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    15 December 2017, Volume 46 Issue 12
    Microscopic Morphology and Magnetic Properties of Co Doped CeO2 Nanocrystals Prepared by Hydrothermal Method
    YANG Sheng-hong;ZHANG Yue-li
    2017, 46(12):  2307-2312. 
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    Co doped CeO 2 nanocrystals with different Co concentrations were prepared by hydrothermal method .The crystal structure , microscopic morphology and magnetic properties of these nanocrystals were investigated by XRD, Raman, SEM and PPMS.The results of XRD and Raman indicate that the CeO2 nanocrystals with different Co concentrations are cubic fluorite structure .No Co and Co oxides peaks were found, which indicates that Co doping replaced the Ce in CeO 2 lattice.The characteristic peaks of XRD show no obvious translation , so the lattice distortion of CeO 2 is not obvious due to Co doping .SEM images show that the nanocrystals are octahedrites with an edge length of about 600-800 nm.Microscopic morphology of Co doped CeO 2 nanocrystals has obvious relationship with the Co doping concentration . With the increase of Co doping concentration , the edge of octahedrites become from clear to fuzzy , and the surface from smooth to rough .PPMS measurements show that all the samples exhibit room temperature ferromagnetism .With the increase of Co doping concentration , the saturation magnetization increases first and then decreases , and the 5;Co doped CeO 2 nanocrystals has the maximum saturation magnetization .The magnetic properties of nanocrystals are obviously changed by different Co doping concentration .The room temperature ferromagnetism of nanocrystals can be modulated by changing the concentration of Co .
    Preparation of InAs/Si (211) Thin Films by Hot Wall Epitaxy and Their Electrical Properties
    HE Li-li;ZHANG Ming;GUO Zhi-ping;LIU Xiang;WU Chang-shu
    2017, 46(12):  2313-2318. 
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    High preferred orientation InAs films were prepared on the surface of single crystalline Si (211) substrates by Hot Wall Epitaxy ( HWE) deposition.The effects of growth temperatures (300 ℃, 350 ℃, 400℃, 450℃, and 500℃) on the structure and electrical properties of the films were studied in details.The phase structure , surface morphology , electrical and optical properties of the films were characterized by X-ray diffraction ( XRD ) , scanning electron microscopy ( SEM ) , atomic force microscopy ( AFM ) and hall measurements ( Hall ) . The results indicate that the InAs films are successfully deposited on the surface of Si (211) substrates by HWE technique .All the films were shown preferentially grown along the ( 111 ) direction with zinc blende structure .With the growth temperature increasing from 300℃ to 500℃, and the full width at half maximum (FWHM) of (111) peak decreases initially and then increases accordingly .The grain size , carrier concentration and Hall mobility of the InAs thin film reaches 73.4 nm, 1022 cm -3 and 102 cm2/(V· s) at 400℃ respectively, which suggests that the optimal growth temperature increases the carrier density significantly by degrading defect recombination .The crystal quality and electrical performance of the films were improved accordingly .The results of SEM and AFM show that the growth of InAs on Si ( 211 ) substrate were mainly three dimensional ( S-K ) growth mode , due to the high lattice mismatch and the special orientation of Si substrate tilted ( 211 ) plane.The surface roughness ( Ra ) decreases first and then increases with increasing of the growth temperatures .The Ra of the film at 400 ℃reaches 48.37 nm.
    Crystal Growth Habit of Hexagonal Flake Magnesium Hydroxide Synthesized by One-step Hydrothermal Method
    FAN Tian-bo;JIANG Yu;LIU Lu-ping;ZHOU Yong-hong;LI Xue;GUO Hong-fan;LI Li;LIU Yun-yi
    2017, 46(12):  2319-2325. 
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    Using magnesium nitrate as reaction material , hexagonal flake magnesium hydroxide were synthesized with gaseous ammonia as precipitator in one-step hydrothermal method .The product was characterized with scanning electron microscope ( SEM) and X-ray powder diffraction ( XRD) .The results show that the optimum temperature was 120 ℃.Growth habit of magnesium hydroxide wais analyzed theoretically through Morphology program .Morphology program is used to calculate the surface energy , surface attachment energy and crystal area percentage of the main exposed surface .The results show that the main exposed surface of magnesium hydroxide will be (001) plane and the regularly exposed surface of magnesium hydroxide will be ( 101 ) plane, most of the morphology of magnesium hydroxide will display the shape of orthohexagonal flake , but will be mixed with irregular hexagonal flake structure .The calculated results are identical with the experimental results .Non-ideality of morphology is caused by exposure degree of ( 001 ) plane changing with temperature .The results lay a foundation for further research on nonideal morphology mechanism .
    Preparation and Characterization of Dye-sensitized Solar Cells by Liquid Phase Deposition Method at Low Temperature
    GUO Su-wen;SUN Yi-ran;QI Jia-bin;ZHENG Yan;ZHANG Qing-hong
    2017, 46(12):  2326-2331. 
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    In order to explore the new method for preparing the TiO 2 thin film, this experiment use liquid phase deposition method to fabricate thin film on the condition of constant temperature and variable temperature .The FTO conductive glass and flexible PET-ITO were selected to be compared .XRD results show that the products are anatase phase titanium dioxide , the conditionof 80 ℃ in favour of better crystallinity .SEM results show the porous structure of TiO 2 film layer .Theefficiency prepared on the condition of variable temperature is the highest , and the sample prepared in 60 ℃ has higher efficiency than it prepared in 80℃.The efficiency of cells prepared at gradient temperature based on FTO reached 5.71;, and on the same conditions the efficiency of cells based on PET-ITO is 4.07;.
    Preparation and Properties of Porous Alumina Ceramics by Phosphate Bonding Method
    FENG Xin;LIU Tao;LI Yang
    2017, 46(12):  2332-2336. 
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    Porous alumina ceramics were prepared by methods of compression molding , drying and sintering with calcined α-Al2 O3 powder as aggregate , aluminum dihydrogen phosphate as binder and paraffin as molding promoter .The effect of sintering temperature and aluminum dihydrogen phosphate content on microstructure , phase composition , linear shrinkage , porosity and flexural strength were studied.The mechanisms of sintering by phosphate bonding method were discussed .Results show that the phase compositions of porous alumina ceramics are α-Al2 O3 and AlPO4 .Porous alumina ceramics are formed by AlPO4 bonding among alumina particles at low temperature .With increasing aluminum dihydrogen phosphate content , the linear shrinkage and flexural strength increase smoothly , while the porosity decrease .The existence of AlPO 4 accelerates the liquid-phase sintering among the alumina particles at high temperature .The linear shrinkage and flexural strength increase sharply with increasing sintering temperature , and the porosity decrease obviously .
    Study on the Crystalline Silicon Films Induced by Monocrystalline Silicon with Epitaxial Growth
    YANG Qi-ming;YANG Wen;DUAN Liang-fei;YAO Chao-hui;YANG Pei-zhi
    2017, 46(12):  2337-2342. 
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    Amorphous silicon films were prepared by magnetron co-sputtering on the substrates of P type monocrystalline silicon , which have been corroded and cleaned via a mixed of acid solutions .The silicon films were realized by a rapid thermal annealing ( RTP) at 480 ℃ for 30 min in N2 atmosphere .Optical metallographic microscope , X-ray diffractometer and Raman scattering were used to characterize the silicon films and monocrystalline substrates .The corrosion effect of mixed acid solution on monocrystalline silicon surface , the structures and band gaps of the films were investigated .The results show that , the smooth surface was obtained after the monocrystalline silicon was corroded by mixed acid solution , a-Si films was turned to crystalline silicon films after rapid thermal annealing and crystal-induced by seed crystal.The crystallization rate raduced from 90.0; to 37.0;, the grain size reduced from 6.65 nm to 1.71 nm, the band gap increased from 1.18 eV to 1.52 eV and the roughness decreased with the a-Si films increasing from 80 nm to 280 nm.
    Thermodynamic Conditions of the Nucleation and Growth of Si Nanoparticles Prepared by Pulsed Laser Ablation
    QIN Ai-li;CHU Li-zhi;DENG Ze-chao;DING Xue-cheng;WANG Ying-long
    2017, 46(12):  2343-2347. 
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    Monte Carlo method was used to simulate silicon nanoparticles produced by pulsed laser ablation in this paper .Combined with the drag force model , the degree of supersaturation suitable for the nucleation and growth was calculated .The results show that the substrate of the secondary sputter causing the nucleation times increase , which lead to the number of small size grains increase; the range of the supersaturation degree suitable for nucleation and growth is different , when the degree of supersaturation is larger ( >2600 ) the nucleation times is more and the growth times is less; when the degree of supersaturation is smaller (250-2600) the growth times is more and the nucleation times is less .
    Synthesis and Photoelectric Properties of Cu2 SnSe3 Nanocrystals with Hot-injection Method
    LIU Yi-ke;TANG Ya-qin;WU Yu-jiao;LIU Fang-yang;JIANG Liang-xing
    2017, 46(12):  2348-2351. 
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    Cu2 SnSe3 nanocrystals were synthesized by a hot-injection method using copper acetylacetonate (Ⅱ) (Cu(acac)2), tin (Ⅱ) chloride, and Se-OLA suspension as reaction precursor.As-synthesized Cu2 SnSe3 nanocrystals were characterized by means of TEM , XRD and EDS.The influence of reaction temperatures on the synthesis was discussed .The Cu2 SnSe3 nanocrystals film yields a good photoresponse in photoelectrochemical tests .The results demonstrate that the synthesized Cu 2 SnSe 3 nanocrystals have potential application in the field of photoelectric conversion .
    Effect of Y2O3-Al2O3 Contents on Phase Composition, Densification, Microstructure and Mechanical Properties of Si3N4 Ceramics
    LIU Cong;GUO Wei-ming;ZHAO Zhe;WU Shang-hua
    2017, 46(12):  2352-2355. 
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    The Si3N4 ceramics were prepared by hot-pressing at 1800℃using different amounts of Y2O3-Al2O3 as sintering additives and α-Si3N4 as raw powder.The effects of Y2O3-Al2O3 content on phase composition , densification , microstructure and mechanical properties were studied .The results show that dense Si3N4 ceramics could be hot-pressed by the addition of 6wt;Y2O3-Al2O3 at 1800 ℃.The densification of Si3N4 ceramics was not affected by the further increase of Y2O3-Al2O3 content, whereas the amounts of α-Si3N4 and β-Si3N4 phases in the ceramics were influenced by the Y2O3-Al2O3 content. The higher Y2O3-Al2O3 content could promote the α-βphase transformation .Regardless of the Y2O3-Al2O3 content , the Si3N4 ceramics had bimodal microstructures composed of fine equiaxedgrains and large elongated grains.When the Y2O3-Al2O3 content increased to 10wt;, the Si3N4 ceramics with higher content of elongated grains show more bimodal microstructure .Based on the present study , it was found that the Si3N4 ceramics with high hardness and high strength could be prepared by the addition of low Y2O3-Al2O3 content(6wt;), and the Si3N4 ceramics with high toughness and high strength could be obtained by the addition of high Y2O3-Al2O3 content(10wt;).
    Experimental Study on the Lapping of Single Crystal Sapphire Dome Using Magnetic Abrasive Finishing
    ZHANG Wu-hui;LU Wen-zhuang;YANG Kai
    2017, 46(12):  2356-2361. 
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    The lapping experiment of single crystal sapphire dome using micro-diamond magnetic abrasive under the control of magnetic field was studied .The effects of lapping pressure , lapping time and ethylenediamine concentration on the removal rate and surface roughness of single crystal sapphire dome were studied systematically .The experimental results show that with the increase of lapping pressure , the removal rate increases but the increase is reduced and the surface roughness decreases but the decrease is reduced.When the concentration of ethylenediamine was 3;and pressure was 25 kPa, the removal rate in the first 30 min can remain above 5 μm· h -1 , but after 30 min, the removal rate began to appear a significant decline .Surface roughness in the first 30 min was reduced to about 110 nm quickly , slightly lower after 30 min.
    First-Principle Study on Electronic Structure and Optical Properties of Rare Earth Elements Sm and C Co-doped SnO2
    PENG Cai-yun;LEI Bo-cheng;XIA Tong;ZHANG Li-li;HUANG Yi-neng
    2017, 46(12):  2362-2368. 
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    Using the first-principles density functional theory , band structures , electronic density of states and optical properties of Sm-doped , C-doped , and Sm-C co-doped SnO 2 systems were calculated .The results show that the Sm-C co-doped SnO 2 structure in which Sm and C are the nearest neighbors is more stable than that of the next-nearest.The energy gap of the co-doped system is minimum , as demonstrates that the energy which made the electrons excite from valence band into the conduction band is the least . the optical absorption edge of the doped systems appeared shifted towards the longer wavelength side , and the degree of the shifting of Sm-C co-doped system is very big , which states that the doping led to expand the range of responding to visible light .The reflection coefficient , static dielectric constant , and static refractive index of doped systems are all bigger than those of pure SnO 2 , especially the optical values of Sm-C co-doped system is the greatest .
    Effect of NH3 Flow Rate on the Structures and Optical Properties of Silicon Rich SiNx Thin Films
    GU Xin;ZHOU Bing-qing;WENG Xiu-zhang;BU Xin-xin;DING De-song
    2017, 46(12):  2369-2373. 
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    With NH3 , SiH4 and N2 as reaction gas, silicon-rich nitride thin films were produced by plasma enhanced chemical vapor deposition method . In the case of optimizing other depositional parameters, the effects of NH3 flow rate were studied on the structures and on optical properties of silicon-rich SiNx thin films.The bonding situation and band gap structures of the film samples were analyzed by Fourier transform infrared absorption , ultraviolet-visible absorption spectrum and XRD .Its research result shows that with the increase of NH3 flow rate, the Si-N bond and N-H bond in the films are strengthened , but the Si-H bond is descended and moves to high wave-number.Meanwhile, the film transformation occurs from amorphous SiN x phase to small crystal Si3N4 phase .Besides , with the increase of NH3 flow rate, the optical band gap of the film is widened gradually and the order degree of the microscopic structures is decreased .In addition, the analysis of XRD pattern shows that the size of the average crystal grain in the films increases gradually with the increase of NH3 flow rate.Based on the above analysis , the conclusion comes that an appropriate increase of NH3 flow rate will contribute to the transformations of films from amorphous SiNx phase to small crystal Si3N4 phase.
    Preparation and Thermal Properties of Shape-stabilized Na2SO4·10H2O Composite PCM with Different Carriers
    LIU Lei;PENG Ben;QIU Gui-bo;GUO Min;CHENG Fang-qin;ZHANG Mei
    2017, 46(12):  2374-2379. 
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    Energy conservation has great significance in today's society.In this paper, Na2SO4 · 10H2O was selected as a phase change material ( PCM ) which was encapsulated into different carriers , such as SiO2 aerogels, X-type molecular sieves, expanded perlite, activated carbon and diatomite by using direct impregnation method for preventing the leakage and guaranteeing the long-term thermal stability during the phase transition .Test results of SEM , DSC and XRD show that the percentage of PCM in the different adsorbents is 80.0;,82.2;,76.9;,89.2; and 60.6; respectively after saturation adsorption . Compared with other carriers the expanded perlite ( EP ) is the most cost-effective carrier material in terms of thermal properties , mechanical properties and cost .The Na2SO4 · 10H2O/EP composite phase change material was further detected for the thermal cycle experiment .After 100 cycles, its calorific value loss is less than 15;, and the undercooling is within 10℃, indicating that the Na2SO4· 10H2O/EP has a good thermal stability .
    Effect of In, Gd Co-doping on the Performance of BaCeO3-based Proton Conductor
    MA Xin-yu;YANG Chun-li;YAN Min;LYU Qiang;CHEN Hong
    2017, 46(12):  2380-2385. 
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    High temperature proton conductors were widely studied , because of their using in fuel cell , hydrogen separation membrane and hydrogen sensor , etc.In this paper, In and Gd co-doped BaCeO3 proton conductors were prepared by modified citrate method .The microstructure , chemical stability and electrical conductivity were further studied .The results show that the basicity of the system is improved after doping due to the low electronegativity of Gd , which leads to poor chemical stability .However , the ion radius of Gd is smaller than that of Ce , which is more favorable for ion transportation .Therefore , Gd single-doping and In , Gd co-doping samples have higher conductivity than traditional proton conductor samples.
    Preparation and Visible Light Photocatalytic Activity of Bi3Ti4O12/α-Bi2 O3/TiO2 Composite Photocatalyst
    WANG Rui-qi;XU Hai-yan;WU Si-wei;FU Min
    2017, 46(12):  2386-2392. 
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    Bi3 Ti4 O12/α-Bi2 O3/TiO2 composite photocatalyst was prepared by using industrial titanium dioxide (TiO2) and Bismuth nitrate pentahydrate (Bi(NO3)3 · 5H2O) as raw materials.Sample's structures were characterized by XRD , XPS, FT-IR, UV-vis, PL spectrum, etc.The results show that the Bi3 Ti4 O12/α-Bi2 O3/TiO2 heterojunction structure is formed .The band gap decreases , the absorption band edge is red shifted , and the photocatalytic efficiency is obviously improved .The photocatalytic activity was tested for the degradation of methylene blue solution under visible light irradiation .The results show that the photocatalytic activity of La doped TiO 2/g-C3 N4 composite photocatalyst is remarkable when the ratio of commercial titanium dioxide and Bismuth nitrate pentahydrate is 1:2.5, the calcination temperature was 600 ℃and the calcination time was 5 h.Irradiated by 12 W LED with 180 min, the degradation rate of MB reaches 96.8;.
    Preparation of Zirconium Silicate Film by Non-Hydrolytic Sol-Gel Method and Its Alkali Corrosion Resistance
    TAN Guang-fan;HU Qing;JIANG Wei-hui;LIU Jian-min;FENG Guo;CHEN Ting;LI Cong
    2017, 46(12):  2393-2398. 
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    Zirconium silicate ( ZrSiO4 ) film was prepared via non-hydrolytic sol-gel method ( NHSG ) combining dip coating process using Zirconium propoxide as zirconium source and tetraethyl orthosilicate as silicon source .The effects of precursor concentration and lifting rate on the morphology , microstructure and alkali corrosion resistance of ZrSiO 4 film were investigated by X-ray diffraction ( XRD ) , Fourier transform infrared spectrometer ( FTIR ) , Scanning electron microscopy ( SEM ) and Atomic force microscope ( AFM ) , respectively .The results show that the smooth and dense ZrSiO 4 film without cracking could be coated on the monocrystalline silicon when the precursor concentration is 0 .1 mol/L and the lifting rate is 1 mm/s.Monocrystalline silicon coated ZrSiO 4 film was soaked in 40; NaOH solution for 42 h at 40 ℃, only a relatively small pit corrosion on the surface was found , the mass varies a little with the corrosion time and the mass loss was only 0 .17;, which indicate that the ZrSiO 4 film had good alkali corrosion resistance .
    Preparation and Photocatalytic Activity of La, Fe Co-doped Mesoporous TiO2 Microspheres
    SONG Yang;YANG Li-rong;FENG Xiao-xin;LIU Xiao-yu;LIU Zhi-gang;XIE Peng-chao;ZHANG Li
    2017, 46(12):  2399-2405. 
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    The La/Fe co-doped monodisperse mesoporous TiO 2 microspheres were prepared by a triblock copolymer ( EO106 PO70 EO106 ( F127 ) ) modified sol-gel method with titanium (Ⅳ) isopropoxide as a titanium source.The prepared sample was characterized by X-ray diffraction, field emission scanning electron microscopy equipped with an energy-dispersive X-ray spectrum, TEM, BET, X-ray photoelectron spectroscopy and UV-visible diffuse reflectance spectroscopy , respectively . The photocatalytic activities of La/Fe co-doped mesoporous TiO 2 microspheres were characterized with methylene blue ( MB) solution as a target pollutant under ultraviolet light .The results show that La 3 +-doping restrains the increase of grain size , the UV-visible light absorption band of La 3 +/Fe3+co-doped TiO2 exhibited red-shift and the optical band gap of mesoporous TiO 2 microspheres is decreased .The photocatalytic activity of La3+(1at;) doped, La3+and Fe3+co-doped TiO2 mesoporous microspheres is higher than that of pure TiO 2 , and the photocatalytic activity of TiO 2 co-doped with Fe 3+( 1 at;) and La3+(1at;) is notably improved due to the cooperative actions of the two dopants .
    First-principles Study on the Electronic Structure and Optical Properties of Hf/Ta/W Doped Anatase TiO2
    FANG Zhi-ping;XIA Tong;LEI Bo-cheng;ZHANG Li-li;HUANG Yi-neng
    2017, 46(12):  2406-2411. 
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    The band structures, electronic density of states and optical properties of Hf-doped, Ta-doped, and W-doped TiO2 systems are computed by the first-principles based on density functional theory .The results show that the impurity leads tolargen the doped systems volumeas the impurity concentration increases.The doped systemsbandgap is less than that of pure TiO2 .From the band structure graphs of the Ta-doped, and W-doped TiO2 systems,it is found that the bottom of conduction band is under the Fermi level, as is known that the two kinds of doped systems are N-type semiconductor .With the various concentrations of Hf/Ta/W being doped in the TiO2 systems , the absorption spectrums of all the doped systems exhibitvarying degrees of red shift , and the light response range of Ta-doped, and W-doped TiO2 systems covers the entire visible area .Especially, the light responsiveness of Ti 0.9375 W0.0833 O2 in the visible region is the strongest .In a word, the impurity atoms ( Hf, Ta, W ) doped greatly improves the photocatalysis of the Anatase TiO2 .
    Hydrothermal Synthesis of ZnO/BiVO4 Composite Photocatalyst and Its Photocatalytic Activity
    LIU Xin;LUO Wen-jing;LI Jia-ke;LAN Feng-sha
    2017, 46(12):  2412-2416. 
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    ZnO/BiVO4 composite photocatalyst was prepared by hydrothermal method , and the influence of ZnO composite method ( directly adding or in-situ forming ) on the performance of ZnO/BiVO4 photocatalyst was studied .The crystal structure , morphology , specific surface area and optical absorption properties of the product were characterized using X-ray diffraction ( XRD ) , scanning electron microsocopy ( SEM) , BET and ultraviolet-visible spectrophotometer .The results show that the ZnO has effects on the phase composition and microstructure of the products , and new phases of V 2 O5 and Bi2 O3 are formed in the products , but the monoclinic BiVO 4 is still the main component .Comparing with the pure BiVO4 , the crystallinity and particle size of the composite become worse and smaller , but the photocatalytic activity of the product is improved . The photocatalytic performances of the samples prepared by direct composite method is improved greatly .The degradation rate of methylene blue is 90. 4; when irradiated for 240 min by high-pressure mercury lamp .The degradation rate of the pure BiVO 4 to methylene blue is only 82 .2;under the same conditions .
    Progress Research on Deposition of Large Size Single Crystal Diamond
    ZHANG Zhao;LU Wen-zhuang;ZUO Dun-wen
    2017, 46(12):  2417-2421. 
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    The unique properties of single crystal diamond (SCD) were stimulated the study of and search for its applications in many fields , including optics and electronics .In this article, the promising approaches to fabricating large size SCD were described while defects were presented simultaneously . Development status confirms the expectations thereby implying the feasibility of these methods of reaching required dimensions .
    Solvothermal Synthesis and Crystal Structure of Selenidostannate Cd( tren) SnSe3
    QI Fei-yan;BAIYIN Meng-he
    2017, 46(12):  2422-2426. 
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    A new selenidostannate Cd(tren)SnSe3(tren=tris(2-aminoethyl) amine) was synthesized by solvothermal method .The single crystal X-ray diffraction analysis show that the compound crystallizes in the triclinic, space group P-1, with a=0.7752(3) nm, b=0.8128(2) nm, c=1.2467(4) nm,α=97.299(19)°,β=103.639(18)°,γ=107.325(17)°, V=0.7121(4) nm3, Z=2, Dc =2.865 Mg· m-3 , Mr =614.21, F(000)=564.The compound is a zero-dimensional cluster structure and is formed by connecting two [Cd(tren)]2 +units from the trans-terminal Se atoms of the [Sn2Se6] unit.The results of UV-Vis diffuse reflectance spectra show that the band gap of the compound is 1.80 eV.
    Research Progress on Photocatalytic Properties of rGO/TiO2 and Its Ternary Composites
    YING Qi-wei;HE Xiao-fang;CAO Xin-xin
    2017, 46(12):  2427-2431. 
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    Excellent photocatalytic performance of rGO /TiO2 composites is possible for its application in the fields of organic dye degradation , rainwater disinfection and catalytic hydrogen evolution .Photocatalytic efficiency and chemical stability are enhanced by rGO /TiO2 composites combined with metals , metal compounds or polymers .The mechanism of reactions were analyzed , the focus and deficiencies of the present research were described , and future development and applications were foreseen .
    Study on Properties and Conductive Mechanism of Nano AgSnO2/Bi2O3 Contact Materials
    ZHAO Cai-tian;WANG Jing-qin;CAI Ya-nan;WANG Hai-tao
    2017, 46(12):  2432-2437. 
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    The electrical properties of AgSnO2 contact material with a small amount of the third element are in the experimental stage , but no theoretical reports were reported .Nano AgSnO2/Bi2O3 contact materials were prepared by sol-gel method.The density of the contact material is 9.73 g/cm3 , hardness is 105.35HV, conductivity is 70.22;IACS, and the contact resistance is smaller .On the basis of doping Bi can improve the properties of contact materials , the conductive mechanism was studied .The results show that the band gap becomes smaller , the electronic transitions easily , and the carrier concentration near Fermi level increases after Bi doping , which made the conductivity of the material enhanced.Finally, the mechanism of enhancing the electrical conductivity of AgSnO2 contact materials by adding a small amount of Bi elements was obtained .
    Effect of Vacuum and Hydrogen Annealing on the Electrical and Optical Properties of ZnO:B Thin Films
    LI Wang;TANG Lu;XUE Fei;LUO Zhe;GUO Peng;LIU Shi-yong
    2017, 46(12):  2438-2442. 
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    B doped ZnO ( BZO ) thin films were fabricated on glass substrates by LPCVD method .The effects of vacuum and hydrogen atmosphere annealing on the optical and electrical properties of BZO thin films were studied respectively .The results show that the two thermal treatments in vacuum and hydrogen atmosphere lead to reverse effects on optical and electric properties of BZO thin films .After vacuum annealing , the electrical conductivity of BZO thin films decreased with annealing temperature increasing and the total transmission of BZO thin films increased over long-wavelength range due to reduction of carrier concentration.On the contrary, after a post thermal treatment in hydrogen atmosphere , the electrical conductivity of the BZO films was obviously improved , simultaneously keeping the transmittance almost the same , which may be attributed to a dramatic increase of carrier mobility .This hydrogen annealing should provide a method for further improving the optical and electrical properties of BZO thin films.
    Preparation and Catalytic Characterization of Pt/SiC with Less Platinum for Oxygen Reduction Reaction
    WU Bing-bing;LI Qian-fu;SONG Kai-yue;ZHU Xiang;ZHANG Bei-lin;GUO Jia-hao
    2017, 46(12):  2443-2450. 
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    Pt/SiC cathode catalyst with 14; of platinum content was prepared by ethylene glycol refluxing method.The crystal structure , surface morphology and surface electronic structure were characterizated by X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM) and X-ray photoelectron spectroscopy (XPS).The electrocatalytic activities of Pt/SiC were characterizated by cyclic voltammetry(CV) and rotating disk electrode (RDE) techniques for oxygen reduction reaction (ORR).The results show that the average particle size of Pt in Pt/SiC catalyst synthesized at 180℃ is 3.4 nm and Pt is fcc structure.On the surface of SiC, Pt(0) is the main existence state, which is conducive to the adsorption and dissociation of O2 on the surface.The Pt/SiC-180 catalyst occupied a similar catalytic performance of commercial catalyst Pt/C(20;) for ORR.The onset potential for ORR at Pt/SiC-180 catalyst significantly shifts positively to 0.95 V, which is close to the onset potential for Pt/C electrodes (0.96 V).The ORR process at Pt/SiC-180 electrode is dominated by a 4-electron process with water as the product at low potential.Pt/SiC-180 catalyst has a higher stability toward ORR and better methanol tolerance than the commercial Pt/C in alkaline medium.Excellent catalytic activity and less platinum are expected to become the potential cathode catalytic material in fuel cell with low platinum .
    Preparation of g-C3N4/ZnCr-LDH Composites and Its Photocatalytic Degradation of Methyl Orange Wastewater
    CAO Le-le;LIANG Jin-tao;TIAN Hao-yang;YANG Hui-min;LIANG Zhen-hai
    2017, 46(12):  2451-2456. 
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    A series of g-C3 N4/ZnCr-LDH nanocomposites with different ratios were successfully prepared by in situ synthesis , the morphology , structure and photoelectrochemical properties were systematically studied, and the catalytic performance of the degradation of methyl orange was carried out under visible light.The results show that the combination of g-C3 N4 and ZnCr-LDH can enhance the absorption intensity of visible light , effectively inhibit the photo-electron-hole recombination , and improve the activity of the composite photocatalyst .The efficiency of degradation of methyl orange by 0.92CN/LDH composite photocatalyst is 97; at 2 h, which is 2 times higher than that of pure g-C3 N4 .Finally, after 5 cycles of continuous experiments , it was found that the degradation activity of the composite photocatalyst is still above 80;, which indicate that the composite has good stability .
    Effect of Ag-doped Sm2O3/TiO2 on the Photodegradation Performance of Methyl Orange
    WANG Shu-xian;LONG Teng;FU Wen-di;HUANG Min;LIU Yong;YOU Yao-hui;ZHENG Xiao-gang
    2017, 46(12):  2457-2463. 
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    The Ag-doped Ag-Sm2O3/TiO2 photocatalyst was synthesized using a photodeposition route , and performed for the UV-light driven photodegradation of methyl orange .The obtained Ag-Sm2O3/TiO2 samples were characterized by several techniques such as XRD , FT-IR, N2-sorption, SEM, TEM, and XPS.The effects of the doping contents of Sm2O3 and Ag on the photodegradation activity in methyl orange as well as photocatalytic stability were also performed .The results suggest that the photocatalytic activity of Sm2O3/TiO2 for the degradation of methyl orange under UV-light irradiation decrease with the increase of Sm2O3 content. Compared with Sm2O3/TiO2 bulks, Ag-Sm2O3/TiO2 exhibit superior photocatalytic activity for the degradation of methyl orange .The photodegradation activity of the as-prepared sample decreases with the increase of the amount of Ag doping .Ag-Sm2O3/TiO2 with Ag content of 3.0 wt; and Sm2O3 content of 3.0wt; show the best photocatalytic activity , and did not seriously deactivate for the degradation of methyl orange after six cycles testing under the same experimental conditions .
    Study on Photocatalytic Property of GO/Tb4 O7 Composite
    HAO Bin;LIU Jin-qiang;WANG Zhi-lin
    2017, 46(12):  2464-2467. 
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    Graphene Oxide/Tb4O7 composite powders were prepared by hydrothermal synthesis with graphene oxide and Tb 4O7 as raw materials.Graphene/Tb4O7 composite powders were characterized and analyzed by SEM , XRD, visible spectrophotometer .Photocatalytic property of graphene oxide/Tb4 O7 composite powder was tested with Rhodamine B solution as model pollutant under the irradiation of UV (ultraviolet) light.The experimental results show that Tb4O7 particles can be evenly distributed on the surface of graphene oxide in the composite powder; with the increasing of the content of graphene oxide (6;, 8;, 10;) , composite powder has good photocatalytic activity on Rhodamine B solution .The degradation rates of the three composite powders are 98.40;, 98.64; and 98.94; in 60 min.
    Preparation of PANI/F-BiPO4 Heterojunction Composite Photocatalyst and Its Visible Light Photocatalytic Activity
    QUAN Yu-lian;YANG Jun;DONG Ya-rong;JING Chang-yong
    2017, 46(12):  2468-2472. 
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    PANI/F-BiPO4 heterojunction composite photocatalyst was fabricated via a facile hydrothermal method followed by chemisorption method .The structures, morphologies , light absorption properties and surface chemical composition of the samples were studied by X-ray diffraction ( XRD ) , field emission scanning electron microscopy (FESEM), UV-Vis diffuse reflectance spectrophotometer (DRS) and X-ray photoelectron spectroscopy ( XPS) .The photocatalytic activity of PANI/F-BiPO4 was investigated by degradation of RhB in the visible light .Besides , the photocatalytic mechanism was discussed .It was found that PANI/F-BiPO4 exhibited strong absorbance because of the heterostructure formed at their interface.At the same time, a built-in electric field was built due to the effective migration of carrier between PANI and F-BiPO4 , which favors the rapid separation of photogenerated holes and electrons .The results show that PANI/F-BiPO4 composite shows excellent photocatalytic activity under the visible light . The degradation rate of 40 mg/L RhB can be up to 98.7; after 4 hour of visible light irradiation .
    Preparation of Nano ZnO by Surfactant-assisted Method and Its Photocatalytic Property
    LI Yong-xia;CHEN Wen-qian;ZHU Jiang
    2017, 46(12):  2473-2477. 
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    Nano ZnO with different morphologies and sizes were synthesized by precipitation method with Zn( NO3 ) 2·6H2O, ammonia water and different surfactants as raw materials .The effect of surfactants on the photocatalytic degradation of methyl orange by nano ZnO was studied . The crystalline phase , morphology , and optical absorption properties of the as-prepared nano ZnO were characterized by X-ray diffraction ( XRD ) , scanning electron microscope ( SEM ) , and UV-Vis spectroscopy etc . The photocatalytic capability of nano ZnO was tested using methyl orange being a degradation material . Results show that nano ZnO prepared by CTAB has uniformed paticle size , good dispersibility and less agglomeration , and exhibited the best photocatalytic degradation property that the degradation percentages is up to 90.6; within 2h.
    Synthesis of Superparamagnetic Fe3 O4 Nanoparticles and Its Relaxation Properties
    XIAO Wang-chuan;JI Xiao-feng;ZHENG Ying;FAN Cai-xia;LAI Wen-zhong;ZHAO Yan;LUO Ju-xiang;ZHENG Ke-li
    2017, 46(12):  2478-2484. 
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    Superparamagnetic Fe 3 O4 nanoparticles with polyacylic acid coating and high hydrophilicity were synthesized by simple coprecipitation method .The influence of Fe2 +:Fe3+( mole ratio) on the nanoparticle size was investigated . The crystal phase of Fe 3 O4 was confirmed by high resolution transmission electron microscopy and X-ray diffraction analysis .Infrared spectrum and thermogravimetric analysis indicate that poly acrylic acid is successfully coated onto the surface of the nanoparticles .The size of particles and their distribution is obtained from TEM .Average crystal size is infered from X-ray diffraction analysis.The average particles size from TEM and XRD are 7.2 nm, 6.7 nm, 8.3 nm and 9. 1 nm, 8.2 nm, 9.1 nm, respectively, corresponding to Fe2+:Fe3+ =1:1.5, 1:1.75 and 1:2. Dynamic laser scatter analysis reveals that it has some larger particles . The nanoparticles show superparamagnetic properties under room temperature .Relaxation analysis indicates that the sample 1:1. 5 is more suitable for T1 contrast agents and 1:1.75 and 1:2 are for T2 ones.It provides a new way for the optimization of the MR contrast agents .
    Preparation and Photocatalyst Properties of TiO2/Zeolite L
    LIU Hui;QI Hong-bin
    2017, 46(12):  2485-2490. 
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    TiO2/zeolite L composite photocatalyst were prepared by sol-gel method, using trtrabutyl titanate as reaction and zeolite L as the supporter .The samples were characterized by the techniques of XRD, SEM and BET . The important factors that affect photocatalyst performance were tested and discussed by degradation of rhodamine B in the Xenon lamp .The results show that the degradation rate from rhodamine B could reach 99.86;at contions of calcination temperature 300℃, loading of TiO215 mmol/g,radiation time 120 min, amount of catalyst 2 g/L.The degradation rate could reach 96.00;after the photocatalyst was regenerated for 4 times, showing the good stability of the TiO 2/zeolite L composite photocatalyst .Kinetics analysis show that the photocatalytic degradation reaction of rhodamine B can be described by the first-order kinetic equation .
    Development of the Lead-Free Piezoelectric Speakers for Portable Electric Devices
    LI Hui;WANG Ning;WANG Bo;HU Dong-yang;FENG Kun-peng;ZHANG Yang-yang
    2017, 46(12):  2491-2496. 
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    BaTiO3-doped Bi0.5(Na0.82 K 0.18)0.5TiO3 lead-free thick films were prepared on Pt-electroded alumina substrates using screen printing , their phase structure , microstructure , dielectric , piezoelectric and ferroelectric properties were investigated .The results show that the morphotropic phase boundary (MPB) of (1-x)BNKT-xBaTiO3 thick films was in the x range of 3mol;-7mol;.5mol; BT-doped BNKT (95BNKT-5BT) thick films exhibited preferable relative dielectric constant of 793, piezoelectric coefficient of 72 pC/N, remnant polarization of 4.35 μC/cm2 , unipolar strain value of 0.817;. However, the addition of 5mol; BT increases the dielectric loss from 1.1; to 6.2;, and also increases the coercive field from 35.77 kV/cm to 53.72 kV/cm.In the end, the prepared 95BNKT-5BT thick films were used to make the soud film , with the help of the driver circuit , the lead-free piezoelectric speaker for protable electronic device was developed .
    Effect of Acidity and Basicity on Zirconia Ceramics by Atomized Slurry CMP
    LI Qing-zhong;XIA Ming-guang;SHI Wei-bin
    2017, 46(12):  2497-2502. 
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    The process of fine atomizing slurry CMP was adopted to polish the zirconia ceramics .The representative acid-base regular in slurry , which has an influence on the MRR, surface morphology and surface roughness for polished zirconia ceramic as well as the effect of acid-base on the stability of fine atomization slurry were studied .The results show that the silica polishing slurry prepared for the fine atomization process has better dispersion stability in the alkaline environment .Although the acid polishing slurry has higher MRR, the acid corrosion of the zirconia ceramic is too large to polish zirconia ceramic;The surface quality polished with organic alkali as a regulator after polishing is significantly better than inorganic and inorganic acids , organic acids;the alkaline polishing slurry used of ethylenediamine after fine atomization was adopted to polish zirconia ceramic , which shows a high quality ultra-smooth , low damage surface and high processing efficiency , surface roughness Rq of 1.67 nm, MRR of 182.23 nm/min.
    Vacuum Brazing of Diamonds with Mechanical Milling Cu-Sn/TiH2 Alloy Powder
    WU Qiao-ping;LUO Zhou;DENG Zhao-hui;KANG Hui-min;FU Zhi-qiang
    2017, 46(12):  2503-2508. 
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    Cu-Sn/TiH2 alloy powders were prepared by using mechanical ball milling method , the prepared powders have the characteristics of small particle size and uniform distribution of elements .The vacuum brazing experiment of Cu-Sn/TiH2 alloy powders and diamonds was further carried out .The experimental results indicate that the diamonds surface formed a continuous and dense TiC layer when the brazing temperature is 920 ℃ and the brazing time is 12 min, and the formed TiC layer can help achieve high bonding strength between brazing alloy and diamonds .The relative density of the brazing layer reach 97 .6;, there is only a little tiny spherical pores .The thermal damage of brazed diamonds is very small , the diamonds mainly occurr micro-fracture, fracture and rubdown in cutting process , and there is few diamonds pull-out during the cutting processing .
    Preparation of UV and Blue Radiation Double Cut-off Coated Eyes-protecting Glass by Sol-gel Method
    ZHAO Sheng;HE Jian-xiong;JIANG Hong
    2017, 46(12):  2509-2513. 
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    The silicon oxide film was coated on the bottom ( tin) surface of 3 mm thick float glass by sol-gel method .The silicon oxide film was embedded with Ag nanoparticles , so that it can achieve the effect of blue light absorption .The zinc oxide film with wurtzite structure was coated on the non-tin surface to achieve the barrier of ultraviolet effect .The effect of heat treatment temperature and film thickness on the near UV and blue light barrier rate was also studied .The result shows that the film is more compact with the increase of annealing temperature .Meanwhile , The absorption rate of blue light also increases gradually , and the absorption peak shifts red .The structure of the silicon oxide film can absorb short wave blue light of 380-450 nm by the reduction of AgNO3 into Ag nanoparticles on tin rich surface .The experimental samples show a bright golden yellow color , and the degree of gold gradually deepened with the increase of film thickness .The Zinc Oxide film shows a stable wurtzite structure with a film thickness of 438 nm, and the surface shows particle state .The UV light ( <380 nm) barrier rate of sample a is 98.83;.The surface of the silicon oxide film is compact with the thickness of 200 nm, and the barrier rate of 380 nm to 450 nm is 90 .73;.The visible light transmittance of the sample from 450 nm to 780 nm can reach 77 .8;.
    Self-assembly Simulation of Nano-porous Structure of Silica Aerogel
    ZHANG Guang-lei;CHEN Yi-bo;JIA Wei-tao;ZHAO Peng-yuan;QIN Guo-qiang
    2017, 46(12):  2514-2520. 
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    The atomic scale model and mechanical properties of SiO2 aerogels was simulated and calculated based on the principle of molecular dynamics .The results indicates that the structure is mainly nano-clusters and connected skeleton structure is difficult to form when the density is 0 .078 g/cm3 .The distribution of silica oxygen elements has been extended to a connected amorphous skeleton structure when the density is 0.172 g/cm3 and above.The stress-strain relationships curve were figured out by applying strains on the different density cell , and the elastic modulus was obtained in different elastic range.The simulation results shows that the elastic modulus is linear with the density .The elastic modulus changes from 0.1265 MPa to 0.7889 MPa when density ranges from 0.078 g/cm3 to 0.443 g/cm3 .
    Study on Single Layer Forming Technology of Light Curing Resin Based Ceramic
    GONG Jun;DING Tong-tong;NING Hui-feng
    2017, 46(12):  2521-2526. 
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    In the ceramic light curing three-dimensional molding process , the single-layer forming effect on the accumulation of green body plays a decisive role .In this paper , we mainly study the influence of the wavelength , the scanning speed , the illumination time and the irradiation distance of the light source on the quality and precision of the molded parts in the printing of single layer blank .The results show that the wavelength of the light source is closer to the absorption wavelength range of the initiator , and the curing effect is better .When the exposure amount of the light source reaches the critical exposure , the slurry can be completely cured .With the increasing scanning speed , continuously reduced , the thickness of the curing gradually reduced , when the scanning speed is very large , the body surface density is very low, the organization looks become loose .In addition , the irradiation distance of the ultraviolet light source has no effect on the molding quality of the green body .
    Effect of Raw Ore Materials on Longquan Celadon Characteristics
    SHI Qun
    2017, 46(12):  2527-2532. 
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    Longquan local raw materials , such as Huangtan clay , Pucheng clay , Zhuxiang clay , and Baoxi clay were used to prepare Longquan celadon by the traditional ceramic technology .The chemical composition and the microstructure of the Longquan celadon samples were characterized by high -speed analyzer, XRD and SEM, et al.The porcelain characteristics were analyzed using the K2O-Al2O3-SiO2 phase diagrams .The results show that the main phases of Longquan celadon are quartz , mullite and porous, as well as a small amount of glass .There is the interface of the glass and the crystal in the glaze well developed .It is studied Longquan celadon features the effects by the raw materials .
    Ultra-wide Bandgap Semiconductorβ-Ga2O3 Single Crystal Growth Breaks through 2 Inches
    TANG Hui-li;HE Nuo-tian;LUO Ping;GUO Chao;LI Qiu;WU Feng;WANG Qing-guo;PAN Xing-yu;LIU Bo;XU Jun
    2017, 46(12):  2533-2534. 
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