(ZrCa)xY2-2xW3O12固溶体吸水性及热膨胀性能研究

人工晶体学报 ›› 2024, Vol. 53 ›› Issue (5): 899-903.

(ZrCa)_xY_2-2xW₃O₁₂固溶体吸水性及热膨胀性能研究

王献立, 付林杰, 于占军, 陈冬霞, 段向阳

郑州航空工业管理学院材料学院,郑州 450046

收稿日期:2023-12-05 出版日期:2024-05-15 发布日期:2024-05-21
通信作者: 陈冬霞,博士,副教授。E-mail:chendx1982@163.com
作者简介:王献立(1986—),男,河南省人,助理实验师。E-mail:wx8115@163.com
基金资助:
河南省自然科学基金(222300420578);河南省高等学校重点科研项目(23B140004);河南省高校科技创新团队支持计划(22IRTSTHN004)

Hygroscopicity and Thermal Expansion Properties of (ZrCa)_xY_2-2xW₃O₁₂ Solid Solution

WANG Xianli, FU Linjie, YU Zhanjun, CHEN Dongxia, DUAN Xiangyang

School of Materials Science and Engineering, Zhengzhou University of Aeronautics, Zhengzhou 450046, China

Received:2023-12-05 Online:2024-05-15 Published:2024-05-21

摘要/Abstract

摘要： 采用固相烧结法制备出(ZrCa)_xY_2-2xW₃O₁₂(x=0、0.1、0.2、0.3、0.4、0.5、0.6、0.7、0.8、0.9和1.0)固溶体,并利用XRD、拉曼光谱、热分析及热膨胀仪对材料的结构、吸水性及热膨胀性进行研究。结果表明,随着(ZrCa)⁶⁺含量的增加,固溶体的吸水性明显降低,结晶水释放后,该系列固溶体的热膨胀系数呈规律性变化。当x=0.6时,(ZrCa)_0.6Y_0.8W₃O₁₂为近零膨胀,且其线性热膨胀系数a_l为2.79×10^-7 K^-1(453~1 000 K)。

关键词: 固溶体, 负热膨胀, (ZrCa)_xY_2-2xW₃O₁₂, 吸水性, 拉曼光谱

Abstract: (ZrCa)_xY_2-2xW₃O₁₂(x =0, 0.1, 0.2, 0.3, 0.4, 0.5, 0.6, 0.7, 0.8, 0.9 and 1.0) are developed with a simple solid state method, and characterized for crystal structure, hygroscopicity and thermal expansion by X-ray diffraction, Raman spectroscopy, thermal analysis and dilatometer. The results show that the hygrosopicity of solid solution decreases obviously, and the coefficient of thermal expansion (CTE) changes regularly after complete release of the crystal water with the increase of (ZrCa)⁶⁺ content. A near-zero thermal expansion (ZTE) is realized for (ZrCa)_0.6Y_0.8W₃O₁₂ as x=0.6, and the linear CTE (a_l) is measured to be 2.79×10^-7 K^-1(453~1 000 K).

Key words: solid solution, negative thermal expansion, (ZrCa)_xY_2-2xW₃O₁₂, hygrosopicity, Raman spectroscopy

中图分类号:

O469
TB39

王献立, 付林杰, 于占军, 陈冬霞, 段向阳. (ZrCa)_xY_2-2xW₃O₁₂固溶体吸水性及热膨胀性能研究[J]. 人工晶体学报, 2024, 53(5): 899-903.

WANG Xianli, FU Linjie, YU Zhanjun, CHEN Dongxia, DUAN Xiangyang. Hygroscopicity and Thermal Expansion Properties of (ZrCa)_xY_2-2xW₃O₁₂ Solid Solution[J]. JOURNAL OF SYNTHETIC CRYSTALS, 2024, 53(5): 899-903.

参考文献

[1] EVANS J S O, HU Z, JORGENSEN J D, et al. Compressibility, phase transitions, and oxygen migration in zirconium tungstate, ZrW₂O₈[J]. Science, 1997, 275(5296): 61-65.
[2] 王献立, 付林杰, 许坤. 负热膨胀材料的研究及应用[J]. 信息记录材料, 2018, 19(12): 38-39.
WANG X L, FU L J, XU K. The study and applying of negative thermal expansion materials[J]. Information Recording Materials, 2018, 19(12): 38-39 (in Chinese).
[3] 石业平, 袁保合, 梁二军. P替代对ZrV₂O₇介电与电导性能的影响[J]. 人工晶体学报, 2019, 48(10): 1938-1944.
SHI Y P, YUAN B H, LIANG E J. Effect of P substitution on dielectric and conductive properties of ZrV₂O₇[J]. Journal of Synthetic Crystals, 2019, 48(10): 1938-1944 (in Chinese).
[4] LIANG E J. Negative thermal expansion materials and their applications: a survey of recent patents[J]. Recent Patents on Materials Science, 2010, 3(2): 106-128.
[5] TUCKER M G, GOODWIN A L, DOVE M T, et al. Negative thermal expansion in ZrW₂O₈: mechanisms, rigid unit modes, and neutron total scattering[J]. Physical Review Letters, 2005, 95(25): 255501.
[6] HAO X K, WANG M Y, LIU X S, et al. High configurational entropy for low phase transition temperature and thermal expansion of A₂M₃O₁₂ oxide ceramics[J]. Ceramics International, 2023, 49(20): 33051-33056.
[7] 付林杰, 王献立, 王伟鹏, 等. ZrSc_xAl_1-xW₂VO₁₂(x=0, 0.3, 0.5, 0.7, 1)陶瓷材料的热膨胀性能研究[J]. 人工晶体学报, 2019, 48(9): 1703-1706+1711.
FU L J, WANG X L, WANG W P, et al. Thermal expansion property of ZrSc_xAl_1-xW₂VO₁₂ ceramic materials(x=0, 0.3, 0.5, 0.7, 1)[J]. Journal of Synthetic Crystals, 2019, 48(9): 1703-1706+1711 (in Chinese).
[8] ARI M, JARDIM P M, MARINKOVIC B A, et al. Thermal expansion of Cr_2xFe_2-2xMo₃O₁₂, Al_2xFe_2-2xMo₃O₁₂ and Al_2xCr_2-2xMo₃O₁₂ solid solutions[J]. Journal of Solid State Chemistry, 2008, 181(6): 1472-1479.
[9] VARGA T, MOATS J L, USHAKOV S V, et al. Thermochemistry of A₂M₃O₁₂ negative thermal expansion materials[J]. Journal of Materials Research, 2007, 22(9): 2512-2521.
[10] RONG W L, LIU F A, WANG X M, et al. Crystal growth and negative thermal expansion properties of a Y₂Mo₄O₁₅ single crystal[J]. RSC Advances, 2023, 13(19): 13006-13013.
[11] WANG L, WANG F, YUAN P F, et al. Negative thermal expansion correlated with polyhedral movements and distortions in orthorhombic Y₂Mo₃O₁₂[J]. Materials Research Bulletin, 2013, 48(7): 2724-2729.
[12] LIANG E J, LIANG Y, ZHAO Y, et al. Low-frequency phonon modes and negative thermal expansion in A(MO₄)₂ (A=Zr, Hf and M=W, Mo) by Raman and Terahertz time-domain spectroscopy[J]. The Journal of Physical Chemistry A, 2008, 112(49): 12582-12587.
[13] YOUNG L, ALVAREZ P T, LIU H F, et al. Extremely low temperature crystallization in the A₂M₃O₁₂ family of negative thermal expansion materials[J]. European Journal of Inorganic Chemistry, 2016, 2016(8): 1251-1256.
[14] LIU H F, ZHANG H, HUANG F Y, et al. Preparation of In_0.5Sc_1.5Mo₃O₁₂ nanofibers and its negative thermal expansion property[J]. Ceramics International, 2023, 49(19): 31627-31633.
[15] 杨海涛, 刁志聪, 尚福亮, 等. Y_2-xSm_xW₃O₁₂固溶体的制备及热膨胀性能研究[J]. 中国钨业, 2010, 25(5): 40-43.
YANG H T, DIAO Z C, SHANG F L, et al. Thermal expansion properties of solid solution Y_2-xSm_xW₃O₁₂[J]. China Tungsten Industry, 2010, 25(5): 40-43 (in Chinese).
[16] 程永光, 刘献省, 宋文博, 等. Y_2-x(LiMg)_xMo₃O₁₂固溶体吸水性与热膨胀性能研究[J]. 光散射学报, 2014, 26(3): 258-264.
CHENG Y G, LIU X S, SONG W B, et al. Hygroscopicity and thermal expansion properties of Y_2-x(LiMg)_xMo₃O₁₂ solid solutions[J]. The Journal of Light Scattering, 2014, 26(3): 258-264 (in Chinese).
[17] LIANG E J, HUO H L, WANG J P, et al. Effect of water species on the phonon modes in orthorhombic Y₂(MoO₄)₃ revealed by Raman spectroscopy[J]. The Journal of Physical Chemistry C, 2008, 112(16): 6577-6581.
[18] SUMITHRA S, UMARJI A M. Hygroscopicity and bulk thermal expansion in Y₂W₃O₁₂[J]. Materials Research Bulletin, 2005, 40(1): 167-176.
[19] WOODCOCK D A, LIGHTFOOT P, RITTER C. Negative thermal expansion in Y₂(WO₄)₃[J]. Journal of Solid State Chemistry, 2000, 149(1): 92-98.

(ZrCa)_xY_2-2xW₃O₁₂固溶体吸水性及热膨胀性能研究

Hygroscopicity and Thermal Expansion Properties of (ZrCa)_xY_2-2xW₃O₁₂ Solid Solution

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