Journal of Synthetic Crystals ›› 2026, Vol. 55 ›› Issue (1): 77-84.DOI: 10.16553/j.cnki.issn1000-985x.2025.0147
• Research Articles • Previous Articles Next Articles
TENG Man1(
), LIU Qinghui1, LIU Peng1(
), LI Bin2, WANG Haili3
Received:2025-07-14
Online:2026-01-20
Published:2026-02-05
Contact:
LIU Peng
CLC Number:
TENG Man, LIU Qinghui, LIU Peng, LI Bin, WANG Haili. Effect of Y2O3 on Optical and Mechanical Properties of MgAl2O4 Transparent Ceramics[J]. Journal of Synthetic Crystals, 2026, 55(1): 77-84.
Fig.1 SEM images of MgAl2O4 powder (a), Y2O3 powder (b), and mixed powder after ball milling (c), and XRD patterns of MgAl2O4 powder and MgAl2O4 ceramics sintered at 1 550 ℃(d)
Fig.2 Transmission curves of MgAl2O4 transparent ceramics with different Y2O3 doping concentrations prepared by HIP at 1 540 ℃ under different presintering conditions
Fig.3 Transmission curves of MgAl2O4 transparent ceramics with different Y2O3 doping concentrations prepared by HIP at 1 600 ℃ under different presintering conditions
Fig.4 (a) Sintering curves of pure MgAl2O4 ceramics after presintering; (b) SEM image of thermal corrosion surface of MgAl2O4 ceramics under presintering at 1 525 ℃; (c) sintering curves of MgAl2O4 ceramics doped with 0.010% Y2O3
Fig.5 Comparison of highest transmittance of MgAl2O4 transparent ceramics with different Y?O? doping concentrations under different presintering conditions. (a) HIP at 1 600 ℃; (b) HIP at 1 650 ℃; (c) comparison of transmittance of MgAl2O4 transparent ceramics with best optical quality at different HIP temperatures
Fig.6 SEM images of thermal crrosion surface of MgAl2O4 transparent ceramics with different Y2O3 doping concentrations after presintering at 1 525 ℃ and HIP at 1 600 ℃
Fig.8 EDX analysis (a) and HRTEM image (b) of grain boundary of MgAl2O4 transparent ceramics doped with 0.020% Y2O3 after presintering at 1 525 ℃ and HIP at 1 600 ℃
| [1] | HAN D, ZHANG J, LIU P, et al. Effect of the pre-sintering atmosphere on the microstructures and optical qualities of transparent spinel ceramics[J]. Ceramics International, 2022, 48(6): 7806-7814. |
| [2] | SALEM S. Technical aspect for oxidation of magnesium and aluminum nitrates to manufacture nano- and micro-sized MgAl2O4 spinel by combustion method[J]. Journal of Advanced Ceramics, 2017, 6(3): 187-195. |
| [3] | GAJDOWSKI C, D’ELIA R, FADERL N, et al. Mechanical and optical properties of MgAl2O4 ceramics and ballistic efficiency of spinel based armour[J]. Ceramics International, 2022, 48(13): 18199-18211. |
| [4] | 雷牧云, 李 祯, 张 微, 等. 镁铝尖晶石透明陶瓷的研究进展[J]. 人工晶体学报, 2023, 52(12): 2108-2124. |
| LEI M Y, LI Z, ZHANG W, et al. Research progress on magnesium aluminate spinel transparent ceramic[J]. Journal of Synthetic Crystals, 2023, 52(12): 2108-2124 (in Chinese). | |
| [5] | 郑培毓, 张 玲, 张晓序, 等. MgO源对纳米η-Al2O3制备镁铝尖晶石的影响[J]. 硅酸盐通报, 2021, 40(3): 1046-1051. |
| ZHENG P Y, ZHANG L, ZHANG X X, et al. Effect of MgO source on preparation of magnesium aluminate spinel by nano-η-Al2O3 [J]. Bulletin of the Chinese Ceramic Society, 2021, 40(3): 1046-1051 (in Chinese). | |
| [6] | REDDY K P R, COOPER A R. Oxygen diffusion in magnesium aluminate spinel[J]. Journal of the American Ceramic Society, 1981, 64(6): 368-371. |
| [7] | ZHANG Y B, WANG S, LIU B, et al. Effect of R2O3 (R=Y, La) on the microstructure, optical, and photoluminescent properties of MgAl2O4∶Cr3+ transparent ceramics[J]. Optical Materials, 2023, 136: 113454. |
| [8] | WAETZIG K, HUTZLER T. Highest UV-vis transparency of MgAl2O4 spinel ceramics prepared by hot pressing with LiF[J]. Journal of the European Ceramic Society, 2017, 37(5): 2259-2263. |
| [9] | SOKOL M, HALABI M, KALABUKHOV S, et al. Nano-structured MgAl2O4 spinel consolidated by high pressure spark plasma sintering (HPSPS)[J]. Journal of the European Ceramic Society, 2017, 37(2): 755-762. |
| [10] | AZIZI-MALEKABADI M, SARRAF-MAMOORY R. Devising a novel method of producing high transparent magnesium aluminate spinel (MgAl2O4) ceramics body using synthesized LiF nanopowder and spark plasma sintering[J]. Materials Chemistry and Physics, 2020, 250: 123035. |
| [11] | LIU L H, MORITA K. Fabrication of MgAl2O4/Al2O3 laminated transparent composite by spark-plasma-sintering (SPS) processing[J]. Scripta Materialia, 2021, 205: 114205. |
| [12] | BENAISSA S, HAMIDOUCHE M, KOLLI M, et al. Characterization of nanostructured MgAl2O4 ceramics fabricated by spark plasma sintering[J]. Ceramics International, 2016, 42(7): 8839-8846. |
| [13] | MORITA K, KIM B N, YOSHIDA H, et al. Distribution of carbon contamination in MgAl2O4 spinel occurring during spark-plasma-sintering (SPS) processing: I-Effect of heating rate and post-annealing[J]. Journal of the European Ceramic Society, 2018, 38(6): 2588-2595. |
| [14] | LIU Q, JING Y Q, SU S, et al. Microstructure and properties of MgAl2O4 transparent ceramics fabricated by hot isostatic pressing[J]. Optical Materials, 2020, 104: 109938. |
| [15] | JING Y Q, LIU Q, SU S, et al. Fabrication of highly transparent Co∶MgAl2O4 ceramic saturable absorber for passive Q-switching in 1.5 μm[J]. Journal of Inorganic Materials, 2021: 679. |
| [16] | ESPOSITO L, PIANCASTELLI A, MARTELLI S. Production and characterization of transparent MgAl2O4 prepared by hot pressing[J]. Journal of the European Ceramic Society, 2013, 33(4): 737-747. |
| [17] | BALABANOV S S, BELYAEV A V, NOVIKOVA A V, et al. Densification peculiarities of transparent MgAl2O4 ceramics: effect of LiF sintering additive[J]. Inorganic Materials, 2018, 54(10): 1045-1050. |
| [18] | SENINA M O, LEMESHEV D O, VERSHININ D I, et al. Effect of B2O3 concentration on the properties of transparent magnesium aluminate spinel ceramics[J]. Inorganic Materials, 2019, 55(8): 846-850. |
| [19] | JING Y Q, LIU Q, MAO X Y, et al. Influence of CaO on microstructure and properties of MgAl2O4 transparent ceramics[J]. Optical Materials, 2021, 111: 110604. |
| [20] | MOHAN S K, SARKAR R. Effect of ZrO2 addition on MgAl2O4 spinel from commercial grade oxide reactants[J]. Ceramics International, 2016, 42(8): 10355-10365. |
| [21] | 邢钰培, 刘 鹏, 韩 丹, 等. La3+ 对MgAl2O4透明陶瓷致密化过程、光学及力学性能的影响[J]. 硅酸盐通报, 2024, 43(3): 1048-1057. |
| XING Y P, LIU P, HAN D, et al. Effect of La3+ on densification process, optical and mechanical properties of MgAl2O4 transparent ceramics[J]. Bulletin of the Chinese Ceramic Society, 2024, 43(3): 1048-1057 (in Chinese). | |
| [22] | BARUAH B, PARIJA S K, SARKAR R. Effect of rare-earth oxides on reaction sintered non-stoichiometric magnesium aluminate spinel[J]. Transactions of the Indian Ceramic Society, 2023, 82(2): 115-121. |
| [23] | 郭浩然, 闫 晖, 单英春, 等. Pechini法制备Y2O3的煅烧温度对无压烧结AlON陶瓷透光性的影响[J]. 人工晶体学报, 2024, 53(11): 2004-2012. |
| GUO H R, YAN H, SHAN Y C, et al. Effects of calcining temperature in the preparation of Y2O3 by Pechini method on the transparency of pressureless sintered AlON ceramics[J]. Journal of Synthetic Crystals, 2024, 53(11): 2004-2012 (in Chinese). | |
| [24] | GUO H R, MA L Y, WANG Y Q, et al. Fast pressureless sintering of highly transparent AlON ceramics by reducing Y enrichment with nano-sized granular Y2O3 as additive[J]. Journal of the European Ceramic Society, 2024, 44(10): 6013-6023. |
| [25] | BARUAH B, SARKAR R. Effect of Y2O3 content on densification, microstructure and mechanical properties of reaction sintered magnesium aluminate spinel[J]. Ceramics International, 2023, 49(1): 755-765. |
| [26] | HASAN M M, DHOLABHAI P P, DEY S, et al. Reduced grain boundary energies in rare-earth doped MgAl2O4 spinel and consequent grain growth inhibition[J]. Journal of the European Ceramic Society, 2017, 37(13): 4043-4050. |
| [1] | LEI Muyun, WANG Ying, LING Hao, WANG Haili, LI Zhen, ZHANG Lisheng. Fabrication of Magnesium-Aluminate Spinel Transparent Ceramics by Two Cycles of Hot Pressing Sintering Method [J]. Journal of Synthetic Crystals, 2026, 55(1): 85-92. |
| [2] | GU Dong, DONG Ling, YANG Jiwei, LI Haiping, LI Jie, ZHU Guisheng, XU Huarui. Properties of Infrared-Visible Compatible Stealth Films Based on ITO/Al/ITO Structures [J]. Journal of Synthetic Crystals, 2025, 54(9): 1607-1613. |
| [3] | DOU Ying, WANG Yingmin, GAO Yanzhao, CHENG Hongjuan. Impact of Selenium Addition on Electrical and Optical Properties of CdSe Single Crystal [J]. Journal of Synthetic Crystals, 2025, 54(8): 1403-1409. |
| [4] | LI Yan, HAN Sun, XU Cheng. Preparation and Performance Study of Liquid Protective Film [J]. Journal of Synthetic Crystals, 2025, 54(6): 1078-1088. |
| [5] | ZHU Jiayi, DU Shuai, ZHOU Pengfei, ZHENG Fan, CHEN Yunlin. Preparation of LiNbO3/ITO Heterojunction Thin Films and Its Optoelectronic Properties [J]. Journal of Synthetic Crystals, 2025, 54(5): 819-824. |
| [6] | HUO Xiaoqing, ZHANG Shengnan, ZHOU Jinjie, WANG Yingmin, CHENG Hongjuan, SUN Qisheng. Preparation and Properties of 3~4 Inch Fe Doped β-Ga2O3 Single Crystal with High Resistance [J]. Journal of Synthetic Crystals, 2025, 54(3): 407-413. |
| [7] | ZHOU Guanggang, WEN Xin’ai, MAO Caiju, CHEN Wenxuan, WANG Xiaochun, CHEN Songhao, ZHOU Xiangyu, ZHANG Wansong, WU Chong. Effect of Oxalic Acid Doping on Optical and Thermal Properties of KDP Crystals [J]. Journal of Synthetic Crystals, 2025, 54(11): 1916-1922. |
| [8] | ZHANG Heng, LIU Congfeng, YUAN Ningyi, SUN Shiwen. Effect of Inclusion Defects on Resistivity of CdZnTe Crystals [J]. Journal of Synthetic Crystals, 2025, 54(11): 1923-1930. |
| [9] | CHU Xuefeng, HUANG Linmao, ZHANG Qi, XIE Yihan, HU Xiaojun. Characterization and Analysis of Indium Tin Oxide (ITO) and Fluotin Oxide (FTO) Transparent Conductive Films [J]. JOURNAL OF SYNTHETIC CRYSTALS, 2024, 53(5): 848-854. |
| [10] | ZHAO Wenhai, TAO Shixu, TONG Siyi, TANG Jian, ZUO Chuandong, CAO Yongge, MA Chaoyang. Research Progress on Lu2O3 Based Laser Transparent Ceramics [J]. JOURNAL OF SYNTHETIC CRYSTALS, 2024, 53(12): 2043-2058. |
| [11] | GAN Shiyan, MEI Bingchu, LI Weiwei. Preparation and Spectral Properties of Er, Na:CaF2 Transparent Ceramics [J]. JOURNAL OF SYNTHETIC CRYSTALS, 2024, 53(12): 2059-2065. |
| [12] | LI Qing, JIANG Zhenxing, WANG Ying, MA Jie, WANG Jun, LIU Peng, ZHANG Jian, FAN Jintai, YU Haohai, ZHANG Huaijin, TANG Dingyuan. Fabrication and Laser Performance of Yb∶Lu2O3 Transparent Ceramics [J]. JOURNAL OF SYNTHETIC CRYSTALS, 2024, 53(11): 1884-1891. |
| [13] | LIU Ziyu, ZHENG Wenwen, FENG Yagang, YE Junhao, LIU Peng, YANG Xianfeng, LI Jiang. Fabrication and Properties of Er∶Lu2O3 Transparent Ceramics with Different Doping Concentrations [J]. JOURNAL OF SYNTHETIC CRYSTALS, 2024, 53(11): 1892-1900. |
| [14] | FENG Yagang, TIAN Feng, LIU Ziyu, LIU Yiyang, WU Lexiang, LI Tingsong, LI Jiang. Fabrication and Properties of Layer-Structured YAG/Yb∶YAG Transparent Ceramics [J]. JOURNAL OF SYNTHETIC CRYSTALS, 2024, 53(11): 1901-1908. |
| [15] | HUANG Qiufeng, DENG Zhiqiang, CHEN Jian, GUO Wang, DENG Zhonghua, LIU Zhuguang, HUANG Jiquan. Valence Regulation and Optical Properties of Cr-Doped YAG Transparent Ceramics [J]. JOURNAL OF SYNTHETIC CRYSTALS, 2024, 53(11): 1909-1917. |
| Viewed | ||||||
|
Full text |
|
|||||
|
Abstract |
|
|||||
E-mail Alert
RSS