturation magnetization of Bi_13.6Gd_2.7Co_4.0Fe_5.7O₄₀/YSZ film reaches 29 emu/cm³. The Bi_13.6Gd_2.7Co_4.0Fe_5.7O₄₀/YSZ film exhibits a strong magneto-optical effect, the magnetic circular dichroic spectrum signal is up to 1 710 deg/cm at wavelength of 716 nm. Therefore, Bi_13.6Gd_2.7Co_4.0Fe_5.7O₄₀/YSZ film is expected to be used in integrated optical isolators and other optical communication devices.

Key words: magneto-optical effect, magnetic circular dichroic spectrum, Bi_26-x-yM_xN_yO₄₀ film, sillenite, magnetron sputtering method, magnetic property

中图分类号:

O734
TB383

高腾, 邢锟, 吴功辉, 陈新, 胡晓琳, 庄乃锋. Bi_26-x-yM_xN_yO₄₀(M, N=Fe, Co, Gd)软铋矿薄膜的制备和强磁光效应[J]. 人工晶体学报, 2021, 50(9): 1655-1661.

GAO Teng, XING Kun, WU Gonghui, CHEN Xin, HU Xiaolin, ZHUANG Naifeng. Preparation and Strong Magneto-Optical Effect of Bi_26-x-yM_xN_yO₄₀ (M, N=Fe, Co, Gd) Sillenite Type Films[J]. JOURNAL OF SYNTHETIC CRYSTALS, 2021, 50(9): 1655-1661.

参考文献

[1] ZHUANG N F, CHEN W B, SHI L J, et al. A new technique to grow incongruent melting Ga∶YIG crystals: the edge-defined film-fed growth method[J]. Journal of Applied Crystallography, 2013, 46(3): 746-751.
[2] ZHUANG N F, WANG C N, WEI Q K, et al. EFG growth and optical properties of incongruent-melting Ga³⁺∶GIG single crystal[J]. Optical Materials, 2014, 36(7): 1160-1164.
[3] TOKUNAGA Y, IGUCHI S, ARIMA T, et al. Magnetic-field-induced ferroelectric state in DyFeO₃[J]. Physical Review Letters, 2008, 101(9): 097205.
[4] WINTGEN D, ECKHARDT B. Symbolic description of periodic orbits for the quadratic Zeeman effect[J]. Journal of Physics B: Atomic, Molecular and Optical Physics, 1990, 23(3): 355-363.
[5] ROJO J C, DIÉGUEZ E. Bismuth germanate, titanate, and silicate[M]//Encyclopedia of Materials: Science and Technology. Amsterdam: Elsevier, 2001: 637-643.
[6] RADAEV S F, SIMONOV V I, KARGIN Y F. Structural features of γ-phase Bi₂O₃ and its place in the sillenite family[J]. Acta Crystallographica Section B Structural Science, 1992, 48(5): 604-609.
[7] STEPANOV S I. Applications of photorefractive crystals[J]. Reports on Progress in Physics, 1994, 57(1): 39-116.
[8] SKORIKOV V M, ZAKHAROV I S, VOLKOV V V, et al. Transmission and absorption spectra of Bi₁₂GeO₂₀, Bi₁₂SiO₂₀, and Bi₁₂TiO₂₀ single crystals[J]. Inorganic Materials, 2002, 38(2): 172-178.
[9] ZHAO W Z. Magneto-optic properties and sensing performance of garnet YbBi∶YIG[J]. Sensors and Actuators A: Physical, 2001, 89(3): 250-254.
[10] BERZHANSKY V N, KARAVAINIKOV A V, MIKHAILOVA T V, et al. Nano- and micro-scale Bi-substituted iron garnet films for photonics and magneto-optic eddy current defectoscopy[J]. Journal of Magnetism and Magnetic Materials, 2017, 440: 175-178.
[11] 徐芳.浅析磁控溅射玻璃镀膜原理[J].中国玻璃,2008,33(6):38-44.
XU F. Analysis on the principle of magnetron sputtering glass coating[J]. China Glass, 2008, 33(6): 38-44(in Chinese).
[12] ALFONSO J E, MARTÍN M J, MENDIOLA J, et al. Bi₁₂(Ga_xBi_1-x)O₁₉_.5 optical waveguides grown by pulsed laser deposition[J]. Journal of Applied Physics, 1996, 79(11): 8210-8215.
[13] JAFER R M, COETSEE E, YOUSIF A, et al. X-ray photoelectron spectroscopy and luminescent properties of Y₂O₃∶Bi³⁺ phosphor[J]. Applied Surface Science, 2015, 332: 198-204.
[14] LI Z X, SHEN Y, YANG C, et al. Significant enhancement in the visible light photocatalytic properties of BiFeO₃-graphene nanohybrids[J]. J Mater Chem A, 2013, 1(3): 823-829.
[15] BIESINGER M C, PAYNE B P, GROSVENOR A P, et al. Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Cr, Mn, Fe, Co and Ni[J]. Applied Surface Science, 2011, 257(7): 2717-2730.
[16] DING Y B, ZHU L H, HUANG A Z, et al. A heterogeneous Co₃O₄-Bi₂O₃ composite catalyst for oxidative degradation of organic pollutants in the presence of peroxymonosulfate[J]. Catalysis Science & Technology, 2012, 2(9): 1977.
[17] ZHANG L, ZHANG X, ZOU Y, et al. Hydrothermal synthesis, influencing factors and excellent photocatalytic performance of novel nanoparticle-assembled Bi₂₅FeO₄₀ tetrahedrons[J]. CrystEngComm, 2015, 17(34): 6527-6537.
[18] DA SILVA M A F M, PEDRO S S, SOSMAN L P. Fe³⁺ concentration dependence of photoacoustic absorption spectroscopy on ZnGa₂O₄ ceramic powders[J]. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2008, 69(2): 338-342.
[19] MARTENS J W D, PEETERS W L, VAN NOORT H M, et al. Optical, magneto-optical and mössbauer spectroscopy on Co³⁺ substituted cobalt ferrite Co²⁺Fe_2-xCo_3+xO₄(0≤x≤2)[J]. Journal of Physics and Chemistry of Solids, 1985, 46(4): 411-416.
[20] FU Q P, XU Q R, ZHAO Z S, et al. New magneto-optical film of Ce, Ga∶GIG with high performance[J]. Journal of the American Ceramic Society, 2016, 99(1): 234-240.

Bi_26-x-yM_xN_yO₄₀(M, N=Fe, Co, Gd)软铋矿薄膜的制备和强磁光效应

Preparation and Strong Magneto-Optical Effect of Bi_26-x-yM_xN_yO₄₀ (M, N=Fe, Co, Gd) Sillenite Type Films

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 14

编辑推荐

Metrics

本文评价

[1]	徐艳, 崔磊, 卜康. 一例混合配体构筑的钴(Ⅱ)一维配位聚合物的合成、晶体结构与磁性质[J]. 人工晶体学报, 2021, 50(5): 894-899.
[2]	冯凯, 吕滨, 程红梅, 吴少凡, 王燕, 刘永兴. 基于磁光应用的TbO_1.81和Tb₂O₃超细粉末的合成[J]. 人工晶体学报, 2021, 50(1): 80-87.
[3]	张昊天, 窦仁勤, 张庆礼, 刘文鹏, 孙贵花, 罗建乔. 磁光晶体的研究进展及应用[J]. 人工晶体学报, 2020, 49(2): 346-352.
[4]	徐刘伟;王帅华;陈养国;吴以恒;李艳;吴少凡. 钒酸镝晶体生长和磁光性能研究[J]. 人工晶体学报, 2019, 48(10): 1834-1837.
[5]	张尧;李翠平;黄绪;朱振宇;刘艳中;申子龙. 低温磁控溅射法制备氧化锌薄膜的光学性能研究[J]. 人工晶体学报, 2018, 47(8): 1517-1523.
[6]	杨天琦;李翠平;曹菲菲. 衬底温度对磁控溅射法制备掺Ta氧化锌薄膜性能的影响[J]. 人工晶体学报, 2017, 46(9): 1714-1719.
[7]	贾丽莎;赵营;涂衡;胡章贵. 新型复合功能晶体Cd4TbO(BO3)3结构与性能研究[J]. 人工晶体学报, 2017, 46(8): 1436-1441.
[8]	刘悦;孔勇发;许京军;Sang-Wook Cheong. Fe掺杂YbMnO3晶体的磁性增强研究[J]. 人工晶体学报, 2015, 44(8): 2024-2027.
[9]	杨华;张玉琦. 基于乙酸根、苯甲酸根和邻菲罗啉的三核锰配合物的合成、结构及磁性研究[J]. 人工晶体学报, 2014, 43(9): 2468-2473.
[10]	闫娟枝;朱苗力. 一维链式三唑锰晶体的结构及磁性能研究[J]. 人工晶体学报, 2014, 43(8): 2164-2169.
[11]	施俐君;郭莉薇;魏庆科;宋财根;胡晓琳;庄乃锋;林树坤;陈建中. 导模提拉法生长Tb3Sc2Al3O12(TSAG)晶体及性质表征[J]. 人工晶体学报, 2013, 42(9): 1735-1740.
[12]	张仲;冯秀鹏;李世帅;黄金昭;陈康. 衬底温度对Ba2FeMoO6薄膜生长的影响及磁性质研究[J]. 人工晶体学报, 2011, 40(5): 1214-1218.
[13]	郭颖楠;刘保亭;赵敬伟;王宽冒;王玉强;孙杰;陈剑辉. 退火工艺对含Ti-Al阻挡层的硅基Pb(Zr_(0.4),Ti_(0.6))O_3铁电电容器结构和性能影响的研究[J]. 人工晶体学报, 2010, 39(1): 62-66.
[14]	郭会斌;王凤英;贺琦;魏俊俊;王耀华;吕反修. 反应磁控溅射法制备HfO2金刚石红外增透膜[J]. 人工晶体学报, 2008, 37(6): 1355-1360.