人工晶体学报 ›› 2021, Vol. 50 ›› Issue (4): 603-618.
蒋金科, 崔双月, 刘阳, 陶绪堂
收稿日期:
2021-03-04
出版日期:
2021-04-15
发布日期:
2021-05-21
通讯作者:
刘 阳,博士,教授。E-mail:liuyangicm@sdu.edu.cn;陶绪堂,博士,教授。E-mail:txt@sdu.edu.cn
作者简介:
蒋金科(1997—),男,河南省人,硕士研究生。E-mail:jk_sdu@163.com
基金资助:
JIANG Jinke, CUI Shuangyue, LIU Yang, TAO Xutang
Received:
2021-03-04
Online:
2021-04-15
Published:
2021-05-21
摘要: 大尺寸有机晶体在太赫兹波产生、中子探测、微波激射等多个关系国计民生、涉及国家安全的领域具有重要应用前景。但大尺寸有机单晶生长一直是国际公认的难题,无论是在生长理论、生长方法还是生长设备方面都远远落后,在整个人工晶体领域相对小众;而且有机晶体硬度低、脆性高、易解理等本征特性为加工和后期应用带来了很多困难,制约了相关领域的发展。有机分子晶体的物化性质决定了其生长方法多采用溶液或气相方法,熔体生长方法在结晶质量控制方面难度更大;但针对上述应用所需的大尺寸单晶和掺杂要求,熔体生长方法相比溶液和气相方法更具优势。本文对熔体法生长大尺寸有机晶体进行分类总结,对影响生长过程和晶体质量的原料提纯、籽晶生长、安瓿设计、固液界面控制、生长及降温速度调控、加热温区等因素进行分析,结合本课题组近年来利用熔体法生长大尺寸有机晶体的实际经验,旨在为大尺寸有机晶体的生长研究提供理论基础和实践经验,突破高质量、大尺寸有机单晶生长的国际难题。
中图分类号:
蒋金科, 崔双月, 刘阳, 陶绪堂. 熔体法生长大尺寸有机晶体[J]. 人工晶体学报, 2021, 50(4): 603-618.
JIANG Jinke, CUI Shuangyue, LIU Yang, TAO Xutang. Melt Growth of Bulk Organic Crystals[J]. JOURNAL OF SYNTHETIC CRYSTALS, 2021, 50(4): 603-618.
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