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    20 December 2025, Volume 54 Issue 12
    Reviews
    Research Progress on the Epitaxial Growth of Cubic Silicon Carbide
    LU Zhengxuan, LI Chen, ZHOU Chao, LU Yuanhao, LI Haochao, KE Shanming, TONG Shukyin
    2025, 54(12):  2037-2059.  doi:10.16553/j.cnki.issn1000-985x.2025.0127
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    Silicon carbide (SiC), as a representative third-generation wide-bandgap semiconductor material, has demonstrated great potential for applications in high-temperature, high-voltage, and high-frequency power electronic devices due to its excellent electrical, thermal, and mechanical properties. Among the various SiC polytypes, cubic silicon carbide (3C-SiC) exhibits higher electron mobility, lower interface trap density, and superior channel characteristics, making it highly competitive for devices operating in the medium voltage range. This review summarizes the recent progress in the epitaxial growth of 3C-SiC, with a particular focus on comparing the characteristics of chemical vapor deposition (CVD) and sublimation epitaxy (SE) in terms of growth processes, defect evolution, and substrate selection. The formation mechanisms and impacts of key structural defects including point defects, stacking faults, anti-phase boundaries, surface protrusions, and residual stress are systematically analyzed. Furthermore, the latest advances in 3C-SiC-based power diodes, MOSFETs, and heterostructure devices are reviewed. Finally, future development directions for improving the epitaxial quality and device performance of 3C-SiC through substrate engineering, defect control, and process optimization are discussed.

    Research Progress on TBC Solar Cell Technology
    GAO Jiaqing, QU Xiaoyong, WU Xiang, GUO Yonggang, WU Weixiong, ZHANG Bo, WEI Kaifeng
    2025, 54(12):  2060-2071.  doi:10.16553/j.cnki.issn1000-985x.2025.0199
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    As a representative of the third-generation high-efficiency crystalline silicon photovoltaic technology, the tunnel oxide passivated back contact (TBC) solar cells deeply integrate the superior interface passivation characteristics of TOPCon technology with the zero front-side shading advantage of interdigitated back contact (IBC) cells, significantly reducing optical absorption losses and carrier recombination, thereby leading to laboratory conversion efficiencies approaching 28%. This paper systematically elaborates on the core structural principles and technical features of TBC cells, with a focused analysis of the breakthrough mechanisms in their optical, passivation, and contact properties. It provides a detailed introduction to key fabrication processes, including back-side patterning design, passivating contact structure fabrication, and metallization techniques. Furthermore, the paper reviews the evolution and latest research progress of TBC technology, while also addressing the challenges faced in its industrialization, such as high process complexity, the need for improved bifaciality, cost control and supply chain maturation, thereby offering valuable insights for subsequent technological optimization and large-scale application.

    Research Articles
    Defect Control of Polytype Inclusion in Large-Diameter SiC Single Crystal Grown by PVT Method
    LU Jiazheng, HU Runguang, ZHENG Lili, ZHANG Hui, HU Dongli
    2025, 54(12):  2072-2082.  doi:10.16553/j.cnki.issn1000-985x.2025.0151
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    This study addresses the control of 6H-SiC polytype inclusions during the physical vapor transport (PVT) growth of 8-inch (1 inch=2.54 cm) N-type 4H-SiC crystals through experimental and numerical simulation approaches. Firstly, the emergence timing and locations of 6H-SiC polytype inclusions were determined via experimental observations (by RF heating system). A numerical simulation of the entire crystal growth process was then conducted, tracking the evolution of temperature at the growth front edge and the carbon supersaturation ratio in its vicinity over time. This enabled the establishment of critical condition criteria for 6H-SiC polytype inclusion formation. Based on these criteria, the correlation between process parameters and 6H-SiC polytype inclusion defects was systematically investigated for a typical large-scale multi-zone resistive-heating PVT growth system. The findings reveal that for a given PVT system, increasing the upper/lower heater power ratio and the argon gas pressure contributes to suppressing the formation of 6H-SiC polytype inclusions.

    Effects of the Temperature Gradient on the Fracture Stress of Large-Sized SiC Grown by PVT Method
    XU Binjie, CHEN Pengyang, LU Sheng’ou, XUAN Lingling, WANG Anqi, WANG Fan, PI Xiaodong, YANG Deren, HAN Xuefeng
    2025, 54(12):  2083-2100.  doi:10.16553/j.cnki.issn1000-985x.2025.0109
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    Fracture stress remains the primary barrier preventing the diameter of silicon carbide (SiC) single crystals grown by the physical vapor transport (PVT) method from exceeding 200 mm. In the present study, the fracture stress was calculated under both 4° off-axis and on-axis growth conditions. The results demonstrate comparable fracture behavior between the two growth conditions, with negligible contributions from basal plane slips and nearly identical effects of prismatic plane slips. Besides, the effects of the temperature gradient on the fracture stress were elaborated, suggesting that almost all fracture stresses arise from the radial temperature gradient at high temperatures, while the axial temperature gradient exhibits minimal effect. Further simulations investigated the effects of temporal shape evolution, crystal convexity, and diameter, revealing a consistent correlation between fracture stress magnitude and radial temperature gradient variation. This study provides furthsinsights into the fracture stress-temperature gradient relationship, offering guidance for fracture prevention during PVT growth.

    Effect of Magnetic Field Strength on the Uniformity of COP Defects in 12 Inch Cz Monocrystalline Silicon
    WANG Zhongbao, ZHANG Youhai, LIU Tianpei, NI Haoran, RUI Yang, MA Cheng, WANG Liguang, CAO Qigang, YANG Shaolin
    2025, 54(12):  2101-2111.  doi:10.16553/j.cnki.issn1000-985x.2025.0130
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    In semiconductor manufacturing, monocrystalline silicon grown by Czochralski (Cz) method serves as the core substrate for microelectronic devices, with its crystal integrity and defect distribution being crucial for chip yield and reliability. However, the issue of non-uniform radial distribution of crystal originated particle (COP) defects during the Cz growth process urgently needs to be addressed. This paper investigates, through numerical simulations and experimental research, the effects of different transverse magnetic field strengths (500 and 3 000 Gs) on melt convection, melt temperature distribution, and the temperature gradient at the solid-liquid interface during the pulling of 12 inch (1 inch=2.54 cm) Cz monocrystalline silicon. It also analyzes the mechanism by which magnetic field strength influences the uniformity of COP distribution. The results indicate that under a 3 000 Gs magnetic field, the melt flow, temperature distribution, and the temperature gradient at the solid-liquid interface are more stable, facilitating the formation of a low-density and uniform COP distribution. In contrast, under a 500 Gs magnetic field strength, the COP distribution throughout the silicon ingot exhibits high density and non-uniformity. The experimental results are consistent with the numerical simulations, verifying the significant impact of magnetic field strength on the uniformity of COP distribution. This study provides a theoretical basis and practical guidance for optimizing the Cz monocrystalline silicon growth process and improving crystal quality.

    X-Ray Imaging Performance of Gd3(Al,Ga)5O12∶Ce Scintillation Screens under Synchrotron Radiation
    LI Mingqing, ZHAO Shuwen, FENG Jing, ZHENG Xiang, GUO Han, YUAN Lanying, DING Dongzhou, FENG He
    2025, 54(12):  2112-2118.  doi:10.16553/j.cnki.issn1000-985x.2025.0176
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    Gd3(Al,Ga)5O12∶Ce (GAGG) scintillators, characterized by high density (6.63 g/cm3), high light yield (>58 000 ph/MeV), fast decay time (~90 ns), and stable physicochemical properties, are promising candidates for high spatial resolution X-ray imaging scintillation screens. Determining the spatial resolution limit of the GAGG scintillation screen and approaching this limit cost-effectively is a significant yet challenging task. In this work, GAGG single crystals without co-doping and with Mg or Yb co-doping were grown by the Czochralski method. A series of GAGG scintillation screens were prepared by cutting and polishing, and their optical and scintillation properties were systematically characterized. The theoretical spatial resolution was calculated via Geant4 simulations, and imaging experiments were conducted at the BL13HB beamline of the Shanghai Synchrotron Radiation Facility (SSRF). Experimental studies confirm that GAGG scintillation screens exhibit superior imaging performance in X-ray applications, particularly beneficial for medical imaging and industrial nondestructive inspection applications. The theoretical spatial resolution of GAGG scintillation screens is 0.4 μm, whereas our experiment attained 0.9 μm (555 lp/mm), a performance level that aligns with current state-of-the-art systems in the field. Comparative analysis reveals that spatial resolution exhibits limited variation with screen thickness in the 0.3~1 mm range, but shows greater sensitivity to surface conditions and optical transmittance. Therefore, in fabricating high-resolution GAGG scintillation screens, excessive reduction in thickness below practical thresholds is unnecessary. Efforts should prioritize improving crystalline optical quality through growth process optimization (inclusion suppression) and polishing technique refinement (surface roughness control).

    Microstructure and Properties of Gd2O2S∶Tb Scintillation Ceramics Fabricated by Pressure-Assisted Sintering
    WU Junlin, HUANG Dong, HU Chen, LI Tingsong, YANG Wenqin, JIANG Xingfen, ZHOU Jianrong, SUN Zhijia, LI Jiang
    2025, 54(12):  2119-2126.  doi:10.16553/j.cnki.issn1000-985x.2025.0134
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    Gd2O2S∶Tb scintillation ceramics have the advantages of high X-ray stopping power, high light output and excellent spectral matching performance and low production cost, making them promising scintillators for security X-ray computed tomography. The Gd2O2S∶Tb nano-powders were synthesized from Gd2O3 powders, Tb(NO33 and H2SO4 by the hot water-bath reduction method in this work. The pure-phase Gd2O2S∶Tb ceramics were fabricated by hot pressing and hot isostatic pressing (HIP) post-treatment. The effects of hot-pressing temperature (975~1 100 ℃) and HIP post-treatment temperature (1 050~1 350 ℃) on the microstructure, optical transmittance and scintillation properties of Gd2O2S∶Tb ceramics were systematically investigated. As the hot-pressing temperature increase from 975 ℃ to 1 100 ℃, the pores within the ceramics decrease and the relative densities increase from 91.4% to 98.9%. As the HIP temperature increase from 1 050 ℃ to 1 350 ℃, the relative density of Gd2O2S∶Tb ceramics gradually increase, with higher HIP temperatures promoting the removal of internal pores. Therefore, compared to HIP treatments at 1 050 and 1 200 ℃, the Gd2O2S∶Tb ceramics treated at 1 350 ℃ exhibit higher total optical transmittance. The Gd2O2S∶Tb ceramics hot pressed at 1 050 ℃ for 1.5 h under 60 MPa and HIP post-treated at 1 350 ℃ for 3 h under 176 MPa Ar atmosphere show the highest total optical transmittance of 20.3% at 545 nm (1 mm in thickness). It also shows the highest X-ray excited luminescence intensity due to the efficient extraction of scintillation light.

    Simulation Study of Low-Frequency Bandgap for Triple Helix Beam Phononic Crystal
    XUE Jingyi, HU Qiguo, YAN Zhaoqiang, LIU Ying, ZHANG Pizhu
    2025, 54(12):  2127-2135.  doi:10.16553/j.cnki.issn1000-985x.2025.0138
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    To mitigate low-frequency vibrational disturbances in engineering applications, this study proposes a triple-helix beam phononic crystal configuration, comprehensive finite element analysis and equivalent modeling demonstrating its superior low-frequency vibration attenuation characteristics. The results indicate that the phononic crystal exhibits a complete bandgap in the range of 47~99 Hz. Within this bandgap, the effective mass became negative, confirming the full reflection vibration isolation mechanism. Transmission loss simulations further corroborate substantial vibration energy attenuation across the bandgap frequencies. Additionally, the phononic crystals demonstrate robust vibration isolation performance under diverse loading conditions, including distributed, concentrated, and torsional loads. The parametric optimization study reveals that precise adjustment of the helix plate thickness, groove width and cylindrical oscillator radius enabled the realization of the band structure with lower frequency and significantly greater bandwidth. This study provides valuable insights and practical engineering significance for low-frequency vibration mitigation.

    Investigation on the Microstructural Evolution Mechanism of GdAlO3-Al2O3 Eutectics Grown by Micro-Pulling-Down Method
    LIU Zhen, XU Jintao, ZHU Shanlin, LIAO Canyuan, HU Hongwei, ZHONG Xingyuan, ZHONG Jiuping
    2025, 54(12):  2136-2145.  doi:10.16553/j.cnki.issn1000-985x.2025.0141
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    GdAlO3(GAP)-Al2O3 oxide eutectic is widely used in high-temperature structural materials due to its high bending strength, excellent creep resistance and oxidation resistance at high temperature. As well known, the properties of eutectic materials are influenced directly by the microstructure of eutectic, and the microstructure of eutectic materials can be arranged in a certain direction through directional solidification technology. Micro-pulling-down method (μ-PD), as a directional solidification technology for crystal growth, has the advantages with large temperature gradient, wide growth rate range, short growth period, and visible growth process. In this work, GdAlO3(GAP)-Al2O3 eutectics were grown by μ-PD, and its microstructure was determined by XRD and SEM. The results show that the microstructure of the obtained eutectics was changed gradually from disorder to order with the increasing of growth rate. The microstructure of eutectic is also influenced by the temperature gradient and growth rate.The evolution mechanism of eutectic microstructure was investigated. By optimizing the growth conditions, large-scale eutectic materials with ordered microstructure are expected to be obtained, which have potential applications in the fields of high-resolution detection imaging, laser display and lighting, optical storage and optical temperature sensor.

    Induced Phase Transformation and Luminescence Performance Optimization of Li+ Doped YPO4∶Dy3+ Phosphors
    ZHAN Junwei, RUAN Yongqi, CHEN Zhiqiang, WEN Lei, PENG Siyan, YANG Liusai
    2025, 54(12):  2146-2155.  doi:10.16553/j.cnki.issn1000-985x.2025.0179
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    A series of YPO4∶Dy3+ phosphors with different Li+ doping concentrations were synthesized via a hydrothermal method combined with high-temperature calcination. The effects of Li+ co-doping on the structure, morphology and luminescence properties of YPO4∶Dy3+ phosphors were systematically investigated. X-ray diffraction (XRD) results indicate that Li+ doping promotes the phase transition of YPO4·0.8H2O from hexagonal to tetragonal phase. Moreover, Li+ could either substitute Y3+ at lattice sites or occupy interstitial positions. Scanning electron microscopy (SEM) results show that with the increase of Li+ doping concentration, the morphology of the phosphor changes from hexagonal prism to spherical particles, and the average particle size gradually decreases. Fluorescence spectroscopy analysis reveals that appropriate Li+ doping can significantly enhance the luminescence intensity of YPO4∶Dy3+ phosphors. When the Li+ doping amount is 5%, the luminescence intensity reaches the maximum value, which is approximately 2.3 times that of the undoped sample. Meanwhile, Li+ doping can also improve the thermal stability of the phosphor. With the increase of Li+ doping amount (x=1%~7%), the CIE chromaticity coordinates of YPO4∶5%Dy3+xLi+ phosphors change gradually from (0.233, 0.283) to (0.238, 0.289). The research results demonstrate that Li+ co-doping is an effective approach to regulate the luminescence properties of YPO4∶Dy3+ phosphors, and provides theoretical basis and experimental foundation for their application in the field of white light-emitting diodes (LEDs).

    Synthesis, Crystal Structure of the Novel Acylthiourea CCT and Its Interaction Study with Calf Thymus DNA
    JIANG Min, XIONG Zihan, ZHANG Tong, YANG Yuru, LI Huiru, LIU Yan, ZHAO Xia
    2025, 54(12):  2156-2163.  doi:10.16553/j.cnki.issn1000-985x.2025.0149
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    Using ammonium thiocyanate, 2-chloro-4-chlorophenylformyl chloride, and 2-aminobenzoic acid as raw materials, a new type of acylthiourea derivative, N-(3-chlorobenzoyl)-N′-2-carboxybenzoyl thiourea (N-(3-chloro-benzoyl)-N′-2-carboxybenzoyl thiourea, CCT) was synthesized through a “one-step method”. The compound was characterized by single-crystal X-ray diffraction (SXRD), nuclear magnetic resonance spectroscopy, Fourier transform infrared spectroscopy (FT-IR), ultraviolet spectroscopy, and fluorescence spectroscopy. The SXRD results indicate that it belongs to the monoclinic crystal system, with the P21/c space group. Through multispectroscopy (ultraviolet absorption spectroscopy and fluorescence competitive substitution) combined with molecular docking technology, the interaction between the target thiourea and calf thymus DNA was determined. The results show that the two formed a complex in a groove interaction mode, without significantly disrupting the complete double helix structure of DNA. Hydrogen bonds are the main force.

    First-Principles Study of Non-Substitutional Point Defects in Germanium-Lead Alloys
    JIA Mengjiang, HUANG Wenqi, WANG Hai, ZHENG Jun
    2025, 54(12):  2164-2172.  doi:10.16553/j.cnki.issn1000-985x.2025.0142
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    Germanium-lead (Ge-Pb) alloys are recognized as one of the most promising silicon-compatible, high-efficiency luminescent materials. However, the attainment of high-quality alloys with elevated lead composition is significantly impeded by the pronounced tendency for lead surface segregation during crystal growth. To elucidate the underlying microscopic mechanisms of this segregation, first-principles calculations based on density functional theory (DFT) were employed. The properties of substitutional lead and non-substitutional point defects (VPbV) in Ge-Pb alloys were systematically investigated across varying lead compositions and under different doping conditions. It was found that an increase in lead composition elevates the formation energy of substitutional lead while concurrently reducing the formation energy of VPbV defects. This energetic trend indicates an enhanced propensity for lead surface segregation at higher lead concentrations. Furthermore, when the alloys are doped with hydrogen (H), the formation energy of substitutional lead reduces relative to the undoped case, whereas the formation energy of VPbV defects increases. This modification in defect energetics demonstrates that hydrogen doping effectively suppresses lead surface segregation. These theoretical results provide a consistent explanation for the experimentally observed patterns of lead surface segregation. Consequently, this study not only offers crucial theoretical guidance for the material growth of high-quality Ge-Pb alloys but also demonstrates that the fundamental concepts and methodologies developed herein can be extended to the investigation of other group-IV alloys.

    Density Functional Theory Investigation of N2O and HCN Adsorption Behavior on SnSe Monolayers
    WU Jiayin, WEI Jingting, LI Bin, LI Zongbao, MO Qiuyan
    2025, 54(12):  2173-2180.  doi:10.16553/j.cnki.issn1000-985x.2025.0163
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    The adsorption behavior, electronic characteristics, and gas sensing performance of β-SnSe monolayers toward N2O and HCN molecules were systematically investigated using density functional theory. Optimized adsorption configurations reveal that both gases are physisorbed onto the SnSe surface, with HCN exhibiting stronger interactions. Adsorption energy calculations demonstrate the exothermic nature of these processes, indicating their thermodynamic feasibility for spontaneous gas capture under ambient conditions. The adsorption of HCN significantly increase the density of states near the Fermi level, thereby enhancing the electrical conductivity of the SnSe monolayer. Furthermore, rapid recovery behaviors for both gas species are observed at room temperature, confirming the excellent reversibility of the sensing system. Under a bias voltage of 1.2 V, the response sensitivity to HCN reaches 61.7%, markedly surpassing that of N2O and outperforming existing two-dimensional sensing materials. Further highlighting the excellent performance of SnSe in HCN detection. These results not only reveal the sensing mechanism of SnSe toward HCN, but also provide theoretical support for the design of low-cost, highly sensitive, and reusable gas sensors suitable for real-time environmental monitoring applications.

    Synthesis and Optical Properties of Bi3+/Eu3+ Co-Doped Zn2GeO4 Phosphors
    WANG Li, SONG Yuxuan, GUO Hui, YANG Dengtao, HUANG Yini, YANG Yunwei, WU Dongni
    2025, 54(12):  2181-2189.  doi:10.16553/j.cnki.issn1000-985x.2025.0131
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    A series of Bi3+/Eu3+ co-doped Zn2GeO4 phosphors (Zn2GeO4∶0.20Eu3+xBi3+x=0.05~0.30) were successfully synthesized via hydrothermal method.The phase structure, morphology, luminescent properties, and energy band regulation mechanism were systematically investigated using X-ray diffraction (XRD), excitation/emission spectroscopy,scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), and first-principles calculations.It was confirmed that both Eu3+ and Bi3+ were effectively incorporated into the Zn2GeO4 host lattice, with Eu3+ occupying Zn2+ sites, and no impurity phases were introduced by Bi3+ doping. First-principles calculations reveal that the Zn2GeO4∶0.20Eu3+xBi3+ system possesses an indirect band gap, with the Fermi level (0.368 8 eV) crossing the conduction band, exhibiting near-metallic behavior, which enhanced the luminescence performance.At the optimal Bi3+ doping concentration of x=0.30,Bi3+ act as efficient sensitizers, transferring the absorbed ultraviolet light energy to the excited state energy levels (5D2 and 5D1) of Eu3+.This significantly enhances the excitation responses of Eu3+ at 384 nm (7F05D2) and 534 nm (7F05D1),as well as the characteristic red emission (5D07F2, 616 nm).The phosphor possesses efficient red emission and tunable luminescence capabilities, providing new insights for the design of solid-state lighting materials.

    Multifunctional Additive of Sodium 4-Chlorobenzenesulfonate Enables Efficient Carbon-Based CsPbI2Br Perovskite Solar Cells
    HUANG Cheng, QIAN Yannan
    2025, 54(12):  2190-2199.  doi:10.16553/j.cnki.issn1000-985x.2025.0121
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    Carbon-based hole-transport-layer-free CsPbI2Br perovskite solar cells have attracted widespread attention owing to their low fabrication cost and excellent thermal stability. However, the rapid crystallization of CsPbI2Br films often leads to a high density of defects, resulting in trap-assisted non-radiative recombination and severe ion migration, which significantly accelerate energy losses and performance degradation of the devices. In this study, a simple and practical additive strategy was adopted to regulate the crystallization and passivate defects in CsPbI2Br using the synergistic effects of anions (4Cl-BZS-) and cations (Na+) from sodium 4-chlorobenzenesulfonate (Na-4Cl-BZS). The 4Cl-BZS- anions coordinate with Pb2+ through the —SO3- and —Cl functional groups located at both ends of the benzene ring, effectively passivating under-coordinated Pb2+ and increasing the formation energy of halide vacancies. This interaction also promotes preferential growth of the perovskite polycrystalline film along the (100) plane, yielding high-quality CsPbI2Br films. Moreover, Na+ cations incorporate into the perovskite lattice via interstitial doping, significantly increasing the migration barrier of halide ions and enhancing the crystal stability of the perovskite. Benefiting from the cooperative action of the cation-anion pair, the resulting carbon-based hole-transport-layer-free CsPbI2Br perovskite solar cell achieves a power conversion efficiency of 13.07%, along with an open-circuit voltage of 1.18 V and a fill factor of 74.26%.

    Simulation Study on the Photoelectric Performance of Formamidinium Tin Iodide Perovskite Solar Cells
    JIANG Jingwen, LUO Yuanxing, WANG Meizhen, HUANG Kewen, LUO Guoping, ZHU Weiling
    2025, 54(12):  2200-2208.  doi:10.16553/j.cnki.issn1000-985x.2025.0137
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    Formamidinium tin iodide (FASnI3) has emerged as a promising alternative to lead-based perovskite materials, owing to its environmental advantages, high absorption coefficient, and appropriate bandgap. A planar FASnI3 perovskite solar cell with the p-i-n structure anode/hole transport layer (HTL)/FASnI3/electron transport layer (ETL)/cathode was simulated and analyzed using SCAPS simulation software. Based on experimental data, an initial simulation model was developed to investigate the effects of carrier transport layer materials, perovskite layer parameters, interface defect density of states, and operating temperature on the photoelectric performance of FASnI3 perovskite solar cells. The simulation results indicate that employing a 30 nm thick CuI HTL increases the device’s power conversion efficiency (PCE) from 9.56% to 10.64%. Further analyses examined the influence of perovskite layer thickness, defect state density and electron affinity, ETL thickness, interface defect state surface density, and operating temperature on device performance. After optimization, the FASnI3 perovskite solar cell is projected to achieve an PCE of 26.63%, with an open-circuit voltage (Voc) of 1.127 V, a short-circuit current density (Jsc) of 28.08 mA·cm-2, and a fill factor (FF) of 84.13%. These simulation results provide a theoretical foundation for experimentally enhancing the photoelectric performance of FASnI3 perovskite solar cells.

    Electrochemical Performance of LiNi0.8Co0.1Mn0.1O2 Cathode Material with Li1.3Al0.3Ti1.7(PO4)3 Coating
    YAO Nianchun, HE Yulin, ZHANG Min, WANG Ziqiang
    2025, 54(12):  2209-2216.  doi:10.16553/j.cnki.issn1000-985x.2025.0126
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    The precursor Ni0.8Co0.1Mn0.1O2(OH)2 was generated by co-precipitation, and LiNi0.8Co0.1Mn0.1O2 (NCM811), the cathode material, was prepared by calcination. The coating modification of NCM811 was investigated utilizing various amounts of Li1.3Al0.3Ti1.7(PO43 (LATP) coating (mass fraction of 1%, 2%, and 3%). The results show that the capacity retention rate is 84.65% after 350 cycles at 3.0~4.3V, while the capacity retention rate of the uncoated NCM811 is 80.58% when the LATP coating amount is 2%. The rate performance test indicates that the discharge specific capacity of the LATP (2%) sample is 117.1 mAh·g-1 at 10 C, while the uncoated NCM811 sample has a specific capacity of 101.8 mAh·g-1. Therefore, we can conclude that an appropriate amount of LATP coating can enhance the lithium ions diffusion rate and optimize the ion transport pathways. Simultaneously, as a coating layer, LATP prevents direct contact between the cathode material and the electrolyte, reducing side reactions. This, in turn, lowers the interfacial impedance and improves the cycling life.